Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Citation - WoS: 9Citation - Scopus: 10Investigation of Reactive Extraction of Monocarboxylic Acids With Menthol-Based Hydrophobic Deep Eutectic Solvent by Response Surface Methodology(Taylor & Francis Inc, 2023) Yıldız, Esra; Lalikoğlu, Melisa; Aşçı, Yavuz Selim; Sırma Tarım, BurcuThe growing demand for producing organic acids by fermentative techniques has increased the significance of separating carboxylic acids from their fermentation broth with the reactive extraction process. Considering the environmental impacts, deep eutectic solvents can be considered as a potential green alternative for the replacement of volatile organic solvents commonly used in the extraction process. In this study, a new type of green solvent named hydrophobic deep eutectic solvent (HDES) based on decanoic acid as a hydrogen bond acceptor and menthol as a hydrogen bond donor was utilized for the reactive extraction of formic, acetic, and propionic acids from their aqueous solutions. The effect of initial acid concentration, HDES molar ratio, and tri-n-octyl amine (TOA) concentration on extraction efficiency was investigated. Modeling of the reactive extraction process was performed via a response surface methodology with a central composite design. Herein, the effect of the parameters of TOA concentration, HDES molar ratio, and initial acid concentration on the distribution coefficient was investigated. According to the results, it was reported that the most effective parameter on the extraction efficiency (%E) was the amount of extractant. The results of the experimental studies showed that the highest separation efficiency was obtained for 5% initial concentrations of formic, acetic, and propionic acids by using a mixture of 0.5 HDES molar ratio solvent and 1.9 mol/L TOA. The extraction efficiencies of these acids were found to be 88.71, 92.52, and 95.90 with +/- 0.1 standard deviation, respectively.Article Citation - WoS: 56Citation - Scopus: 59Suzuki Cross-Coupling Reaction of Aryl Halides With Arylboronic Acids Catalysed by Pd(ii)-Nay Zeolite(Elsevier Ltd., 2003) Bulut, Hatice; Artok, Levent; Yılmaz, SelahattinPd(II)-exchanged NaY zeolite showed high activity in the Suzuki cross-coupling reactions of aryl bromides and iodides without added ligands. The DMF:water ratio, and the type and amount of base were found to be critical for the efficiency of the reaction. The catalyst is reusable after regeneration.