WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7150
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Article Citation - WoS: 6Citation - Scopus: 9Holistic Managements of Textile Wastewater Through Circular, Greener and Eco-Innovative Treatment Systems Developed by Minimal To Zero Liquid Discharge(Elsevier, 2024) Aydıner, Coşkun; Doğan, Esra Can; Mert, Berna Kiril; Pala, Burcu; Demirozlu, Tugba Nur; Balcı, Esin; Narci, Ali Oguzhan; 01. Izmir Institute of TechnologyNew pragmatic and viable solutions to reduce or prevent discharge and to protect reserves are currently among the top-prioritised research for cleaner, circular, and resource-efficient use of industrial waters. So, the development of eco-sustainable water management is essential for green industrial development that will meet versatile and eco-sensitive regulatory standards, especially in water-intensive industries. Textile wastewater was reclaimed in semi to fully closed loops for minimal to zero liquid discharge. Concentrate-mixed wastewater was steadily treated in a hybrid membrane oxidation reactor at 60-80 % synergistic performances with remarkable UF fluxes of 96.4-820 L/m2h without any sludge discharge. Effluent was purified with 90-100 % removals and 20-80 L/m2h in nanofiltration and reverse osmosis. Due to Fenton-specific operation, more handling by ion exchange and neutralisation required to harvest membrane reuse waters and reactor discharge effluents with guaranteed Fe and pH. All-in-one system simulations indicated that high quality reuse waters are produced by 99.9 % efficiency and 98 and 100 % savings in iron and acid but 20-51 % more oxidant through concentrate recycling and regenerant reuse. It was also revealed that reactor effluents can be released to the sea or conventional biological treatment or can be eco-sustainably exploited for in-situ chemical and ex-situ bio-induced recovery of vivianite. This research demonstrates that how textile wastewater can be managed holistically by liquid discharge approaches from 50 % minimal to 99.9 % zero just in two-step, i.e. pretreatment and preconcentration, with consumable minimisation and valuable waste recovery through the eco-innovative systems which are developed as circular, greener, and sludge-free compatible with sustainable development goals.Article Citation - WoS: 15Citation - Scopus: 19Immobilization of Esterase From Bacillus Subtilis on Halloysite Nanotubes and Applications on Dibutyl Phthalate Degradation(Elsevier, 2023) Rosales, Emilio; Pazos, Marta; Sofuoğlu, Aysun; Balcı, Esin; Sofuoğlu, Aysun; 03.02. Department of Chemical Engineering; 03. Faculty of Engineering; 01. Izmir Institute of TechnologyDibutyl phthalate (DBP) is one of the listed phthalic acid esters (PAEs) known as the priority toxicants which exhibit carcinogenic and teratogenic properties and is responsible for endocrine disruption. Therefore, its removal has become a matter to tackle with. In this work, the feasibility of DBP degradation by esterase and lipase enzymes obtained from various microorganisms and the immobilization of the most effective in a clayey material were investigated. Esterase from Bacillus subtilis exhibited the highest degradation efficiency reaching a complete degradation. Its immobilization onto halloysite nanotubes (HNTs) by adsorption method was studied by response surface methodology using a central composite design face-centered. The four selected factors that affect the HNT-enzyme composite generation were: pH, adsorption time, enzyme/HNT (E/H) ratio, and adsorption temperature, and the optimal conditions were determined (pH 7, time 360 min, E/H ratio 0.2, temperature 30oC). Consequently, the activity did not significantly decrease by immobilization, and the adsorption efficiency and relative activity were determined to be 73.15% and 82.7%, respectively. Besides, the immobilization enhanced thermal and storage stability. As for enzyme reusability, after 7 continuous cycles, the composite maintained almost 75% of its initial activity. Both the free enzyme (1 mg/mL) and the composite degraded 100 mg/L DBP with 100% efficiency and several byproducts were detected. Moreover, the composite could be reused for 7 cycles keeping a remarkable catalytic activity. Overall, this study indicated that the HNT-enzyme composite may be used as an effective candidate for remediation of the environmental media contaminated with DBP and other PAEs.(c) 2023 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).Article Citation - WoS: 4Citation - Scopus: 5Continuous Treatment of Diethyl Hexyl and Dibutyl Phthalates by Fixed-Bed Reactor: Comparison of Two Esterase Bionanocomposites(Elsevier, 2022) Sanroman, Maria Angeles; Balcı, Esin; Sofuoğlu, Aysun; Pazos, Marta; Sofuoğlu, Aysun; 03.02. Department of Chemical Engineering; 03. Faculty of Engineering; 01. Izmir Institute of TechnologyThe removal of Diethyl hexyl phthalate (DEHP) and Dibutyl phthalate (DBP) is of great importance due to their potential adverse effects on the environment and human health. In this study, two bionanocomposites prepared by immobilization of Bacillus subtilis esterase by crosslinking to halloysite and supported in chitosan and alginate beads were studied and proposed as a green approach. The esterase immobilization was confirmed by physical-chemical characterization. Bionanocomposite using chitosan showed the best degradation levels in batch tests attaining complete degradation of DBP and around 90% of DEHP. To determine the operational stability and efficiency of the system, two fixed bed reactors filled with both bionanocomposites were carried out operating in continuous mode. Chitosan based bionanocomposite showed the best performance being able to completely remove DBP and more than 85% of DEHP at the different flowrates. These results proved the potential of these synthesized bionanocomposites to effectively remove Phthalic Acid Esters.Article Citation - WoS: 20Citation - Scopus: 25Indoor Air Partitioning of Synthetic Musk Compounds: Gas, Particulate Matter, House Dust, and Window Film(Elsevier, 2020) Genişoğlu, Mesut; Genişoğlu, Mesut; Sofuoğlu, Sait Cemil; Sofuoğlu, Aysun; Sofuoğlu, Sait Cemil; Sofuoğlu, Aysun; 03.02. Department of Chemical Engineering; 03.07. Department of Environmental Engineering; 03. Faculty of Engineering; 01. Izmir Institute of TechnologyDue to diversity of contaminants indoors and complexity in the physical structure of particulate matter, partition process of chemicals affects indoor concentration distribution. Synthetic Musk Compounds (SMCs) are ubiquitously found in household and personal care products, thus, in the environment. Exposure to SMCs is important for human health, therefore, their partitioning in indoor environmental media is a key issue. In this study, gas particle, house dust, andwindowfilm partitioning of SMCs were investigated in an indoor micro-environment. In a sealed and unoccupied room, a polycyclic and nitro musk mixture was left for volatilization for an hour. Then, samples were collected using XAD-2 sandwiched between two PUF plugs, glass-fiber filter, and wipes for gas, PM10, window-film, house dust phases, respectively, for 145 h. Collected samples were analyzed using a GC-MS. Results demonstrated that MC concentrations decreased over time, non-linearly. Six of the SMCs partitioned to PM10 with at least 10% at beginning of the experiment, whereas the number of compounds dropped to two at the end, showing that SMCs may partition well between the two phases but they tend to be in the gas phase. They were also detected in the film and dust phases but a decrease pattern similar to gas-particle was not observed. Spearman correlations indicate that the dust and film-associated concentrations were governed by similar processes but PM-associated concentrations were not. SMCs may be found in all phases, mainly in house dust in terms of mass among the studied media and unaccounted surface reservoirs. Therefore, their partitioning between indoor media has key implications for human exposure. (C)20 Elsevier B.V. All rights reserved.