Master Degree / Yüksek Lisans Tezleri
Permanent URI for this collectionhttps://hdl.handle.net/11147/3008
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Master Thesis Valorization of Biomass for Fuel and Chemicals Production(01. Izmir Institute of Technology, 2023) Yüksel Özşen, Aslı; Yüksel Özşen, Aslı; 03.02. Department of Chemical Engineering; 03. Faculty of Engineering; 01. Izmir Institute of TechnologyRapidly increasing global energy demand resulting from the growing population and worldwide development increased consumption of limited fossil fuel usage that causes severe environmental deterioration by CO2 emission have sparked interest in finding green, renewable, and sustainable alternative sources for energy. Bio-oil, derived by several biomass via liquefaction, is a promising candidate to replace fossil fuels. Turkey is a country, 27% of which is covered with forests (mostly oak trees). Therefore, it has great potential for cheap lignocellulosic feedstock forest residues from industrial applications and harvesting. In the present study, the thermal liquefaction of oak wood particles (OWP) was performed using various solvents besides water, such as ethanol, 1-butanol, and 1,4-dioxane. The experiments were carried out in a batch reactor for 1 and 2 h residence time at different temperatures (210oC, 240oC, and 270oC). Bio-oil samples obtained at best reaction temperature, 270oC, optimum residence time, 1 h, were analyzed with TGA, CHNS elemental analyzer, FTIR, and GC-MS. Based on energy recovery calculations, the enhancement of pristine OWP's energy efficiency depends on bio-oil yield, and quality was confirmed for all solvent types. 1,4-dioxane showed the best performance in yielding the maximum bio-oil with 51.8%. The higher heating values of the bio-oils ranged from 22.1 to 35 MJ/kg. Phenolic groups were the predominant components of bio-oil produced from OWP, while intensity of alcohols, ketones, and acids varied based on using solvents.Master Thesis Energy, Exergy and Enviromental Assessment of a Novel Multi-Generation System Fed by Biomass and Geothermal Energy Sources(01. Izmir Institute of Technology, 2022) Gökçen Akkurt, Gülden; Mohammadpourfard, Mousa; Gökçen Akkurt, Gülden; Mohammadpourfard, Mousa; 03.06. Department of Energy Systems Engineering; 03. Faculty of Engineering; 01. Izmir Institute of TechnologyEnergy is the one of the critical tools that ensure the development of the countries. Since almost no country is completely energy independent, it is very important for countries to use the available energy efficiently and to produce their own energy from renewable energy sources. Multi-generation systems combine various cycles and processes to produce number of outputs and valuable market products using one or multiple energy sources as input. By creating a multi-generation system powered by renewable sources can increase system efficiency and provide some additional outputs such as hydrogen, heating, cooling, and domestic hot water. In this thesis, a novel multi-generation system consisting of a biomass gasification cycle, a double-flash geothermal cycle, an Organic Rankine Cycle and a PEM electrolyzer subsystems, is proposed to increase the efficiency and energy production from biomass and geothermal energy sources instead of using a single source for a single output. The proposed system is analyzed in terms of energy, exergy, and environmental impact point of view. By performing parametric studies for biomass flow rate, turbine inlet temperature, and single-objective optimization, effects on thermodynamic behavior and environmental impact are investigated for subsystems and overall system. The best operating conditions are determined. The findings indicate that energy efficiency of the proposed multi-generation system is 75% higher than a double-flash geothermal power plant. Based on the parametric study, biomass mass flow rate is encountered as the most significant parameter, which caused an 11.7% increase in energy efficiency, and 225% increase in environmental impact cost.