Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection

Permanent URI for this collectionhttps://hdl.handle.net/11147/7148

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Publisher: search.filters.publisher.ElsevierSubject: search.filters.subject.White light

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  • Article
    Citation - WoS: 8
    Citation - Scopus: 9
    Tuning the Colour of Solution Processed Perylene Tetraester Based Oleds From Yellowish-Green To Greenish-White: a Molecular Engineering Approach
    (Elsevier, 2023) Aksoy, Erkan; Bozkuş, Volkan; Varlıklı, Canan
    Three regioisomericaly pure 1,7-di-ethynyl bridged perylene-3,4,9,10-tetracarboxy tetrabutylesters functionalized with triisopropylsilyl-ethynylen (PTE1), phenyl-ethynylen (PTE2) and tetraphenylsilyl-ethynylen (PTE3) groups were synthesized. Photophysical, thermal, electrochemical, and solution processed electroluminescence (EL) behaviours were investigated in comparison with a basic perylene-3,4,9,10-tetracarboxy tetrabutylester (PTEref) structure. Stepwise π conjugation, allowed tuning the absorption and photoluminescence wavelengths of the PTEs without disturbing the photo, thermal and electrochemical stabilities; ≫10h, >250 °C, and >50 cycles, respectively. Electron mobility of PTE2 is measured to be more than 10-fold of the other PTE derivatives. Individual utilization of PTE derivatives as solid-state emitters in poly(N-vinylcarbazole) (PVK): 2-(4-Biphenylyl)-5-phenyl-1,3,4-oxadiazole (PBD) host matrix produced yellowish-green EL. Benefiting from higher electron mobiliy, PTE2 emitter presented the best device efficiency values with an EL maximum of 535 nm. Whereas dual doping of the synthesized PTEs with PTEref resulted in greenish-white light with increased stability. Although the emitting layer contained no red emitting component, optimization of the dual doping ratio of PTEref:PTE3 produced a colour rendering index value of 76 with Commission Internationale d'Eclairage coordinates of (0.29, 0.37).
  • Article
    Citation - WoS: 14
    Citation - Scopus: 16
    Bodipy-Based Organic Color Conversion Layers for Wleds
    (Elsevier, 2020) Yüce, Hürriyet; Güner, Tuğrul; Dartar, Suay; Kaya, Beraat Umur; Emrullahoğlu, Mustafa; Demir, Mustafa Muammer
    The usage of organic dyes in phosphor conversion layer of WLED is an attractive approach since they have high molar extinction coefficient and photostability. Various types of organic pigments have been employed for this purpose such as BODIPY, perylene diimide, Rhodamine B, pyrene, Nile red, etc. Among those, BODIPY-based organic dyes appear to be promising candidate for white light generation. In this work, for the first time, red and green emitting BODIPY-based organic molecules have been used as colour conversion layer. These molecules were associated with PMMA in DMF solution and the resulting solution was subjected to electrospinning. Colorful electrospun mats were embedded into PDMS matrix and their free-standing PDMS composite films were used as color conversion layers over blue LED to produce white light such that CRI of 95 and CCT of 4200 K was achieved. These values show that BODIPY-based organic molecules containing fiber composites are promising candidates to be used as color conversion layers for white light applications.