Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection

Permanent URI for this collectionhttps://hdl.handle.net/11147/7148

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  • Article
    Citation - WoS: 1
    Citation - Scopus: 1
    Adsorption and Diffusion Characteristics of Lithium on Hydrogenated ?- and Ss-Silicene
    (Beilstein-Institut Zur Forderung der Chemischen Wissenschaften, 2017) İyikanat, Fadıl; Kandemir, Ali; Bacaksız, Cihan; Şahin, Hasan
    Using first-principles density functional theory calculations, we investigate adsorption properties and the diffusion mechanism of a Li atom on hydrogenated single-layer α- and β-silicene on a Ag(111) surface. It is found that a Li atom binds strongly on the surfaces of both α- and β-silicene, and it forms an ionic bond through the transfer of charge from the adsorbed atom to the surface. The binding energies of a Li atom on these surfaces are very similar. However, the diffusion barrier of a Li atom on H-α-Si is much higher than that on H-β-Si. The energy surface calculations show that a Li atom does not prefer to bind in the vicinity of the hydrogenated upper-Si atoms. Strong interaction between Li atoms and hydrogenated silicene phases and low diffusion barriers show that α- and β-silicene are promising platforms for Li-storage applications.
  • Article
    Citation - WoS: 89
    Citation - Scopus: 94
    Effects of Li Substitution in Bi-2223 Superconductors
    (Springer Verlag, 2008) Bilgili, Özlem; Selamet, Yusuf; Kocabaş, Kemal
    The effects of Li substitution on the properties of high temperature superconductor Bi 17Pb 0.3Sr 2C 2Cu 3-x Li x O y were investigated. The samples were prepared by substituting Li (x=0.00-0.20) with changing ratios by a solid state reaction method. The samples were characterized by X-ray diffraction, DC electrical resistivity, AC magnetic susceptibility, and scanning electronic microscopy (SEM). The X-ray diffraction studies were done at room temperature and the lattice constants of the material were determined by indexing all the peaks observed. This study shows that there are two coexisting phases; high-T c (2223) phase and low-T c (2212) phase. The lattice structure of the material belongs to the orthorhombic unit cell. The volume fraction was estimated from the intensities of Bi-(2223) and Bi-(2212) phases. The sample with 20 wt% of added Li showed the higher volume fraction of Bi-(2223) phase formed (81%) compared to the other samples. The DC electrical resistivity of all the samples decreased as the wt% of Li increased. Both the onset critical temperatures T c (onset) and zero electrical resistivity critical temperatures T c (R=0) of the samples were determined from the DC electrical resistivity measurements. The observed value of the onset critical T c (onset) temperature was 110 K agreeing well with the magnetic susceptibility measurements. We obtained T c onset at 112 K from AC magnetic susceptibility measurements. © 2008 Springer Science+Business Media, LLC.