Master Degree / Yüksek Lisans Tezleri
Permanent URI for this collectionhttps://hdl.handle.net/11147/3008
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Master Thesis Kinetics of Silica Polymerization at Various Conditions(01. Izmir Institute of Technology, 2022) Hasköylü Toker, Öykü Çağ; Demir, Mustafa Muammer; Baba, AlperSilica is the most abundant element on Earth because the Earth's crust is composed mainly of metal silicates. The source of this silica is mainly volcanic rocks, which come to the surface through tectonic activity and are the primary source of heat for geothermal activity. The silica concentration in a geothermal fluid is higher than the solubility limit of natural waters, so scaling of (metal) silicates is often observed in geothermal operations. This situation has become critical for geothermal power plants. Since silicates have an insulating structure, they lead to a reduction in energy efficiency during fluid transport. The formation of silica-rich deposits should be understood to minimize the negative effects of the scaling. Briefly, silicic acid molecules in the reservoir system are condensed, and the monomeric silicic acid molecules bind to each other via covalent bonds. In the course of this reaction, dimers, tetramers and short oligomers are formed, and eventually a large polymeric silica network is formed. In the presence of metals, both the kinetics of polymerization and the structure of the network are inevitably affected. In this study, the presence of kinetic parameters (different salts such as FeCl3, MgCl2, AlCl3 and NaCl), the reaction process, the rate and the activation energy of silica polymerization at different temperatures between 25 and 90 °C were investigated. The yellow silicomolybdate method was used to determine the concentration of monomeric silica. The order of the polymerization reaction was given as 3. The polymerization occurs in the initial phase, in the first 40 minutes, where the activation energy was about 29.52 ± 2.28 kJ/mol and the rate constant was of the order of 4x10-8 mol-2∙L2∙s-1. The results also confirmed that pH has a stronger effect on the kinetics of silica polymerization than temperature. The neutral solution decreases rapidly, while the acidic solution has an induction phase in the first hour of polymerization. Different temperatures did not affect the polymerization rate as much as pH. At 25°C the experiment showed the fastest polymerization, but at 90°C the low concentration changed from the beginning. During all these experiments, no scaling of amorphous silica was observed, only the polymerization of silica.Master Thesis Preparation and Characterization of Serum Albumin Nanoparticles Obtained From Modified Bovine Serum Albumin(01. Izmir Institute of Technology, 2021) Özmen Egesoy, Tuğçe; Akdoğan, Yaşar; Demir, Mustafa MuammerThe serum albumin has been used as a drug nanocarrier for a long time due to its rich drug transportation ability. Here, modified bovine serum albumin (BSA) proteins were obtained by conjugation with ethylenediamine and dopamine molecules, separately. Using these modified proteins, new BSA nanoparticles were obtained by a desolvation method. Native BSA has a net negative charge at the physiological condition. However, ethylenediamine conjugation yields a positive charge on it, and thus produces cationic BSA (cBSA) protein. On the other hand, dopamine functionalization (D-BSA) makes BSA eager to coordinate with transition metals. After preparation of modified proteins (cBSA and D-BSA), their nanoparticles were prepared with desolvation method but using different crosslinking mechanisms. For cBSA NPs preparation, a traditional crosslinking agent of glutaraldehyde was used. However, for D-BSA NPs preparation, Fe(III) ions were added to the system to achieve the stable nanoparticle formation. In order to obtain cBSA NPs, several organic solvents were used as desolvating agents. cBSA NPs with an average size around 200 nm were obtained in a high formation yield (54.8%) only through addition of acetonitrile to the cBSA aqueous solution. Similarly, different desolvating agents were studied to obtain D-BSA NPs. The promising results were obtained upon addition of 1:5 (v/v) of water/acetone mixture. After addition of the desolvating agent, Fe(III) ions were added to the solution to interconnect D-BSA with each other. This connection is pH sensitive therefore albumin nanoparticles were stable at basic pH values but not at acidic pH values. By this way, pH sensitive D-BSA NPs around 300 nm particle sizes were obtained.Master Thesis Development of a New Antiscalant for Minimization of Stibnite Scaling in Geothermal Binary Plants(01. Izmir Institute of Technology, 2021) Karaburun, Emre Mustafa; Baba, Alper; Demir, Mustafa Muammer; Demir, Mustafa Muammer; Baba, AlperDemand for renewable and sustainable energy resources has been increasing in recent years due to the adverse effects of fossil energy resources (gases, oil, coal ect,) on human health and nature. Since geology properties of our country is rich in geothermal energy resources, there is a remarkable increase in plant capacities every year. Geothermal energy is the energy obtained from the fluid, gas, and steam that have been stored in reservoirs by carrying the heat energy accumulated in the rocks in the depths of the earth or surfaced along the discontinuity zones.The increase in the use of geothermal energy and the increase in the capacity of the power plants has also revealed the problem of scaling. The main cause of deposition are the decrease in solubility of minerals by a decrease in pressure and temperature upon pumping the geothermal brine up to the ground. Calcium carbonate, calcium sulphate, metal silicates (Mg, Fe) are the most widely accepted types of scaling. In recent years, antimony and arsenic sulfide scaling have been encountered in volcanic and metamorphic regions. Between these two types of scaling, antimony sulfide is mostly seen in the heat-exchangers and preheaters where the temperature drops suddenly. In this thesis, the antimony sulfide scaling formed in the geothermal power plant was synthesized in an autoclave reactor under specified conditions. Water-soluble polymers nominee for being antiscalants such as Poly (vinyl sulfonic acid), Poly (acrylamide-co-vinyl sulfonic acid), Poly (acrylamide-co-vinyl phosphonic acid), Alginic Acid, Natural antiscalants, Polyacrylic acid, and Polyvinyl alcohol were employed. The results suggest that polymers containing vinyl sulfonic acid and acrylamide likely shows remarkable progress in increasing the concentration of ions in decantate, particularly at low dosages. (≈5 ppm)Master Thesis Fabrication and Characterization of Ceramic Fibers From Preceramic Polymers(Izmir Institute of Technology, 2019) Özmen, Ecem; Ahmetoğlu, Çekdar Vakıf; Demir, Mustafa MuammerCeramic fibers which are classified as oxide and non-oxide fibers are preferred to use in applications which are carried out at high temperature since they have high strength, low thermal expansion, corrosion, and oxidation resistance. Non-oxide fibers are generally produced using preceramic polymers by the spinning method. The production of ceramic materials using preceramic polymers by spinning method is more advantageous than other methods since the production of complex materials could be achieved at lower temperatures. The preceramic polymer family is basically classified as polysiloxane, polysilazane and polycarbosilane. In this thesis, it was aimed to obtain ceramic fiber in the most economical way. In this context, a spinning device was designed and made. Additionally, polysiloxane which is the most economical preceramic polymer was used to produce ceramic fiber. Polysiloxanes were spun by melt spinning. Obtained fibers were cured by different methods. As a result of pyrolysis, 65-130 μm thickness SiOC fibers were achieved.Master Thesis A Comparative Study on the Photocatalytic Activity of Dye-Sensitized and Non-Sensitized Graphene Oxide-Ti̇o2 Composites Under Simulated and Direct Sunlight(01. Izmir Institute of Technology, 2019) İlhan, Hatice; Varlıklı, Canan; Demir, Mustafa MuammerAmine modified graphene oxide (mGO) and TiO2 composite was synthesized by low temperature hydrothermal method. Characterization of the synthesized material was carried out by using X-ray diffraction, X-ray photoelectron spectroscopy, and BET analysis techniques. The films of mGO:TiO2 and formerly synthesized TiO2, N-TiO2, GO-TiO2 and GO:N-TiO2 were fabricated by doctor blade method and employed as photocatalysts for the photodegradation of Rhodamine-B (RhB) dye under simulated (Xe lamb) and direct sun-light. P25 was also used as reference photocatalyst for all of the synthesized ones. Photodegradation of RhB was monitored by UV-Vis spectroscopy. Among all the catalysts, GO:N-TiO2, the composite of GO and N-doped TiO2, presented the best photocatalytic activity and although the activity of mGO:TiO2 was better than the activities of P25 and TiO2, it presented lower degradation rate constant even than that of the N-TiO2. It is proposed that increased abundance of C-C bonds and decreased number of oxygenated functional groups on mGO:TiO2, in addition to the morphological difference between GO (sheet like) and mGO (dot like) has great influence on their photocatalytic activities. Among the GO containing photocatalysts including mGO:TiO2, specific surface area (SSA) and number of RhB molecules per film volume were the lowest and particle size was the highest for mGO:TiO2. Although the number of RhB molecules per film volume was higher in mGO:TiO2 than that of the N-TiO2, it is thought that approximately 2 folds higher SSA of N-TiO2 allowed better photocatalytic performance. Additionally, the films were sensitized with PTE dye to obtain effective catalysts in visible region and reusability of the films were also tested. Degradation rate constants of all fabricated films have increased under both of the irradiation media and no significant change in rate constants were detected after the reusability tests.Master Thesis Fabrication of Colloidal Photonic Crystals Via Langmuir Blodgett Technique and Their Integration of Polymer Matrix(Izmir Institute of Technology, 2019) İnci, Ezgi; Demir, Mustafa Muammer; Varlıklı, CananColloidal films have potential uses in various fields such as photonics, electronics, sensors, membrane filters, and surface devices owing to their unique optical properties. Photonic crystals composed of uniform diameter colloidal silica particles have been arranged in a periodic structure by taking inspiration from nature. The periodic structure of silica particles has physical interaction with light in a visible range. This special interaction is known as structural coloration. The close-packed monolayers and multilayers of colloidal silica particles in large area can be produced by using Langmuir Blodgett method. The integration of these photonic films with transparent polymer matrices having an elastomer feature provides for their use in optical sensor applications. In this thesis, we examined the fabrication of mechano-sensitive nanostructured films based on colloidal particles. Silica colloidal particles were synthesized at different sizes by using Stöber Process. Langmuir-Blodgett deposition was used to create three-layer of photonic crystal films with different particle diameters. For this purpose, various substrates were examined for the Langmuir Blodgett deposition process before starting the coating. The coated silica particles on the glass substrate were then embedded in an elastomeric transparent matrix. The generation of structural coloration after stretching was examined in manufactured elastomer films. In accordance with this purpose, various polymers such as acrylates and siloxanes with elastomer properties have been used. The structural characterization of these composite films and their optical properties were summarized in this thesis.Master Thesis A Novel Approach for Fabrication of Free-Standing Conductive Network: Pedot: Pss Based Bendable Chemo and Photoresistor(Izmir Institute of Technology, 2019) Mutlu, Mustafa Umut; Yıldız, Ümit Hakan; Demir, Mustafa MuammerElectrospinning is a simple and versatile technique for the fabrication of polymeric nanofibrous substrate with high surface to volume ratio. Besides high surface to volume ratio, their dimensional stability and flexibility make it a perfect candidate for conductive network for various sensor applications. Free-Standing conductive network can be fabricated by deposition of PEDOT:PSS or MWCNT through bendable nanofibrous substrate. As a simple example for sensor applications, the moving object has been sensed through the electrostatic interactions between fibers and object. The sensing range has been found to be 1-5 cm above the surface of fabric. By the controlled combination of conductive polymers and electrospun polymer nanofibers effective device miniaturization has been provided without loss of performance. The noncontact motion sensor platform has unique flexibility and light weight holding a potential for wearable sensor technology. For another application as a wearable electronics, the controlled combination of conductive network and light-matter interaction provides opportunities to fabricate photo-resistor exhibits broad band response 400 to 1600 nm that holding promises for ultra-thin sensors used in telecommunication. As a final example, we report the effect of gold and iron oxide nanoparticles on the selectivity and sensitivity of MWCNT or PEDOT:PSS based chemiresistor responsive to VOCs. The interplay between conductive layer by gold and iron oxide nanoparticles resulted a significant conductivity improvement that affecting selectivity which is governed by the interaction between electron-donating VOCs and NP doped conductive layer due to variation in charge carrier densities in conductive layer lattice.Master Thesis Synthesis of Artificial Metal (fe,mg) Silicate Deposits Under High Pressure and Temperature Conditions and Development of Polymeric Inhibitor for Metal Silicate Scaling(Izmir Institute of Technology, 2017) Çelik, Aslı; Demir, Mustafa MuammerTurkey has to import energy from other countries, because of having not enough sources. Geothermal energy is one of the renewable energy that can be readily founded in Turkey. At the core of the Earth by definition, the high temperature and pressure cause some rock to melt, creating magma convection upward since it is lighter than the solid rock. The magma heats rock and water in the crust. Tuzla geothermal field is the study area and there are NaCl, Mg ,Fe,Si , Ca and Zn metals and CO2 (g) in brine. While geothermal fluids are pumped from down to top the temperature and pressure decreased and CO2 is released. So,the pH level increases and causes silicate, sulfonate and calcide scaling problems. Moreover, silica is reacted with metal oxides to more stable scales. The production of electricity decreases and while cleaning and the system is shot-down. The present method of strong acid cleaning, harms components as well as create potential risk for the health of employees. In this project, artificial metal-silicate deposit was synthesized with close composition and morphology to natural scale, and potential inhibitors were synthesized and tested. Firstly, synthesizing of artificial deposit is necessary in the laboratory setting. For this purpose, we can simulate the course of temperature and pressure values will be used in autoclave reactor system. Secondly, the functional groups that exhibit inhibitory feature(s) have the potential of macromolecules (Poly (vinyl sulfonic acid), Poly (vinyl phophonic acid), Polyacrylamide and their copolymers and tercopolymer) were tested.Master Thesis Field Emission Electron Source Based on Silicon Carbide Nanopillars(Izmir Institute of Technology, 2017) Yeşilpınar, Damla; Çelebi, Cem; Demir, Mustafa MuammerIn this thesis work, I studied the fabrication and the field emission characteristics of SiC nanopillar based electron field emitters. The first objective of this thesis was to fabricate a large area nanopillar array on bulk 6H-SiC substrate. Accordingly, a nanosphere assisted technique was developed to create a conventional Cr/Ni hard mask to acquire desired etch mask pattern on the C-terminated face of 6H-SiC. The nanopillars were then fabricated by ICP-RIE. Two sets of nanopillars with different aspect ratios and geometries were fabricated for two different ICP-RIE durations. 1 min long etch resulted in nanopillar arrays with blunt tip apex and an aspect ratio of 3.4, where 2 min long etch produced nanopillar arrays with an aspect ratio of 4.9 and a sharp tip apex with an estimated radius of curvature of about 18 nm. As the second objective; the electron field emission characteristics of the produced nanopillars with two different aspect ratios and geometries were investigated and the obtained results were compared with each other. We found that the nanopillars with sharp tip apex produced field emission currents up to 240 μA/cm2 under 17.4 V/μm applied electric field, as the nanopillars with blunt tip apex produced an emission current of 70 μA/cm2. The threshold electric fields were found to be 9.1 V/μm and 7.2 V/μm for the nanopillars with blunt and sharp tip apex, respectively. Time dependent stability measurements yielded stable electron emission without any abrupt change in the respective current levels of both samples.Master Thesis Glucose Biosensor Applicatiın of Electrospun Polyvinyl Alacohol (pva) Fibers(Izmir Institute of Technology, 2016) Berber, Emine; Demir, Mustafa Muammer; Yıldız, Ümit HakanElectrospinning is a simple and versatile technique for the fabrication of polymeric nanofibrous membranes with high surface to volume ratio. Besides the large surface area of the fibrous membranes, their dimensional stability and flexibility allows the immobilization of biomolecules on to the nanofiber surfaces. Therefore, electrospun nanofibers have been extensively used in enzyme electrodes. This thesis examines the glucose biosensor application of electrospun polyvinyl alcohol (PVA) nanofibers – carbon nanotube (CNT) nanocomposite membranes. By manipulating the structural design and the composition of the nanocomposite membranes, glucose sensing efficiency of the five different enzyme electrodes a) Glucose oxidase (GOx) immobilized PVA electrospun electrode, b) Glucose oxidase (GOx) immobilized PVA electrospun electrode containing multi-walled carbon nanotube (MWCNT), c) Glucose oxidase (GOx) immobilized PVA electrospun electrode containing Poly(diallyldimethylammonium chloride) (PDDA) functionalized multi-walled carbon nanotube (MWCNT) d) Glucose oxidase (GOx) immobilized PVA electrospun electrode containing Poly(diallyldimethylammonium chloride) (PDDA) functionalized single-walled carbon nanotube (SWCNT), e) Interfacially cross-linked PVA electrospun electrode containing Poly(diallyldimethylammonium chloride) (PDDA) functionalized multi-walled carbon nanotube (MWCNT) were comperatively studied. PVA electrospun nanofibers were fabricated by using electrospinning technique. Morphology and average diameter of the fibers were characterized by using Scanning Electron Microscopy (SEM). Average diameter for the neat PVA electrospun fibers were 115 nm. Carbon nanotubes were oxidatively functionalized by acid treatment and addition of functional groups after acid treatment was proved by using Raman Spectroscopy. Glucose sensing activities of the electrodes were amperometrically measured at an applied voltage -0.5 V (vs. Ag/AgCl) in 0.1M phosphate buffer solution (PBS pH 7). Glucose detection sensitivies of the electrodes were calculated as 19.6, 27.7, 67.5, 44.4, 4.0 μA mM-1cm-2 respectively.
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