Master Degree / Yüksek Lisans Tezleri
Permanent URI for this collectionhttps://hdl.handle.net/11147/3008
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Master Thesis Preparation and Characterization of Calcite (caco3) Particulate Filled Thermoplastic Composites(Izmir Institute of Technology, 2014) Kızıltepe, Esin; Tanoğlu, MetinNano-sized particle filled polymer composites have been received great attention of researchers and industrial institutions in recent years due to their unique properties, save as high mechanical strength, thermal and solvent resistance as compared to traditional composite materials. In this study, calcium carbonate (CaCO3) filled polypropylene (PP) and Polyethylene (PE) composite blends were prepared using a co-rotational twin screw extruder with a calcite particle content varying from 0 to 30 wt. % . Tensile and three-point bending test coupons were prepared by injection moulding using the extruded composite blends. The effects of calcite reinforcement (with and without stearic acid treatment) on the microstructural, thermal and mechanical properties of neat PP and PE were investigated. Nano-CaCO3 powders were characterized by means of Scanning Electron Microscopy (SEM) and X-Ray Diffraction (XRD). The PE and PP were characterized via differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). Analytical results were compared with the experimental results.Master Thesis Joining and Interfacial Properties of Aluminum/Glass Fiber Reinforced Polypropylene Sandwich Composites(Izmir Institute of Technology, 2009) Guruşçu, Aslı; Tanoğlu, MetinThe joining of separate components using a suitable technique is a critical step in the manufacture of composite structures. For good property performance of aluminum/glass fiber reinforced polypropylene (Al/GFPP) laminates, one of the most important problems is to obtain good adhesive bond strength.In the present study, Al/GFPP laminates have been manufactured with various surface pretreatment techniques. Adhesion at the composite/metal interface has been achieved by surface pretreatment of Al with amino based silane coupling agent, incorporation of polyolefin based adhesive film and modification with PP based film containing 20 wt. % a maleic anhydride modified polypropylene (PP-g-MA). The mechanical properties shear, peel and bending strength of the adhesively bonded Al/GFPP laminates were investigated to evaluate the effects of those various surface treatments. In addition, peel strengths of Al foam/GFPP laminates with various surface treatments were measured. The fracture surfaces have been examined by scanning electron microscope (SEM). Results showed that the adhesion of the laminated Al/GFPP systems were improved by treatment of aluminum surfaces with amino-based silane coupling agent. Based on peel and bending strength results, Al/GFPP laminates with incorporation of polyolefin based adhesive films exhibited significant increase on the adhesive behaviour. Modification of Al/GFPP interfaces with PP-g-MA layer leads to highest improvement on the adhesion properties.
