WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7150
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Article Citation - WoS: 9Citation - Scopus: 18Improvement of Photophysical Properties of Cspbbr3 and Mn2+:cspb(br,cl)(3) Perovskite Nanocrystals by Sr2+ Doping for White Light-Emitting Diodes(American Chemical Society, 2022) Yüce, Hürriyet; Mandal, Mukunda; Yalçınkaya, Yenal; Andrienko, Denis; Demir, Mustafa MuammerAll-inorganic metal halide perovskite nanocrystals (NCs) having the general formula ABX(3), where A is a monovalent cation, for example, Cs+, B is a divalent cation, typically Pb2+, and X is Cl-, Br-, I-, or their binary mixture, show potential in optoelectronic devices. In this work, we explore the effect of B-site doping on the optoelectronic properties of CsPbX3 NCs (X = Br, Cl). First, the Pb2+ ions in the pristine CsPbBr3 NC are partially substituted by Mn2+ ions. The alkaline earth metal strontium is then doped on both pristine and the Mn2+-substituted NCs. We found that a small percentage of Sr2+ doping remarkably improves the photoluminescence quantum yield of CsPbBr3 and Mn2+-state emission in Mn2+:CsPb(Br,Cl)(3) NCs. Perovskite NC film/ poly(methyl methacrylate) composites with all four NC variants were used in a white light-emitting diode (WLED), where Sr2+ doping increased the luminous efficiency of the WLED by similar to 4.7%. We attribute this performance enhancement to a reduced defect density and an attenuated microstrain in the local NC structure.Article Citation - WoS: 2Citation - Scopus: 5Experimental Modeling of Antimony Sulfides-Rich Geothermal Deposits and Their Solubility in the Presence of Polymeric Antiscalants(Elsevier, 2022) Karaburun, Emre; Sözen, Yiğit; Çiftçi, Celal; Şahin, Hasan; Baba, Alper; Akbey, Ümit; Yeşilnacar, Mehmet İrfan; Erdim, Eray; Regenspurg, Simona; Demir, Mustafa MuammerAntimony (Sb)-rich geothermal deposits have been observed in many geothermal power plants worldwide. They occur as red-colored, sulfidic precipitates disturbing energy-harvesting by clogging the geothermal installations. In order to prevent the formation of this scale, information on its physicochemical features is needed. For this purpose, Sb-rich sulfide-based deposits were synthesized at controlled conditions in a pressurized glass reactor at geothermal conditions (135 °C and 3.5 bar). Various polymeric antiscalants with different functional groups, such as acrylic acid, sulphonic acid, and phosphonic acid groups were tested for their effect on Sb sulfide solubility. An additional computational study was performed to determine the binding energy of Sb and S atoms to these groups. The results suggest that sulfonic acid groups are the most affective. Therefore, it was concluded that these macromolecule containing sulfonic acid groups and poly (vinyl sulfonic acid) derivatives could potentially act as antiscalants for the formation of antimony sulfide.Article Citation - WoS: 4Citation - Scopus: 6Electrospinning of Fatty Acid-Based and Metal Incorporated Polymers for the Fabrication of Eco-Friendly Fibers(Wiley, 2022) Erdem, Çağlar; Isık, Tuğba; Horzum, Nesrin; Hazer, Baki; Demir, Mustafa MuammerAccumulation of plastic wastes occupies large space in gyres of the oceans called the 7th continent. This high-level concentration of toxic plastic wastes causes harmful consequences for marine life, therefore petroleum-originated plastics must be replaced (or at least partially) with natural resources. The environmental trends in material preparation promote the utilization of greener methods and materials when the limited primary sources are considered. Starting from the fatty acid macroperoxide initiators, synthesis of bio-based polymers using less commercial chemicals and stepwise green synthesis schemes could be possible in the near future. In this research, autoxidized vegetable oil initiators (castor, limonene, and soybean oil) containing metal nanoparticles (silver, platinum, and gold) are employed for free radical polymerization of vinyl monomers. The metal loaded and vegetable oil-based polymers are processed by electrospinning and end up with the successful fabrication of continuous fibers. Ag-loaded ricinoleic acid based polymers show notable antibacterial activity against Escherichia coli. This approach offers a remarkable minimization of the initiator consumption in the synthesis of such synthetic macromolecules as well as nanoparticle containing polymer composites while still maintaining the ease of processing. Transforming the obtained graft copolymers to electrospun nanofibers facilitates the use as support materials for antibacterial surfaces.Article Citation - WoS: 4Citation - Scopus: 4Effects of Alkaline Earth Metal Additives on Methylammonium-Free Lead Halide Perovskite Thin Films and Solar Cells(Wiley, 2022) Yüce, Hürriyet; LaFollette, Diana K.; Demir, Mustafa Muammer; Perini, Carlo A.R.; Correa-Baena, Juan-PabloOrganic–inorganic lead halide perovskite solar cells are regarded as one of the most promising technologies for the next generation of photovoltaics due to their high power conversion efficiency (PCE) and simple solution manufacturing. Among the different compositions, the formamidinium lead iodide (FAPbI3) photoactive phase has a bandgap of 1.4 eV, which enables the corresponding higher PCEs according to the Shockley–Queisser limit. However, the photoactive crystal phase of FAPbI3 is not stable at room temperature. The most high-performing compositions to date have reduced this problem by incorporating the methylammonium (MA) cation into the FAPbI3 composition, although MA has poor stability at high temperatures and in humid environments, which can limit the lifetime of FAxMA1−xPbI3 films. CsxFA1−xPbI3 perovskites are also explored, but despite better stability they still lag in performance. Herein, the additive engineering of MA-free organic−inorganic lead halide perovskites using divalent cations Sr2+ and Ca2+to enhance the performances of CsxFA1−xPbI3 perovskite compositions is explored. It is revealed that the addition of up to 0.5% of Sr2+ and Ca2+ leads to improvements in morphology and reduction in microstrain. The structural improvements observed correlate with improved solar cell performances at low additive concentrations.Article Citation - WoS: 10Citation - Scopus: 10Hydrogeology and Hydrogeochemistry of the Geothermal Systems and Its Direct Use Application: Balçova-Narlıdere Geothermal System, İzmir, Turkey(Elsevier, 2022) Baba, Alper; Sözbilir, Hasan; Sayık, Tolga; Arslan, Sinan; Uzelli, Taygun; Tonkul, Serhat; Demir, Mustafa MuammerThe Balçova-Narlıdere geothermal system, located in western Turkey, is an extensional domain type geothermal play. Geological, hydrogeological, and geothermal studies have been done in the Balçova-Narlıdere geothermal field since 1960. As a result of these studies, production and research wells were drilled in the area by both the public and private sectors. Of the 37 wells drilled in the Balçova-Narlıdere geothermal field, 26 were drilled by İzmir Geothermal Energy Company Inc. (16 productions, 4 re-injection, 4 gradientst, 2 unused) and 11 by the İzmir Governorship Investment Monitoring and Coordination Department and companies in the private sectors. There are two reservoirs, one shallow and one deep, in the geothermal field. Well depths are less than 200 m in the shallow reservoir. The deep production wells have depths ranging from 400 to 1,100 m and reservoir temperatures reaching 140 °C. The electrical conductivity (EC) values in the shallow production wells range from 1,200 to 1,500 µS/cm. EC values in the deep production wells vary from 1,871 to 2,025 µS/cm, and all geothermal fluids in the field are mineral-rich waters. In the İzmir geothermal district heating system, the newest technologies are used, and operational costs are very low. İzmir Geothermal Energy Company Inc. has been operating since 1996 and has reached 38,460 residences. The current capacity of the system is approximately 160 MWt. Cooling systems continue to spread in Turkey, focusing on electric air conditioning systems and geothermal heating systems, but both economic and applicability problems have slowed the expansion of cooling systems. However, İzmir Geothermal Energy Company Inc. began operating its first geothermal cooling application in Balçova in 2018, cooling 1,900 m2 of the indoor area by lithium bromide absorption and 90/85 °C geothermal temperature regime by supplying 6/9 °C clean cold water to the coolers in the buildings. These results show that the extensional domain type geothermal system in the Balçova-Narlıdere region is suitable for both heating and cooling applicationsArticle Citation - WoS: 3Citation - Scopus: 6Hybrid Photonic-Plasmonic Mode-Coupling Induced Enhancement of the Spontaneous Emission Rate of Cds/Cdse Quantum Emitters(Elsevier, 2022) Gökbulut, Belkıs; İnanç, Arda; Topçu, Gökhan; Özçelik, Serdar; Demir, Mustafa Muammern this paper, a hybrid photonic-plasmonic resonator, which comprises an electrospun polymer fiber with a micrometer diameter and a core/shell nanostructure with a gold nanoparticle core, is constructed to investigate the dynamics of the coupled spontaneous emission of CdS/CdSe quantum dots (QDs). The gold nanoparticle core; covered with a silica shell, anchored with individual CdS/CdSe QDs, is placed inside a hollow cylindrical nanocavity formed on the surface of the microfiber to enable integration of the optical mode with the plasmonic effect, which is induced by the localized surface plasmons of the metal nanoparticle being present in the vicinity of the dipoles. The spontaneous emission rate of the QDs, coupled into the hybrid photonic-plasmonic mode, is measured to enhance by a factor of 23 via a time-resolved experimental technique. This result suggests that the regeneration of the optical mode-field inside the photonic-plasmonic resonator through the interaction of the dipoles with the localized surface plasmons of a metal nanoparticle strongly enhances the density of the electromagnetic states of the quantum emitters to facilitate an enhanced spontaneous emission within the host medium of the proposed polymer based-photonic structure.Article Citation - WoS: 9Citation - Scopus: 7Understanding the Impact of Sri2 Additive on the Properties of Sn-Based Halide Perovskites(Elsevier, 2022) Yüce, Hürriyet; Perini, Carlo A. R.; Hidalgo, Juanita; Castro-Mendez, Andres-Felipe; Evans, Caria; Demir, Mustafa MuammerOrganic-inorganic halide perovskites have been identified as favorable candidates for the next generation of photovoltaics. Adding alkali metal halides to perovskite films has been shown to be a viable option to improve the perovskite film quality and to modulate their fundamental properties. In this work, we perform optical and electron-beam based characterizations of mixed Sn/Pb based perovskite films to investigate the effect of the addition of the alkaline metal halide SrI2. By analyzing structural (X-ray diffraction), morphological (Scanning Electron Microscopy), optical (photoluminescence), and chemical properties (X-ray photoelectron spectroscopy), we show a complex interplay of effects upon addition of Sr2+ into the perovskite solution. Low concentrations of Sr2+ increases lattice strain, which hints at incorporation of the additive into the perovskite lattice and improves the film optoelectronic properties. As the additive concentration increases beyond 0.5 mol %, microstrain decreases. At concentrations >0.5 mol %, Sr2+ induces significant reduction of the average domain size, which impacts both structural and optical properties of the perovskite film.Article Citation - WoS: 3Citation - Scopus: 5Plasmon-Induced Spectral Tunability of Perovskite Nanowires(Elsevier, 2021) Gökbulut, Belkıs; Topçu, Gökhan; Demir, Mustafa Muammer; İnci, Mehmet NaciIn this paper, plasmon-assisted spectral tunability in random media, composed of Perovskite (CsPbBr3) nanowires surrounded by Au nanoparticle clusters in polystyrene matrix, is achieved. The interaction between the surface plasmons and the quantum sources is observed to generate photoluminescence from the higher excited state energy levels of the excited semiconductor nanowires, which results in a blueshifted fluorescence emission of 50 nm. The localized surface plasmon properties are also determined to be tuned by plasmonic pumping of the quantum sources at different resonant frequencies. Thus, the first observation of the tunable blueshifted fluorescence emission of the semiconductor nanocrystals surrounded by plasmonic nanoparticle aggregates is achieved. The dramatic changes in the spectral profiles of the fluorescent nanowires are attributed to be due to the fast dynamics surface enhanced fluorescence mechanism.