Master Degree / Yüksek Lisans Tezleri
Permanent URI for this collectionhttps://hdl.handle.net/11147/3008
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Master Thesis Effects of Oxygenation in Stratified Reservoirs on Concetrations of Manganese and Iron in Bottom Sediments(Izmir Institute of Technology, 2019) Vural Aydın, Buse; Elçi, Şebnem; Ökten, Hatice Eser; Elçi, Şebnem; Ökten, Hatice Eser; 03.07. Department of Environmental Engineering; 03.03. Department of Civil Engineering; 03. Faculty of Engineering; 01. Izmir Institute of TechnologyIron and manganese accumulation in drinking water reservoirs is a challenging issue and should be controlled in order to prevent their adverse effects on human health. Accumulation of these elements not only clogs pipeline systems but also causes stains on fixtures and laundry. In addition, high concentrations of iron and manganese may lead to various health problems when ingested. This study focuses on the release mechanism of iron and manganese from sediments to water column and investigates methods to prevent this release. Effects of lack of hypolimnetic aeration, acid-base condition and thermal stratification on iron and manganese concentrations at water column were investigated through laboratory experiments. Experiments showed that total iron (Fe) and ferrous iron (Fe2+) concentrations in the water column decreased gradually following aeration in hypoxia conditions. A similar behavior was also observed for manganese concentrations. However, the concentration of dissolved manganese (Mn) in alkaline water condition is observed to be less than the aerated water case. This is an indication that iron and manganese react differently under different acidity of water in consideration.Master Thesis Exposure and Risk Assessment for Arsenic in Simav Plain by Ingestion of Edible Crops(Izmir Institute of Technology, 2017) Terzi, Begüm; Sofuoğlu, Sait Cemil; Gündüz, Orhan; Sofuoğlu, Sait Cemil; Gündüz, Orhan; 03.07. Department of Environmental Engineering; 03. Faculty of Engineering; 01. Izmir Institute of TechnologyIngestion is the main route of exposure to arsenic. The pathways of concern are ingestion of drinking water and arsenic-accumulating plants. Simav plain has been shown to have the natural arsenic conamination of waters and soil. However, foodstuff was not made a subject of investigation. In this study, arsenic exposure via ingestion of edible plants cultivated in Simav plain was investigated based on the modeling of the measured soil concentrations and data collected from the literature, which were for bioconcentration factors, plant consumption rates, background arsenic concentrations in plants, plant root depths, and body weights. Eighteen plant species, which are bean, broccoli, cabbage, carrot, cauliflower, corn, cucumber, eggplant, garlic, lettuce, okra, onion, potato, radish, spinach, sunflower seed, tomato, and wheat were studied. Chronic-toxic and carcinogenic risks associated with the consumption contaminated foodstuff were assessed with two approaches: scenario based point estimates (deterministic approach) and population based estimates (probabilistic approach). Monte Carlo simulation was used to determine chronic-toxic and carcinogenic risks via ingestion of edible plants probabilistically. Wheat was found as the plant variety with the highest non-carcinogenic and carcinogenic risks which was followed by potato, tomato, cucumber, corn, cabbage, eggplant, and onion. Non-carcinogenic risk levels for broccoli, cauliflower, garlic, and radish were below the threshold level. However, their carcinogenic risk levels were considerable. The risk levels estimated in this study are exceptionally high, indicating consumption of the plants cultivated in Simav may pose significant chronic-toxic and carcinogenic health risks.Master Thesis Solid Phase Extraction of Ibuprofen in Waters With Molecularly Imprinted Polymers Prior To Hplc-Dad Determination(İzmir Institute of Technology, 2016) Ölçer, Yekta Arya; Eroğlu, Ahmet Emin; Eroğlu, Ahmet Emin; 04.01. Department of Chemistry; 04. Faculty of Science; 01. Izmir Institute of TechnologyEndocrine disrupting compounds (EDCs) attract great attention worldwide due to their undesired effects on human health. Ibuprofen, an example of endocrine disrupters, is a nonsteroidal anti-inflammatory drug (NSAID). In this study, highly selective molecularly imprinted polymers (MIPs) with different morphologies (as monolith and microspherical beads) were synthesized by bulk and precipitation polymerization strategies. MIPs were prepared by using acetonitrile as porogen, methacrylic acid (MAA) as monomer, trimethylolpropane trimethacrylate (TRIM) as crosslinker and the analyte, ibuprofen, as the template. MIPs revealed higher affinity to the template molecule as compared with non-imprinted polymers (NIPs). The MIP prepared by precipitation polymerization was decided to be used as the primary solid phase extraction (SPE) sorbent due to its higher binding capacity towards ibuprofen compared to the MIP prepared by bulk polymerization. Selectivity of MIP to ibuprofen was examined in the presence of structurally related compounds. In this study, a molecular imprinting solid phase extraction (MISPE) methodology was proposed for determination of ibuprofen prior to HPLC-DAD analysis. For this purpose, critical experimental parameters of MISPE method were optimized and determined as follows; solution pH of 8.0, sorbent amount of 25.0 mg for 10.0 mL of 1.0 mgL-1 working solution, sorption time of 30 min and MeOH:H2O (acetic acid, pH 3.0) ratio of 80:20 as desorption solution. The accuracy of the proposed methodology was verified with spike recovery tests for tap and drinking waters and overall recovery was found as 97.4 (± 0.3) for n=3.