WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7150
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Article Citation - WoS: 6Citation - Scopus: 9Holistic Managements of Textile Wastewater Through Circular, Greener and Eco-Innovative Treatment Systems Developed by Minimal To Zero Liquid Discharge(Elsevier, 2024) Aydıner, Coşkun; Doğan, Esra Can; Mert, Berna Kiril; Pala, Burcu; Demirozlu, Tugba Nur; Balcı, Esin; Narci, Ali OguzhanNew pragmatic and viable solutions to reduce or prevent discharge and to protect reserves are currently among the top-prioritised research for cleaner, circular, and resource-efficient use of industrial waters. So, the development of eco-sustainable water management is essential for green industrial development that will meet versatile and eco-sensitive regulatory standards, especially in water-intensive industries. Textile wastewater was reclaimed in semi to fully closed loops for minimal to zero liquid discharge. Concentrate-mixed wastewater was steadily treated in a hybrid membrane oxidation reactor at 60-80 % synergistic performances with remarkable UF fluxes of 96.4-820 L/m2h without any sludge discharge. Effluent was purified with 90-100 % removals and 20-80 L/m2h in nanofiltration and reverse osmosis. Due to Fenton-specific operation, more handling by ion exchange and neutralisation required to harvest membrane reuse waters and reactor discharge effluents with guaranteed Fe and pH. All-in-one system simulations indicated that high quality reuse waters are produced by 99.9 % efficiency and 98 and 100 % savings in iron and acid but 20-51 % more oxidant through concentrate recycling and regenerant reuse. It was also revealed that reactor effluents can be released to the sea or conventional biological treatment or can be eco-sustainably exploited for in-situ chemical and ex-situ bio-induced recovery of vivianite. This research demonstrates that how textile wastewater can be managed holistically by liquid discharge approaches from 50 % minimal to 99.9 % zero just in two-step, i.e. pretreatment and preconcentration, with consumable minimisation and valuable waste recovery through the eco-innovative systems which are developed as circular, greener, and sludge-free compatible with sustainable development goals.Article Citation - WoS: 2Tekstil Endüstrisinde Bütünleşik Membran Sistemi ile Su Geri Kazanımı ve Hibrit İleri Oksidasyon/membran Filtrasyonu ile Konsantrelerin Arıtımı ve Yönetimi(Pamukkale Üniversitesi, 2018) Kırıl Mert, Berna; Doğan, Esra C.; Balcı, Esin; Tilki, Yasemin M.; Aksu, Şeyda; Gören, Ayşegül Yağmur; Aydıner, CoşkunBu çalışmada, etkinliği bilinen UF/NFsıkı/TO membran kombinasyonu ile tekstil atıksularının arıtımının yanısıra %75-80 su geri kazanım oranı dahilinde oluşan membran konsantrelerinin, bütünleşik ileri oksidasyon prosesi (Fenton ve foto-Fenton (UVA-365–UVC-254))/batık UF sistemi ile daha önce belirlenen optimum işletme şartlarında oksidasyona tabi tutularak yönetimi gerçekleştirilmiştir. Yapılan deneysel çalışmalar sonucunda, UF/NFsıkı/TO membran konfigürasyonu ile arıtımı sonucunda oluşan konsantre akımlarının Fenton, foto-Fenton (UVA-365) ve (UVC-254) prosesleri/batık UF sistemi ile oksidasyonu sonrası, ardışık işletimli foto-Fenton (UVC-254)/UH050 hibrit prosesinin 9.88 H2O2/TOK ve 7.27 H 2 O 2 /Fe 2 + oranlarında, 44 L/m 2 .sa’lik süzüntü akısında %86 KOİ giderimi ile KOİ değeri 167 mg/L’ye ve %74.2 TOK giderimi ile TOK değeri 104 mg/L’ye kadar düşürülerek en iyi performans gösteren yenilikçi proses olduğu sonucuna varılmıştır. Oluşan membran konsantrelerin oksidasyonu sonrasında kalan konsantrenin tehlikelilik özellikleri, bertaraf/geri kazanım yöntemleri ve yeniden kullanım alternatifleri değerlendirildiğinde tekstil endüstrisi atıksularının foto-Fenton (UVA-365) ile arıtımı sonucunda oluşan konsantre haricinde diğer tüm konsantrelerin tehlikeli özelliğine sahip olduğu görülmüştür. Konsantrelerin bertaraf/geri kazanım yöntemleri ayrıntılı olarak değerlendirildiğinde, gerekli düzenlemeler (nem içeriği, susuzlaştırma, uygun debi ve/veya karışım oranları) yapıldığı takdirde bu konsantrelerin düzenli depolama, yakma ve merkezi atıksu arıtma sistemine verme gibi seçeneklerle bertaraf edilebileceği sonucuna varılmıştır.Article Citation - WoS: 22Citation - Scopus: 25Novel Hybrid Treatments of Textile Wastewater by Membrane Oxidation Reactor: Performance Investigations, Optimizations and Efficiency Comparisons(Elsevier, 2019) Aydıner, Coşkun; Mert, Berna Kiril; Doğan, Esra Can; Yatmaz, Hüseyin Cengiz; Dağlı, Sönmez; Aksu, Şeyda; Gören, Ayşegül Yağmur; Balcı, EsinFeasible reclamation of industrial wastewaters by consuming less resource and time requires researchers to develop advanced and sophisticated solutions to meet today's versatile needs. In this respect, novel technological applications of hybrid membrane oxidation reactor (MOR) comprising of the Fenton or photo-Fenton enhanced ultrafiltration (FEUF and pFEUF), was demonstrated for treating textile washing wastewater. Their comparative hybrid performances were explored based on response surface analyses of Taguchi experimental designs that were optimized for maximized responses at minimum oxidant and acid consumptions. From eleven specific variables, those affecting the hybrid treatment performances at significant levels were found as H2O2 amount, process time, membrane type, Fe2+ concentration and temperature. The pFEUF treatment showed better and faster organics removal efficiency than by FEUF, and the UF process was seen to be more affected from changing operational conditions in pFEUF. Organic pollutants were oxidized by 56.6 +/- 8.7% degradation and 31.5 +/- 3.2% mineralization, while UF allowed a synergistic contribution to the hybrid MOR performance by 38.1 +/- 4.7% and 17.3 +/- 3.1%, respectively. Compared to simultaneous MOR and external UF after Fenton, sequential MOR was found as the best solution by an efficiency of 84.5% COD, 70.5% TOC, and 155.6 L/m(2).h. The effluents could be readily produced with quality suitable for directly discharging to the sewage infrastructure system resulting in a complete treatment. This study proved that the developed MOR techniques are technologically favorable for the treatment of industrial organic wastewaters due to high treatment performances and less resource, time and land needs. It can be finally declared that they can be used as rather attractive solutions for not only wastewater reclamation but also water recovery by further handling of their effluents. (C) 2019 Elsevier B.V. All rights reserved.