Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Citation - WoS: 3Citation - Scopus: 3Effects of Different Precursors on the Aging and Electrocaloric Properties of Mn-Doped Ba0.95sr0.05tio3 Ceramics(Springer, 2023) Karakaya, Merve; Erdem, Emre; Akdoğan, Yaşar; Adem, UmutIn this study, the effects of different types of Mn precursors (MnO2 and Mn2O3) and sintering temperature on the defect dipole formation, ferroelectric aging and electrical properties were investigated by using Ba0.95Sr0.05TiO3 ceramics as the base. Both Mn precursors were substituted to the Ti-site as 1 mol% and two different sintering temperatures of 1325 and 1400 degrees C were used to study the effect of grain size. We deduced that slightly higher amounts of Mn2+ can be incorporated into the perovskite structure when MnO2 is used as the precursor, by using X-ray diffraction and electron paramagnetic resonance spectroscopy. Mn-doped samples sintered at 1325 degrees C age faster than those sintered at 1400 degrees C. Aging caused a decrease in the electrocaloric effect whereas Mn-doping increased it. This study shows that Mn precursor used for the acceptor doping affects the amount of Mn incorporated into the structure and therefore electrical properties of the resulting ceramics.Article Citation - WoS: 103Citation - Scopus: 110Cold Sintering of Ceramics and Glasses: a Review(Elsevier Ltd., 2020) Ahmetoğlu, Çekdar Vakıf; Karacasulu, LeventTraditionally ceramic artifacts are processed at high temperatures (> 1000 degrees C) by classical sintering techniques such as solid state, liquid phase and pressure-assisted sintering. Recently, inspired from the geology, novel sintering approaches that allow the densification of ceramic components at relatively low temperatures <= 400 degrees C have been proposed. While initial efforts for such low temperature densification concept were developed in the mid-70s, the topic has become increasingly prominent in the last decade. Currently, these low temperature methods can be classified into four main groups: (i) hydrothermal reaction sintering (HRS), (ii) hydrothermal hot pressing (HHP), (iii) pressure-assisted densification techniques: room-temperature densification (RTD), cold sintering (CS), warm press (WP), and finally no-pressure assisted method called (iv) reactive hydrothermal liquid phase densification (rHLPD). Above named techniques are commonly assisted by an aqueous solution used as either reactant or transient liquid phase to assist densification. Starting from the background in traditional sintering processes, this review aims to explore in depth the existing literature about low temperature densification approaches along with their advantages & disadvantages, and probable application areas.Article Citation - WoS: 6Citation - Scopus: 6The Expansion Behavior of Slurries Containing Recycled Glass Powder Carboxymethyl Cellulose, Lime and Aluminum Powder(Elsevier, 2020) Zeren, Doğuş; Şentürk, Ufuk; Güden, MustafaThe rheology and foaming/expansion of the slurries of a waste/recycled glass powder with 50, 55 and 60 wt% of solid (glass powder) were experimentally investigated. The glass powder slurries were foamed using aluminum powder as foaming agent (0.75 wt%) and calcium hydroxide as activator (1 wt%). Sodium carboxymethyl cellulose (CMC) was added to the slurries as a binder with the amounts between 0 and 4 wt%. The expansions of the slurries were measured in-situ using a laser sensor and reported as percent volume expansion. The CMC-addition increased the viscosities of the slurries, particularly the fine size powder slurries. The slurries with the relatively low-viscosity exhibited lower initial expansion rates compared to the slurries with the relatively high-viscosity. The maximum expansions of the slurries increased from 300 to 350%, when the viscosity increased to 5 Pa s and reached a steady value around 400% between 5 and 50 Pa s. The expansions of the slurries could not be achieved above 50 Pa s since they became too thick to be foamed. The foam samples made from the slurries with 55 and 60 wt% of solid and sintered at 700 and 750 degrees C for 30 min had the average densities between 355 and 530 kg m(-3) and the average compressive strengths between 0.2 and 0.5 MPa. Increasing sintering time to 60 min at 750 degrees C increased the average compressive strength from 0.5 to 1.5 MPa for the foam samples made from the slurry with 60 wt% of solid. These proved that both sintering temperature and time were effective in increasing the compressive strengths of the foamed structures. The thermal conductivities of the sintered foam samples with the densities of 355 and 504 kg m(-3) were measured 0.042 and 0.057 W m(-1) K-1, respectively. (C) 2019 Elsevier Ltd. All rights reserved.Article Citation - WoS: 60Citation - Scopus: 70Foam Glass Processing Using a Polishing Glass Powder Residue(Elsevier Ltd., 2013) Attila, Yiğit; Güden, Mustafa; Taşdemirci, AlperThe foaming behavior of a powder residue/waste of a soda-lime window glass polishing facility was investigated at the temperatures between 700 and 950 °C. The results showed that the foaming of the glass powder started at a characteristic temperature between 670 and 680 °C. The maximum volume expansions of the glass powder and the density of the foams varied between 600% and 750% and 0.206 and 0.378 g cm−3, respectively. The expansion of the studied glass powder residue resulted from the decomposition of the organic compounds on the surfaces of the glass powder particles, derived from an oil-based coolant used in the polishing. The collapse stress of the foams ranged between ∼1 and 4 MPa and the thermal conductivity between 0.048 and 0.079 W K−1 m−1. Both the collapse stress and thermal conductivity increased with increasing the foam density. The foams showed the characteristics of the compression deformation of the open cell brittle foams, which was attributed to the relatively thick cell edges.