Civil Engineering / İnşaat Mühendisliği
Permanent URI for this collectionhttps://hdl.handle.net/11147/13
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Article Citation - WoS: 4Citation - Scopus: 6Testing the Performance of Various Polymeric Antiscalants for Mitigation of Sb-Rich Precipitates Mimicking Stibnite-Based Geothermal Deposits(Hindawi Publishing Corporation, 2020) Çiftçi, Celal; Karaburun, Emre; Tonkul, Serhat; Baba, Alper; Demir, Mustafa Muammer; Yeşilnacar, Mehmet İrfanScaling is frequently observed in geothermal fields and reduces the energy harvesting of power plants. Recently, Sb-rich deposits have developed in many fields around the world. Various polymeric macromolecules have been used as antiscalants to mitigate the formation of scale. Testing potential commercial antiscalants in field conditions is a tedious and costly process. The artificial synthesis of geothermal deposits in the lab is a more practical and economical way to test the performance of antiscalants. This study obtained a Sb-rich deposit by refluxing SbCl3 and Na2S center dot 3H(2)O in 18 h. The product was found to be a mixture of Sb2O3 and Sb2S3. We examined the performance of antiscalants such as poly(ethylene glycol), poly(vinyl pyrrolidone), Gelatin, and poly(vinyl alcohol) of various molecular weights at 5 to 100 ppm. The formation of Sb2S3 is suppressed in the presence of the polymeric antiscalants. The dosage was found to be critical for the solubilization of Sb-rich deposits. Gelatin of 5 ppm showed the highest performance under the conditions employed in this study. While low dosages improve the concentration of [Sb3+], high dosages are required to increase the solubility of [S2-]. Moreover, the amount of deposit is reduced by 12.4% compared to the reference (in the absence of any polymeric molecules). Thus, comparatively, Gelatin shows the most promising performance among the molecules employed.Article Citation - WoS: 13Citation - Scopus: 16Experimental Modeling of Silicate-Based Geothermal Deposits(Elsevier Ltd., 2017) Çelik, Aslı; Topçu, Gökhan; Baba, Alper; Akdoğan, Yaşar; Şentürk, Ufuk; Demir, Mustafa MuammerScaling by metal silicates represents a major obstacle for geothermal systems. A composition that enables the fabrication of artificial deposits is necessary for the rapid testing of potential inhibitors. In this work, artificial deposits were synthesized by employing experimental conditions similar to those in the Tuzla Geothermal Field in Turkey. Although refluxing enabled the formation of a precipitate that was similar to naturally formed deposits in color and texture, their elemental composition and morphology showed a mismatch. An autoclave enabled the production of a precipitate that more closely resembled naturally formed deposits in color, texture, elemental composition, and structure.Article Citation - WoS: 35Citation - Scopus: 45Types of the Scaling in Hyper Saline Geothermal System in Northwest Turkey(Elsevier Ltd., 2014) Demir, Mustafa Muammer; Baba, Alper; Atilla, Vedat; İnanlı, MustafaTuzla is an active geothermal area located in northwestern Turkey, 80km south of the city of Canakkale and 5km from the Aegean Coast. The geothermal brine from this area, which is dominated by NaCl, has a typical temperature of 173°C. Rapid withdrawal of fluid to ambient surface conditions during sampling causes precipitation of various compounds known as scaling. Scaling is one of the important problems in Tuzla geothermal system that reduces the efficiency of the geothermal power plant and causes economical loss. The aim of this study was to determine the type of scaling as a first step towards preventing its formation. The scales formed in the geothermal system were divided into two groups according to location: the ones that formed in downhole and the ones that accumulated along the surface pipeline. Both scales were examined in terms of their elemental composition, structure and morphology using XRF, XRD, and SEM, respectively. The former was found to be mainly composed of PbS (Galena) and CaCO3 (aragonite or calcite). In contrast, the latter was heterogeneous in nature and consisted of mainly saponite like amorphous structure along with submicrometer-sized amorphous silica particles, layered double magnesium and iron hydroxide, and NaCl.
