WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

Permanent URI for this collectionhttps://hdl.handle.net/11147/7150

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  • Article
    Citation - WoS: 2
    Catalytic Activity of Heteropolytungstic Acid Encapsulated Into Mesoporous Material Structure
    (Walter de Gruyter GmbH, 2007) Gündüz, Gönül; Dimitrova, Rayna P.; Yılmaz, Selahattin
    The paper presents a spectroscopic and catalytic study of encapsulated Keggin type heteropoly acid (12-tungstophosphoric acid, HPW) in the mesopores of MCM-41 molecular sieves. Nitrogen physisorption, FTIR, SEM, XRD and catalytic methods have been used to characterize and compare the properties of the samples. Methanol conversion, alpha-pinene isomerization and ethyl acetate oxidation have been applied as model reactions for the evaluation of acid site activity. The combined physicochemical and catalytic investigations clearly show that the introduction of 12-tungstophosphoric acid into MCM-41 causes significant changes in the properties of the sample.
  • Article
    Citation - WoS: 53
    Citation - Scopus: 60
    Properties of N-Eicosane Silk Fibroin-Chitosan Microcapsules
    (John Wiley and Sons Inc., 2011) Başal, Güldemet; Şirin Deveci, Senem; Yalçın, Dilek; Bayraktar, Oğuz
    PCM microcapsules containing n-eicosane were prepared by complex coacervation of silk fibroin (SF) and chitosan (CHI). Chemical characterization of microcapsules was carried out using Fourier-transform infrared (FT-IR) spectroscopy. Thermal properties and thermal stability of microencapsulated n-eicosane were determined by differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). FTIR spectra confirmed the encapsulation of n-eicosane within the microcapsules. Results from thermal analyses showed that microcapsules consisted of an average of 45.7 wt % n-eicosane, and had a thermal energy storage and release capacity of about 93.04 J/g and 89.68 J/g, respectively.