Master Degree / Yüksek Lisans Tezleri

Permanent URI for this collectionhttps://hdl.handle.net/11147/3008

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Department: search.filters.department.Thesis (Master)--İzmir Institute of Technology, Materials Science and EngineeringSubject: search.filters.subject.Porous materials

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  • Master Thesis
    Modelling of Pore Formation in Porous Materials
    (Izmir Institute of Technology, 2017) Ülker, Sevkan; Güden, Mustafa; Akdoğan, Yaşar; Güden, Mustafa; Akdoğan, Yaşar; 03.09. Department of Materials Science and Engineering; 03.10. Department of Mechanical Engineering; 03. Faculty of Engineering; 01. Izmir Institute of Technology
    The purpose of this thesis is to model the expansion behavior of aqueous slurries. Foamed or cellular material made using such method is known, especially in the concrete industry. What appears to be lacking in the literature is the knowledge of pore formation and pore growth in inorganic particles based on aqueous slurry systems that result in the formation of cellular structures. The motivation of this study is to provide a scientific view in identifying and explaining the critical parameters that govern the pore growth and expansion of such slurry based systems. Bubble growth and pore formation are also studied experimentally. Experimental results are used to compare with the empirical study conducted by Kanehira at al. (Kanehira, et al., 2013), and mathematical modeling of pore formation plotted with Wolfram Mathematica software. Experimental procedure consists of three types of aluminum and calcium ratios which provide information about bubble growth and pore formation. These types are 50% aluminum – 50% calcium hydroxide (50/50), 70% aluminum – 30% calcium hydroxide (70/30), and 80% aluminum – 20% calcium hydroxide (80/20). According to the results of studies, mathematical modeling system consists of the pressure difference between the inside and outside of a spherical bubble as the driving force for defining growth. While aluminum ratio increases, bubble growth rate decreases due to release of hydrogen gases which affect bubble expansion phenomenon. In the experimental and mathematical modeling, 50/50 ratio has maximum bubble growth rate compared to 70/30 and 80/20 ratios. The results of experimental and mathematical modeling suggest that viscosity is a very significant parameter which controls the bubble growth rate.
  • Master Thesis
    Development and Characterization of Pmma Based Porous Materials Used for High Pressure Casting of Sanitaryware Ceramics
    (Izmir Institute of Technology, 2004) Ergün, Yelda; Tanoğlu, Metin; Tanoğlu, Metin; 03.10. Department of Mechanical Engineering; 03. Faculty of Engineering; 01. Izmir Institute of Technology
    The ceramic whiteware / sanitaryware industry is rapidly undergoing to implement high-pressure casting techniques for ceramic article production. In high pressure technique, porous materials with open cell microstructure that allow drainage of water from the ceramic suspension under applied pressure are needed. In addition, a relatively high mechanical performance of the porous structure is required to obtain a long service life from the material under the cycled high pressures. The polymethyl methacrylate (PMMA) based polymeric porous structures have become the most suitable type of materials for this purpose because of their short casting periods and high service lives. The superior service life and performance of these materials are closely related to their microstructure. In the present study, PMMA-based porous materials were produced by water-in-oil emulsion polymerization technique. The porous systems were produced with various compositions of the constituents in the emulsion and various filler sizes to investigate the effect of the constituents and the sizes on the microstructure of PMMA-based materials. The variations on the pore microstructure were related to the performance of the material. The pore morphology and porosity of the samples was investigated using optical and scanning electron microscopy techniques (SEM). Water permeability was measured using a custom made permeability apparatus. The mechanical properties such as compressive collapse stress and elastic modulus values were determined by performing mechanical compression tests. It was found that increasing water surfactant concentration increases the porosity, water permeability and decreases mechanical properties and reversely increasing the amount of monomer in the emulsion decreases the porosity, water permeability and increases the mechanical properties. Fracture toughness values of the materials were measured by using single edge notch three point bending (SENB) test method. Fracture toughness test results and fracture surface analysis show that materials are fractured in brittle manner. It was found that lower concentrations of water and higher concentrations of monomer result in thicker cell walls and improve the fracture toughness of the material. To investigate the residual mechanical properties, specimens were subjected to cyclic loadings. After cyclic loading, increase of elastic modulus with the percentage of 52 and decrease of collapse stress values were measured.