Master Degree / Yüksek Lisans Tezleri
Permanent URI for this collectionhttps://hdl.handle.net/11147/3008
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Master Thesis Investigation of Electrochemical Co2 Capture System(Izmir Institute of Technology, 2022) Güler, Cansu; Uzunlar, ErdalFossil fuels have been used as a primary energy source for many years to meet the increasing energy demand since the industrial revolution. Fossil fuels are an important source of carbon that triggers global warming and climate change. To reduce the accumulation of carbon dioxide in the atmosphere, carbon capture has become more important. Conventional carbon capture technology is a thermally regenerated amine-based capture based on monoethanolamine (MEA). In this process, carbon dioxide is captured in an absorption column with the amine solution, and CO2-amine solution is sent to the stripping column, where the solution is heated to release the captured CO2 and regenerate the amine solution. However, an important disadvantage of this process is that it requires high energy for the CO2 release step. Recently, electrochemical CO2 capture process is proposed in the literature to decrease the energy requirement. The aim of this study is to investigate the electrochemical CO2 capture process using homopiperazine (HPZ). Unlike the conventional CO2 capture process, the CO2 release step is performed using an electrochemical cell. In the anode compartment of this electrochemical cell, the formed CO2-amine complexes are converted into amine-metal complexes from which the CO2 is released. The amine-metal complexes are then sent to the cathode, where the complex decomposes and metal deposition occurs. Laboratory-scale studies of the electrochemical capture process using MEA and HPZ as solvent were carried out. In the obtained results, it was found that HPZ has higher CO2 capture capacity and CO2 release rate than MEA and a similar CO2 absorption rate as MEA. In addition, UV-Vis spectra analyses showed that the reaction rate at the anode was much higher than the reaction rate at the cathode for both amines.Master Thesis Design of a Physical Human-Robot Interface for Lifting Operations(Izmir Institute of Technology, 2022) Nalbant, Uğur; Dede, Mehmet İsmet Can; Dede, Mehmet İsmet CanIn this thesis, the design of a physical human-robot interface for lifting operations which controls the vertical movement of the payload is studied. The new design uses a low stiffness type of admittance control method that is aimed at reducing the surface impact force of the payload and providing better control for the operator while having the option of high stiffness admittance control. To reduce impact forces by using low stiffness admittance control, a sliding handle mechanism is introduced into the system. This type of design includes springs and bearings to create a low stiffness admittance-type user interface. Mathematical models are developed to calculate spring forces and mechanical strength. According to design requirements and mathematical calculations, the prototype is designed and manufactured. In the tests, it is seen that the spring forces are low, and the sliding motion of the handle is not consistent over different displacements. According to the test results, revisions are done, and the final design of the system is developed. In the final tests, it is seen that the new design of the physical human-robot interface performance is improved and the problem of the sliding motion of the handle is solved. Also, the surface impact forces are reduced with low stiffness admittance control. Another improvement of the new design is the ability to control the payload with high stiffness admittance control if the user chooses it. With this option, users can control the payload by touching the payload. Having both types of control methods, the user can choose which type of control method to use to handle payload in the factory.Master Thesis Experimental Investigation and Computational Fluid Dynamics (cfd) Analysis of Geothermal Sourced Hot Air Drying(Izmir Institute of Technology, 2022) Keleş, Nazlı; Gökçen Akkurt, Gülden; Helvacı, Hüseyin UtkuDrying is one of the oldest methods used to increase the product's shelf life and reduce transportation costs, consisting of heat and mass transfer between the product and the surrounding environment. One of the most common drying methods is hot air drying. The most critical parameters in hot air drying processes are drying air temperature, air velocity and relative humidity. Renewable energy resources can be used as heat/electricity in drying processes. Geothermal energy resources are highly suitable for hot air drying with their temperature compatibility and reliability. The geothermal resources in Turkey have a high potential for hot air drying. This Thesis examines tomato slices' quality parameters at different drying air temperatures and velocities. A cabinet-type geothermal sourced hot air dryer is installed in the Yenikale Heat Center of the Balcova-Narlidere Geothermal District Heating System in Izmir-Turkiye. Drying experiments are carried out at 40-60-80°C air temperatures and 0.5-1.5 m/s air velocities to examine their effects on drying kinetics and quality of dried tomatoes, such as pH, color, and moisture. With the help of the data obtained, drying time, drying rate, moisture rate, and effective diffusion coefficients are determined, and dimensionless moisture rate is modeled using thin layer models. Also, energy and exergy analyses are made for each experiment. Finally, experimental and simulation results are compared by using CFD to perform experimental design. The simulations created by using CFD are obtained in a much shorter time and more accurately since all materials used for the experiment are idealized.Master Thesis Statistical Analysis of the Effect of Meteorological Parameters on Pm10(Izmir Institute of Technology, 2022) Birim, Necmiye Gülin; Gökçen Akkurt, Gülden; Turhan, CihanAir pollution is a serious threat where the pollutants in the air in solid, liquid and gaseous states reach levels that would harm the natural balance of the environment and the lives of vital organisms. Especially in industrialized cities, in addition to the effects of urbanization, physical environment characteristics may also play a role in the formation of environmental problems. Therefore, it is of high importance to understand the characteristics of the natural environment in the studies on air quality, in order for urban spaces to be livable areas. In this study, the correlations between PM10 pollutant data and certain meteorological parameters that were obtained from 3 stations in İzmir province were statistically evaluated. PM10 data was studied according to pre-pandemic, mid-pandemic and post-pandemic periods between 2017–2021. Meteorological data was gathered for a twelve-month period between February 2021 and January 2022 and its effect on PM10 data for the same period was analyzed. In the statistical analysis that was performed via Minitab software, hourly average data of PM10 was the dependent variable; temperature, relative humidity, and wind speed and direction were the independent variables. In the analysis that Pairwise Pearson Correlation Coefficient (r) was used, the most significant correlation was found to be between relative humidity and wind speed.Master Thesis Numerical and Experimental Investigation of an Electric Vehicle Battery Module Thermal Management System(Izmir Institute of Technology, 2022) Gediksiz, Çağlar; Çetkin, ErdalToday, electric vehicles play an essential role in preventing pollution from fossil sources. Therefore, it is vital to develop battery technology in electric vehicles. The biggest problem experienced is the thermal runaways, which is a phenomenon that may cause burning and explosions following the decrease in battery capacities. The thermal runaway problem can be solved by using the thermal management system to keep the temperature range under control. In this study, a 6.7 kWh battery pack was produced. Battery pack operation consists of two parts, mechanical and thermal. In the mechanical part, battery pack assembly and drop tests, one of the mechanical tests, were carried out. At the end of the battery pack assembly, voltage measurements were made, and the accuracy of the assembly was demonstrated. Besides, a numerical and experimental study supported drop tests. As a result of this study, the battery case did not show permanent deformation (2.529x 108 N/m2) as suggested in the numerical experiments (1.263x 108 N/m2). Discharge characteristics and battery module model were discussed in the thermal management part. The information in the literature confirmed the discharge characteristic. The gap between the battery cells reached its most efficient value at 8 mm. In the developed battery module, thermal management was attempted using a heat plate and a cooling pipe. According to the numerical results, the battery module reaches 311.37K at 10C discharge. In the experimental process, the battery pack was charged with 15 amps and discharged with 30 amps. Moreover, the temperature values reached a maximum of 31 degrees. In the experiment on electric vehicles, a maximum discharge level of 255 A was observed. In this experiment, the battery pack reached a maximum of 36 degrees.Master Thesis Coupled Wake and Blockage Modelling for a Wind Farm(Izmir Institute of Technology, 2022) Çam, Janset Betül; Bingöl, FerhatOne of the significant reasons for the power loss in wind farms is the wake effect. Therefore, the wake effect is crucial for designing a wind farm. However, only wake modeling is not sufficient to explain power losses. Wake is the turbulent, complex, and relatively weak flow behind the wind turbine. The wake effect is not required for the front row turbines in wind farms, and the wake model cannot be applied. It is assumed that the wind farm directly encounters the free stream wind speed. However, the blockage effect, also known as the induction zone effect, is observed at the front of the wind turbines. Due to this effect, the wind farm encounters a lower wind speed than the free-stream wind speed. This situation reduces the accuracy of the Annual Energy Production (AEP) calculation in wind farms. The motivation of this study is to obtain an improved coupled wake and blockage model that converges to the accurate SCADA data of a wind farm more than the wakeonly or blockage-only models. This study applies seven wake and six blockage models to the wind farm. The similarities and differences between the coupled models and the wind farm SCADA data and their reasons are discussed.Master Thesis Investigation of Applicability of Uv-Light Emitting Diodes (uv-Leds) as an Alternative Technology in Pasteurization of Cold-Pressed and Newly Formulated Mixed Beverage(Izmir Institute of Technology, 2022) Baykuş, Gökçen; Ünlütürk, SevcanThe aims of this thesis were to evaluate the cold pressing technique for juice extraction and to evaluate whether the cold pressed mixed beverage can be pasteurized with ultraviolet light emitting diodes (UV-LEDs) using E. coli K12 as the target microorganism. Initially, the physical, chemical and optical properties of cold pressed juice (CPJ) were compared with juice extracted by centrifugal juicer (CDJ). The CPJ was then exposed to UV-LEDs simultaneously and sequentially and the microbial inactivation was evaluated. Besides, barrier technologies have been tried to increase the UV-LED inactivation effect. It has been found that the juice yield performance of the cold pressing technique is better than the centrifuge method. The total phenolic content of the CDJ and CPJ was 922 ± 0.01 mg GAE/L, and 867.25 ± 0.01 mg GAE/L, respectively. However, DPPH radical scavenging activity of both beverages were not significantly different. The use of UV-LEDs in simultaneous or sequential mode could not achieve a 5-log reduction in pertinent microorganism required as part of HACCP mandated by US Federal regulations for juice issued by the Food and Drug Administration (FDA). However, filtration and addition of ginger juice revealed that the inactivation efficiency of UV-LEDs increased in highly turbid juice reaching to 3.65 ± 0.218 log10 CFU/ml. In conclusion, this study showed that UV-LEDs used simultaneously at different wavelengths may have the potential to be used in turbid cold press juice pasteurization when combined with different barrier technologies.Master Thesis Dynamics and Bioinformatis of Microbial Spoilage Ecology of Kefir(Izmir Institute of Technology, 2022) Memon, Ayşe; Baysal, Ayşe Handan; Sezgin, EfeIn this study, it was aimed to characterize the microbiological properties, bacterial composition, and microbial stability of 5 different commercial milk kefir beverage products during refrigerated storage. In order to determine the microbiological load and compositions, total mesophilic aerobic bacteria, yeast and molds, lactic acid bacteria, Lactobacilli, Lactococci, total coliforms, and E.coli were investigated by cultural conventional analysis for milk kefir beverages. According to the obtained data, microbiological and hygienic characteristics of the samples were found acceptable. The bacterial load of the kefir beverage samples ranged between 7.086 and 8.794 log10 cfu.ml-1 for viable total aerobic mesophilic bacteria (TAMB), 6.792 and 8.382 og10 cfu.ml-1 for lactic bacteria (LAB), <10 and 6.322 log10 cfu.ml-1for Lactobacillus, 5.857 and 8.146 log10 cfu.ml-1 Lactococcus, 5.176 and 7.218 log10 cfu.ml-1 for yeasts, negative for molds, coliform bacteria and negative for E. coli. Principal component analysis (PCA) of the compounds separated the kefir beverages according to the storage time and kefir brands. Strong relationship were found between storage time and PC1 and between kefir brands and PC2. To date, information on microbial properties, bacterial composition, and constancy of commercial kefir is scant, and to the best of our knowledge, this is the first research to contribute information on kefir beverages in microbial properties, bacterial composition, and their stability during refrigerated storage by evaluating Fourier Transform Infrared Spectroscopy (FTIR) spectra analysis and Bioinformatics besides cultural conventional analysis.Master Thesis Development of Co-Evolution Tracker Tool for Software With Acceptance Criteria(Izmir Institute of Technology, 2022) Yalçın, Ali Görkem; Tuğlular, Tuğkan; Tuğlular, TuğkanTesting is a vital part of achieving good-quality software. Deploying untested code can cause system crashes and unexpected behavior. In order to reduce these problems, testing must be prioritized. However, once test suites are created, they should not remain static throughout the software updates. Since whenever software gets updated, new functionalities are added or existing functionalities are changed, so whenever the application is updated, test suites must be updated along with the software. If the old test suites are used with the new updates, unexpected testing results can occur. In order to repair test cases in the process of software evolution, analyzing real-world projects’ software and test case evolution is an important prerequisite. Software repositories contain valuable information about the software systems. Having access to older versions and by differentiating adjacent versions’ test and production code changes can provide information about the evolution process of the software. This thesis concentrates on the development of a tool that is used for the analysis of 21 real-world projects in the terms of co-evolution of both software and its test suites. Related projects are retrieved from repositories and filtered according to this study’s needs, then for each project's every update is analyzed, and graphs and analysis related to the co-evolution process are created.Master Thesis A Computational Chemistry Study on the Interactions Between Hydrogenated Borophene and Amino Acids(Izmir Institute of Technology, 2022) Bozkurt, Yağmur; Elmacı Irmak, NuranIn this work, the adsorption behavior of hydrogenated borophene to amino acids was examined to provide its geometric and electronic structures information and to check whether hydrogenated borophenes’ potential can be used in new biosensor devices for amino acids or not. In the aspect of this thesis adsorption of 4 amino acids from different types of amino acid classes (acidic, basic, nonpolar, and polar) on hydrogenated borophene surfaces has been studied by computational chemistry methods. Electronic and geometric structures of B36H6 and its complexes with glycine, tyrosine, aspartic acid, and histidine were obtained by DFT calculations at B3LYP-D2 / 6-311G** level of theory. In the energetically most favorable configurations of complexes, amino acids approaching from the bottom of the B36H6 surface with a horizontal orientation (exception for histidine complexes) of amino acid was observed. The most reactive parts of the B36 structure (edges) have been stabilized with hydrogenation, the whole boron cluster became more stable and adsorption ability has fallen. It was found that hydrogenated borophene has indistinguishable electronic responses for each the amino acids studied in this thesis since the complexes exhibited nearly the same band gap. Thus, hydrogenated borophene shows no sensor ability to GLY, TYR, ASP, and HIS.