Master Degree / Yüksek Lisans Tezleri
Permanent URI for this collectionhttps://hdl.handle.net/11147/3008
Browse
3 results
Search Results
Master Thesis Joining and Interfacial Properties of Aluminum/Glass Fiber Reinforced Polypropylene Sandwich Composites(Izmir Institute of Technology, 2009) Guruşçu, Aslı; Tanoğlu, Metin; Tanoğlu, Metin; 03.10. Department of Mechanical Engineering; 03. Faculty of Engineering; 01. Izmir Institute of TechnologyThe joining of separate components using a suitable technique is a critical step in the manufacture of composite structures. For good property performance of aluminum/glass fiber reinforced polypropylene (Al/GFPP) laminates, one of the most important problems is to obtain good adhesive bond strength.In the present study, Al/GFPP laminates have been manufactured with various surface pretreatment techniques. Adhesion at the composite/metal interface has been achieved by surface pretreatment of Al with amino based silane coupling agent, incorporation of polyolefin based adhesive film and modification with PP based film containing 20 wt. % a maleic anhydride modified polypropylene (PP-g-MA). The mechanical properties shear, peel and bending strength of the adhesively bonded Al/GFPP laminates were investigated to evaluate the effects of those various surface treatments. In addition, peel strengths of Al foam/GFPP laminates with various surface treatments were measured. The fracture surfaces have been examined by scanning electron microscope (SEM). Results showed that the adhesion of the laminated Al/GFPP systems were improved by treatment of aluminum surfaces with amino-based silane coupling agent. Based on peel and bending strength results, Al/GFPP laminates with incorporation of polyolefin based adhesive films exhibited significant increase on the adhesive behaviour. Modification of Al/GFPP interfaces with PP-g-MA layer leads to highest improvement on the adhesion properties.Master Thesis Preparation and Characterization of Corn Zein Nanocomposite Coated Polypropylene Films for Food Packaging Applications(Izmir Institute of Technology, 2010) Özçalık, Onur; Tıhmınlıoğlu, Funda; Tıhmınlıoğlu, Funda; 03.02. Department of Chemical Engineering; 03. Faculty of Engineering; 01. Izmir Institute of TechnologyFeasibility of prepared novel corn zein nanocomposite (CZNC) coated polypropylene (PP) film (CZNC-PP) structures for food packaging applications was investigated. Excellent barrier properties of corn zein nanocomposites were successfully combined with mechanically strong PP as an eco-friendly promising alternative to conventional barrier packaging systems. In this study, the effect of nano-sized layered silicate amount, type and processing of CZNC layer on the barrier, mechanical, optical and surface properties of the CZNC-PP films were investigated. Incorporation of organomodified montmorillonite (OMMT) by solution intercalation into zein coating matrix improved barrier and mechanical properties of PP films. The properties of single CZNC layers and interactions between layered silicates and zein matrix were also investigated. Fine delamination of OMMT in zein coating was found to be responsible for the improvements in oxygen and water vapor barrier of single corn zein layers due to more tortuous path formed for permeation of oxygen and water vapor. Prepared CZNC-PP films achieved nearly 4 times reduced oxygen permeability while WVP of the films were reduced by 30% with 5 wt% OMMT content in 5.9 m corn zein coating. Meanwhile, improvements were less significant for unmodified nanoclay loadings due to the incompatibility between unmodified MMT and corn zein. Hydrophobicity of CZNC surface increased with increasing OMMT loading in accordance with WVP results. Permeation data was fitted to various phenomenological models predicting the permeability of polymer nanocomposites as a function of clay concentration and aspect ratio of nanoplatelets. While significant improvements in mechanical properties including doubled elastic modulus and 75% higher yield strength of PP films were obtained, incorporation of OMMT in CZNC layer did not change the color of CZNC-PP films significantly.Master Thesis Polyropylene - natural zeolite composite films(01. Izmir Institute of Technology, 1999) Özmıhçı, Filiz; Balköse, Devrim; Özmıhçı, Filiz; Balköse, Devrim; 03.02. Department of Chemical Engineering; 03. Faculty of Engineering; 01. Izmir Institute of TechnologyIn this project, preparation and characterization of polypropylene natural zeolite composites were studied. Three different series of preparation methods were performed, hot press, microscope slide, and extrusion. The composites are ranged between 0-10 wt%, 0-50 wt%, and 0-6 wt% zeolites, for hot press, microscope slide, and extrusion respectively.Polymer matrix composites are materials which contain polymers as matrix materials surrounding very small reinforcing fibers or fillers. Polymeric composites have great potential from a manufacturing standpoint and show advantages. Such as they are inexpensive, derive from natural sources, present lower density than mineral fillers, and increases the mechanical properties of the final product.In this research polypropylene was used as a matrix material and natural zeolite as a filler. Natural zeolite particles were modified with polyethylene glycol to break agglomerates and make a homogenous dispersion of natural zeolite in polypropylene matrix. These composites were characterized by using differential scanning calorimetry, thermal gravimetric analyzer, infrared spectrophotometer, optical microscopy, mechanical testing and by density measurement device. It has been found that, branched shaped air pockets existed in hot pressed and extruded composites. This causes low mechanical strength, and the densities of these films also indicate the presence of voids in the composite.