Civil Engineering / İnşaat Mühendisliği
Permanent URI for this collectionhttps://hdl.handle.net/11147/13
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Article Citation - WoS: 2Citation - Scopus: 2Sample Collection Into Sterile Vacuum Tubes To Preserve Arsenic Speciation in Natural Water Samples(American Society of Civil Engineers (ASCE), 2013) Gündüz, Orhan; Gürleyük, Hakan; Çakır, Ayşe; Elçi, Alper; Baba, Alper; Şimşek, CelalettinThe accurate speciation analysis of arsenic is a serious concern for water quality monitoring programs. Because the preservation of sample integrity until analysis is one of the most important aspects of speciation, this study aims to compare the performance of four different sample preservation methods under diverse conditions of sample quality. Natural samples with different characteristics were collected into the following containers to study their effectiveness: (1) standard high-density polyethylene bottle with no preservative; (2) empty, sterile Vacuette tube with no preservative; (3) sterile tripotassium ethylenediaminetetraacetic acid (K3EDTA) Vacuette tube with K3EDTA additive; and (4) empty, sterile Vacuette tube with added hydrochloric acid (HCl). Known concentrations of arsenite [As(III)] were also added to each container to monitor the oxidation of As(III) to arsenate [As(V)]. The results revealed recovery ratios exceeding 95% in all containers with sterile vacuum conditions. In particular, the K3EDTA Vacuette tube yielded a recovery very close to 100% of the spiked As(III), which is known to rapidly oxidize to As(V). Overall, collecting the sample into a container under sterile vacuum conditions and using a universally accepted preserving agent such as EDTA or HCl significantly improved the preservation of the original species distribution in the water matrix studied, compared to sampling without the use of preservation methods. After validation by future research, these sterile vacuum tubes can possibly be utilized for collecting and storing samples for the routine speciation analysis of other elements such as selenium, chromium, and antimony.Article Citation - WoS: 24Citation - Scopus: 28Effect of Alteration Zones on Water Quality: a Case Study From Biga Peninsula, Turkey(Springer Verlag, 2010) Baba, Alper; Gündüz, OrhanWidespread and intense zones of silicified, propylitic, and argillic alteration can be found in the Çan volcanics of Biga Peninsula, northwest Turkey. Most of the springs in the study area surface out from the boundary between fractured aquifer (silicified zone) and impervious boundary (argillic zone). This study focuses on two such springs in KirazlI area (KirazlI and Balaban springs) with a distinct quality pattern. Accordingly, field parameters (temperature, pH, and electrical conductivity), major anion and cation (sodium, potassium, calcium, magnesium, chloride, bicarbonate, and sulfate), heavy metals (aluminum, arsenic, barium, chromium, cobalt, cupper, iron, lithium, manganese, nickel, lead, and zinc), and isotopes (oxygen-18, deuterium, and tritium) were determined in water samples taken from these springs during 2005 through 2007. The chemical analyses showed that aluminum concentrations were found to be two orders of magnitude greater in KirazlI waters (mean value 13813.25 μg/L). The levels of this element exceeded the maximum allowable limits given in national and international standards for drinking-water quality. In addition, Balaban and KirazlI springs are >55 years old according to their tritium levels; KirazlI spring is older than Balaban spring. KirazlI spring is also more enriched than Balaban spring based in oxygen-18 and deuterium values. Furthermore, KirazlI spring water has been in contact with altered rocks longer than Balaban spring water, according to its relatively high chloride and electrical conductivity values.