Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection

Permanent URI for this collectionhttps://hdl.handle.net/11147/7148

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Publisher: search.filters.publisher.Elsevier Ltd.Subject: search.filters.subject.Crystalline materials

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  • Conference Object
    Citation - WoS: 6
    Citation - Scopus: 9
    Sub-Bandgap Optical Absorption Spectroscopy of Hydrogenated Microcrystalline Silicon Thin Films Prepared Using Hot-Wire Cvd (cat-Cvd) Process
    (Elsevier Ltd., 2006) Göktaş, Oktay; Işık, Nebile; Okur, Salih; Güneş, Mehmet; Carius, Reinhard; Klomfaß, Josef; Finger, Friedhelm
    Hydrogenated microcrystalline silicon (μc-Si:H) thin films with different silane concentration (SC) have been prepared using the HW-CVD technique. Dual beam photoconductivity (DBP), photothermal deflection spectroscopy (PDS), and transmission measurements have been used to investigate the optical properties of the μc-Si:H films. Two different sub-bandgap absorption, α(hν), methods have been applied and analyzed to obtain a better insight into the electronic states involved. A good agreement has been obtained in the absorption spectrum obtained from the PDS and DBP measurements at energies above the bandgap. Differences between PDS and DBP spectra exist below the bandgap energy where DBP spectra always give lower α(hν) values and show a dependence on the SC. For some films, differences exist in the α(hν) spectra when the DBP measurements are carried out through the film and substrate side. In addition, for some films, there remains fringe pattern left on the spectrum after the calculation of the fringe-free absorption spectrum, which indicates structural inhomogeneities present throughout the film.
  • Article
    Citation - WoS: 46
    Citation - Scopus: 48
    Drying of Semicrystalline Polymers: Mathematical Modeling and Experimental Characterization of Poly(vinyl Alcohol) Films
    (Elsevier Ltd., 2004) Wong, Sim-Siong; Alsoy Altınkaya, Sacide; Mallapragada, Surya K.
    A mathematical model was developed to predict the drying mechanism of semicrystalline polymers involving multiple solvents. Since drying of semicrystalline polymers can be accompanied by changes in polymer degree of crystallinity, the model integrates crystallization kinetics and the Vrentas-Duda diffusion model to provide a better understanding of the mechanism. The model considers the effect of external conditions such as temperature, film shrinkage and diffusion and evaporation of multiple solvents during drying. Poly(vinyl alcohol) (PVA)/water/methanol was chosen as a test system. The drying kinetics of PVA films swollen in water and methanol were investigated using gravimetric techniques. The model predicts that higher temperatures, lower film thicknesses and lower methanol to water ratios increase the drying rate. The model predictions were compared with experimental data and showed good agreement.