Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article A Quantitative Description of Barite Thermodynamics, Nucleation and Growth for Reactive Transport Modelling(Elsevier, 2024) Dideriksen,K.; Zhen-Wu,B.Y.; Dobberschütz,S.; Rodríguez-Blanco,J.D.; Raahauge,P.J.; Ataman, Evren; Stipp,S.L.S.The regression of available thermodynamic data in the BaSO4–NaCl–H2O system yielded Pitzer ion interaction parameters that accurately describe the activities of aqueous species and mineral solubilities in this system. This thermodynamics description is compared with published Pitzer parameter sets, and combined with a model for the kinetics of barite nucleation and growth, based on classical nucleation theory. Both the thermodynamic and nucleation/growth models have been incorporated into the PHREEQC computer code to facilitate calculation of the extent and consequences of barite formation in natural and engineered systems. Results of geochemical modelling calculations agree adequately with the amount of barite scale thicknesses derived from calliper measurements from an oil well if the effective surface free energy of barite nuclei is assumed to be ∼50 mJ m−2. Better results, however, are achieved using a temperature dependent effective surface free energy. In contrast, calculations performed by ignoring the effects of barite nucleation lead to a substantial overestimation of the amount of scale formed in our modelled systems. The success of our mineral nucleation and growth model to describe scaling in our modelled system suggests this description of precipitation rates can be applied to many other mineral-aqueous fluid systems, in particular where supersaturation is slight and the solids forming have substantial surface free energy. © 2024 Elsevier LtdArticle Citation - WoS: 54Citation - Scopus: 59Orientation Dependent Tensile Properties of a Selective-Laser 316l Stainless Steel(Elsevier, 2021) Güden, Mustafa; Yavaş, Hakan; Tanrıkulu, Ahmet Alptuğ; Taşdemirci, Alper; Akın, Barış; Enser, Samed; Karakuş, Ayberk; Arslan Hamat, BurcuThe effect of specimen inclination angle with respect to building direction on the tensile properties of a selective laser melt 316L alloy was investigated. Tensile test specimens were fabricated with the angles between 0 degrees to 90 degrees at 15 degrees intervals using a rotation scanning. In addition, 316L alloy test specimens were generated in the ANSYS 2020R1 additive module and tensile tested in LS-DYNA in order to determine the effect of residual stresses on the tensile strengths. The microscopic analysis revealed a strong < 110 > fiber texture orientation along the building direction (the loading axis of 0 degrees inclined specimens) and a weak 111 texture or nearly random distribution of directions in the normal to the building direction (tensile loading axis of 90 degrees inclined specimens). The yield and tensile strength increased and ductility decreased with increasing inclination angle. The strength variation with the inclination angle was shown well-fitted with the Tsai-Hill failure criterion. Although, the used numerical models indicated an inclination-dependent residual stress, the difference in the residual stresses was much lower than the difference in the strengths between 0 degrees and 90 degrees inclined specimens. Predictions showed a lower twinning stress in 0 degrees inclined specimens due to < 110 > fiber texture orientation in the tensile axis. The fiber texture resulted in extensive twinning; hence, higher ductility and tension-compression asymmetry in 0 degrees inclined specimens. Based on these results, the variations in the strength and ductility of tested SLM-316L specimens with the inclination angle was ascribed to the variations in the angle between the fiber texture orientation and loading axis.