WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

Permanent URI for this collectionhttps://hdl.handle.net/11147/7150

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Access Right: Open AccessInstitution Author: search.filters.institutionAuthor.İnan, Alper

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  • Article
    Citation - WoS: 21
    Citation - Scopus: 22
    Redox-Responsive Release of Active Payloads From Depolymerized Nanoparticles
    (Royal Society of Chemistry, 2017) Lv, Li-Ping; Jiang, Shuai; İnan, Alper; Landfester, Katharina; Crespy, Daniel
    The difference in the reactivity of two monomers, aniline (ANI) and 2,5-dimercapto-1,3,4-thiadiazole (DMcT), was employed to design nanoparticles with completely different nanostructures. The monomers were simultaneously polymerized by tandem oxidative polymerization occurring in the miniemulsion droplets. DMcT is also a corrosion inhibitor and its polymer can be depolymerized by reduction, which avoids the unwanted release of the payload DMcT when the capsules are not activated. The redox-responsive release profile of DMcT from the composite particles is controlled by the morphology of the particles and it was investigated for monolithic, multi-hollow, and yolk-shell structures. These PANI/PDMcT composite particles may find potential application in Li-S batteries or in the self-healing systems for corrosion protection.