WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7150
Browse
2 results
Search Results
Article Citation - WoS: 3Citation - Scopus: 5Temperature Dependent Electrical and Electrocaloric Properties of Textured 0.72pmn-0.28pt Ceramics*(Taylor & Francis, 2021) Böbrek, İrem; Berksoy Yavuz, Ayşe; Kaya, M. Yunus; Alkoy, Sedat; Okatan, Mahmut Barış; Mısırlıoğlu, İbrahim Burç; Mensur Alkoy, EbruLead magnesium niobate (PMN) - lead titanate (PT) solid solution ceramics in the ratio of 0.72PMN-0.28PT was produced by a combination of tape-casting in ⟨001⟩(pc) textured and random forms. The Lotgering factor, f, of textured ceramics was approximately calculated as 80%. Modified Curie-Weiss analysis indicated relaxor dominant behavior for both the random and textured ceramics. Development of texture led to an enhancement in the electromechanical properties with converse piezoelectric charge coefficient (d(33)*) under 20 kV/cm electric field reaching 545 pm/V for the textured ceramic. Electrocaloric (EC) behavior of random and textured ceramics were obtained from indirect measurements using temperature dependent polarization vs. electric field hysteresis loops. An EC temperature change (Delta T-EC) of similar to 0.5 K was calculated from the PMN-28PT ceramics at around 80 degrees C under an electric field of 60 kV/cm. Development of texture was demonstrated to have led to an anisotropy in the EC response.Article Citation - WoS: 14Citation - Scopus: 13Effect of Texture on the Electrical and Electrocaloric Properties of 0.90pb(mg1/3nb2 Relaxor Ceramics(American Institute of Physics, 2020) Mensur Alkoy, Ebru; Okatan, M. Barış; Aydın, Ecem; Kılıç, Yusuf; Mısırlıoğlu, I. Burç; Alkoy, SedatFunctional properties of ferroelectric compositions depend strongly on the type of stable crystalline phase at a given temperature and texturing. In addition to defining a governing crystallographic axis among the grains with respect to a global reference axis, texturing in these systems is also often meant to imply the relationship between an external applied field and the polar axis. Here, we synthesize randomly oriented and 001(pc) textured 0.90Pb(Mg1/3Nb2/3)O-3-0.10PbTiO(3) solid solutions that fall into the relaxor category. A >95% degree of 001(pc) texturing was achieved by the use of single crystal BaTiO3 template crystallites whose volume fraction does not exceed 5% of the entire sample volume. Electrical measurements made on random and textured samples reveal the impact of texture on the hysteresis and the dielectric response. A Curie-Weiss analysis of the temperature dependent dielectric data shows the degree of relaxor behavior in random and textured samples. As similar compositions have recently been getting interest for electrothermal management applications, we compute the electrocaloric (EC) response of the random and textured samples using indirect methods followed by an estimation of the EC response with a subsequent thermodynamic analysis to shed light on the effect of texture on the observed differences between the textured and the random oriented samples. We finally compare and contrast on the desirability of texturing in these systems for use as EC components for thermal management applications.
