Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Citation - WoS: 29Citation - Scopus: 40Geothermal Resources for Sustainable Development: a Case Study(Wiley, 2022) Baba, Alper; Chandrasekharam, DornadulaTurkey's primary energy source is fossil fuels, with a contribution of 55%. According to the International Energy Agency forecast, fossil fuels will continue to be the primary energy source for the next decade. The current CO2 emissions from fossil fuel-based energy are 400 Mt. If the present energy usage trend continues, then the emissions will cross 500 Mt by 2030. However, Turkey has large scope to mitigate climate-related issues and follow sustainable development agenda by increasing the share of geothermal energy as a primary energy source mix. The country established a strong geothermal energy program in 1984 by installing a 17 MWe geothermal power plant in Kızıldere and made tremendous progress in this field. Currently, the power generation has crossed 1665 MWe. Turkey has drawn a new road map to enhance its primary energy source mix by developing its radiogenic granites (Enhanced Geothermal Systems) for power generation and carbon dioxide capture programs. This is an emerging technology that is being recommended for Turkey. Currently, France, Australia, and the United Kingdom are surging ahead in implementing Enhanced Geothermal Systems (EGS), and France has established a pilot power plant using EGS and generating 10 MWe. The United Kingdom will be starting its 3 MWe power plant. The hydrothermal source, in combination with Enhanced Geothermal Systems, can contain the annual CO2 emissions to 500 Mt and reduce the per-capita CO2 emissions to 4.5 tons annually. One of the greatest contributions to climate mitigation and sustainable development made by the geothermal industry is the sequestration of CO2 from the Kızıldere geothermal power plant for the manufacturıng of dry ice and use CO2 from the Tuzla geothermal power plant for minimizing scaling. This dry ice technology can be extended to the cement industry to capture 18 billion CO2 being emitted annually from clinker manufacturıng units. The dry ice will be useful in combating forest fires that are common in Turkey. The article discusses the new technological developments that Turkey is adopting to mitigate climate change and achieve sustainable development goals.Article Citation - WoS: 59Citation - Scopus: 67Design and Thermodynamic Analysis of a Novel Methanol, Hydrogen, and Power Trigeneration System Based on Renewable Energy and Flue Gas Carbon Dioxide(Pergamon-Elsevier Science LTD, 2021) Nazerifard, Reza; Khani, Leyla; Mohammadpourfard, Mousa; Mohammadi-Ivatloo, Behnam; Gökçen Akkurt, GüldenIn this paper, a new trigeneration system is proposed to decrease atmospheric carbon dioxide emission and produce methanol, hydrogen, and power. The system is composed of an organic Rankine cycle, a direct methanol fuel cell, a carbon capture unit, a proton exchange membrane electrolyzer, and a methanol synthesis unit. A flue gas stream with a defined composition, solar energy, and the atmospheric air are the system?s inlets. In the design step, special attention is paid to heat and mass integration between different components so that its waste can be lowered as much as possible. Then, mass balance law, energy conservation principle, exergy relations, and auxiliary equations are applied for each subsystem to investigate the system's thermodynamic performance. Also, the effect of changing operating parameters on the performance of each subsystem is studied. The obtained results show that the proposed system has the energy and exergy efficiencies of 66.84% and 55.10%, respectively. Furthermore, 94% of the total exergy destruction rate belongs to the water electrolyzer, while the contribution of the organic Rankine cycle is negligible. The performance of the methanol synthesis reactor depends strongly on its inlet temperature. Maximum equilibrium methanol concentration and carbon dioxide conversion are achieved at the inlet temperature of 210 degrees C. The parametric studies reveal that there is an optimum fuel cell current density in which its produced power density is maximized.Article Citation - WoS: 21Citation - Scopus: 22Role of Ph on Co2 Sequestration in Coal Seams(Elsevier Ltd., 2016) Özdemir, EkremThe effect of acidic or basic pre-treatment on the adsorption capacity of CO2 on coals was investigated. Argonne Premium Pocahontas No. 3, Upper Freeport, Pittsburgh No. 8, Lewiston-Stockton, Blind Canyon, Illinois No. 6, Wyodak, and Beulah-Zap coals were washed in weak solutions of H2SO4 and NaOH to the pH values of 10, 7, and 2, after an initial washing in acidic water. Attempts to treat the Wyodak and Beulah-Zap coals were unsuccessful because the base treatment after the initial acid treatment resulted in a suspension which could be separated neither via filtration through a 45 μm filter nor centrifugation. Equilibration took several days in some cases, although the as-received coal had been ground to 150 μm. Acid washing preferentially removed Ca (calcite) and Mg. Aluminosilicate clays were not notably removed. Iron was removed in significant amounts only after base treatment, possibly after it was converted to hematite. The adsorption capacity of CO2 on the acid treated coals was higher than both the base treated and untreated coals. The difference in adsorption capacities for acid and base treated coals was related to the pore sizes and mineral matter removal from the coals, where the calculated average pore size was higher for acid treated coals than for the base treated coals. It is concluded that the pH decrease due to CO2 dissolution in cleat water is favored in coal seam sequestration, which resulted in an increase in storage capacity of coals.Article Citation - WoS: 100Citation - Scopus: 116The Effect of Char Properties on Gasification Reactivity(Elsevier Ltd., 2014) Duman, Gözde; Uddin, Md Azhar; Yanık, JaleIn this study, CO2 gasification of raw and acid-washed chars obtained from various types of lignocellulosic biomasses (woody and agricultural waste biomasses) was studied under isothermal conditions (850 C) using thermal gravimetric analysis. The effect of surface area and alkali/earth alkali metals on the reactivity of the chars was investigated. The different kinetic models were used to fit with the reactivity data by using least square method. The gasification of chars with higher surface area was found to be faster than that of chars having lower surface area. The acid treatment decreased the overall gasification rate for each raw chars. However, although the AI (alkali index) values of chars obtained from agricultural biomasses had equal or higher than that of woody biomass chars, their initial rates were considerably lower. It was concluded that indigenous alkali metals of chars have a remarkable influence of gasification reactivity but an adequate surface area should be provided to react with CO2.