Civil Engineering / İnşaat Mühendisliği
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Article Citation - WoS: 21Citation - Scopus: 27Increasing Solubility of Metal Silicates by Mixed Polymeric Antiscalants(Elsevier Ltd., 2019) Topçu, Gökhan; Çelik, Aslı; Kandemir, Ali; Baba, Alper; Şahin, Hasan; Demir, Mustafa MuammerThe increase of silicate solubility is a big challenge for both hot and cold water because it reduces the deposition of metal silicates frequently observed in such systems and causes operational obstacles. The deposition of silicate coats the inner surface of the pipelines in an uncontrolled manner and reduces the harvesting of energy from brines. In this work, the solubility performance of two commercial water-soluble polymeric agents (poly(ethylene glycol) (PEG) and poly(vinyl alcohol) (PVA)) of various molecular weights employing dosage from 25 to 100 mg/L was examined. Along with dispersant-type antiscalant, poly(acrylamide) (PAM), poly(vinylsulfonic acid, sodium salt) (PVSA), and poly(vinylphosphonic acid) (PVPA) having chelating acidic groups were employed. Metal silicate deposits were obtained artificially in the lab-scale pressurized reactor. The experimental conditions employed were quite similar to a model power plant located in Çanakkale, Turkey. The concentration of dissolved silica was increased from 130 to 420 mg/L when 100 mg/L PEG 1500 and 25 mg/L PVSA were employed as a mixture. For the atomic-level understanding of the interaction of chelating groups with metal cations, DFT calculations were performed too.Article Citation - WoS: 28Citation - Scopus: 30Hydrogeochemical and Isotopic Composition of a Low-Temperature Geothermal Source in Northwest Turkey: Case Study of Kırkgeçit Geothermal Area(Springer Verlag, 2011) Şanlıyüksel, Deniz; Baba, AlperChemical and isotopic compositions of three hot springs and one cold spring in the Kirkgecit geothermal field, located 15 km southwest of Canakkale-Biga in the northwest of Turkey, were monitored five times during 2005 and 2007. The physico-chemical characteristics of the hot springs are average discharge 3–3.5 L/s, surface temperature 45–52 C, pH 8.9–9.3, and electrical conductivity (EC) 620–698 lS/cm. The cold spring has a temperature of 12–13 C, pH 7.5–8.3, and EC 653–675 lS/cm. The hot waters are Na-SO4 type, whereas the cold water is Ca-HCO3 type. Chemical geothermometers suggest that the reservoir temperature is around 80–100 C. The isotopic data (oxygen-18, deuterium and tritium) indicate that the thermal waters are formed by local recharge and deep circulation of meteoric waters.