WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7150
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Article Biquandle Power Brackets of Oriented Links(Tubitak Scientific & Technological Research Council Turkey, 2025) Güğümcü, Neslihan; Nelson, Sam; 04.02. Department of Mathematics; 04. Faculty of Science; 01. Izmir Institute of TechnologyIn this paper, we introduce biquandle power brackets, an infinite family of invariants of oriented links containing the classical skein invariants and the quandle and biquandle 2-cocycle invariants as special cases. Biquandle power brackets are generalizations of biquandle brackets in which the values of Kauffman states also depend on the biquandle colors they admit. We provide example computations and discuss the relationship between these new invariants and the previous cases.Review Citation - WoS: 1Citation - Scopus: 2Organ-On Platforms for Drug Development, Cellular Toxicity Assessment, and Disease Modeling(Tubitak Scientific & Technological Research Council Turkey, 2024) Khurram, Muhammad Maaz; Bedir, Erdal; Cinel, Gokturk; Yesil Celiktas, Ozlem; Bedir, Erdal; 03.01. Department of Bioengineering; 03. Faculty of Engineering; 01. Izmir Institute of TechnologyOrgans-on-chips (OoCs) or microphysiological platforms are biomimetic systems engineered to emulate organ structures on microfluidic devices for biomedical research. These microdevices can mimic biological environments that enable cell-cell interactions on a small scale by mimicking 3D in vivo microenvironments outside the body. Thus far, numerous single and multiple OoCs that mimic organs have been developed, and they have emerged as forerunners for drug efficacy and cytotoxicity testing. This review explores OoC platforms to highlight their versatility in studies of drug safety, efficacy, and toxicity. We also reflect on the potential of OoCs to effectively portray disease models for possible novel therapeutics, which is difficult to achieve with traditional 2D in vitro models, providing an essential basis for biologically relevant research.Article Citation - WoS: 10Effects of Seismic Activity on Groundwater Level and Geothermal Systems in İzmir, Western Anatolia, Turkey: the Case Study From October 30, 2020 Samos Earthquake(Tubitak Scientific & Technological Research Council Turkey, 2021) Uzelli, Taygun; Baba, Alper; Ozturk, Bahadir; Baba, Alper; Sozbilir, Hasan; Tatar, Orhan; 03.03. Department of Civil Engineering; 01.01. Units Affiliated to the Rectorate; 01. Izmir Institute of Technology; 03. Faculty of EngineeringThe October 30, 2020 Samos earthquake (Mw 6.6) affected the Aegean Sea and environs, caused destruction and loss of life in the city of & Idot;zmir located 70 km away from the earthquake epicenter. Before this earthquake, water resources were monitored in the areas of Bayrakl & imath;, G & uuml;lbah sigma e, and Seferihisar. For this purpose, 10 groundwater monitoring wells were drilled in the Bayrakl & imath; area, where groundwater level, temperature, and electrical conductivity changes were monitored at 1-h intervals in 5 wells. Besides physical parameters such as groundwater levels, temperatures and electrical conductivities, hydrogeochemical cations, and anions measured in the study area. Change in the groundwater levels was observed before, during, and after the Samos earthquake. A trend of rising groundwater level was observed two days before the mainshock, to a height of 10 cm, and the level was maintained till the end of the earthquake. The water levels returned to its original height after about 7 to 10 days of the earthquake. Moreover, electrical conductivity (EC) values were changed because of the interaction with the surrounding rocks and well walls, mixing with different waters during the earthquake shaking. The essential anomalies were observed in the geothermal fields of G & uuml;lbah sigma e and Seferihisar. Due to this earthquake, new geothermal springs emerged along the NE-SW trending G & uuml;lbah sigma e and Tuzla faults, located about 50 to 20 km from the Samos earthquake epicenter, respectively. The new geothermal waters are in Na-Cl composition and similar to other geothermal springs in the region. While the recorded water temperatures in the new geothermal springs vary from 40 to 45 degrees C in Seferihisar, it was measured between 35 and 40 degrees C in G & uuml;lbah sigma e. Due to these anomalies, it is found essential to monitor the effect of the earthquake on the physical and chemical characteristics of the groundwater and its usefulness in earthquake predictions.Article Citation - WoS: 1Citation - Scopus: 2Lacoo3 Is a Promising Catalyst for the Dry Reforming of Benzene Used as a Surrogate of Biomass Tar(Tubitak Scientific & Technological Research Council Turkey, 2024) Çağlar, Başar; Üner, Deniz; 03.06. Department of Energy Systems Engineering; 03. Faculty of Engineering; 01. Izmir Institute of TechnologyTar build-up is one of the bottlenecks of biomass gasification processes. Dry reforming of tar is an alternative solution if the oxygen chemical potential on the catalyst surface is at a sufficient level. For this purpose, an oxygen-donor perovskite, $LaCoO_3$, was used as a catalyst for the dry reforming of tar. To circumvent the complexity of the tar and its constituents, the benzene molecule was chosen as a model compound. Dry reforming of benzene vapor on the $LaCoO_3$ catalyst was investigated at temperatures of 600, 700, and 800 °C; at $CO_2/C_6H_6$ ratios of 3, 6, and 12; and at space velocities of 14,000 and 28,000 h–1. The conventional Ni(15 wt.%)/$Al_2O_3$ catalyst was also used as a reference material to determine the relative activity of the $LaCoO_3$ catalyst. Different characterization techniques such as X-ray diffraction, $N_2$ adsorption-desorption, temperature-programmed reduction, and oxidation were used to determine the physicochemical characteristics of the catalysts. The findings demonstrated that the $LaCoO_3$ catalyst has higher $CO_2$ conversion, higher $H_2$ and CO yields, and better stability than the Ni(15 wt.%)/γ-$Al_2O_3$ catalyst. The improvement in activity was attributed to the strong capacity of $LaCoO_3$ for oxygen exchange. The transfer of lattice oxygen from the surface of the $LaCoO_3$ catalyst facilitates the oxidation of carbon and other surface species and leads to higher conversion and yields.Article Citation - WoS: 3Citation - Scopus: 3Β-Ketoenamine-linked covalent organic framework for efficient iodine capture(Tubitak Scientific & Technological Research Council Turkey, 2024) Büyükçakır, Onur; Büyükçakır, Onur; 04.01. Department of Chemistry; 04. Faculty of Science; 01. Izmir Institute of TechnologyExploring the materials that effectively capture radioactive iodine is crucial in managing nuclear waste produced from nuclear power plants. In this study, a β-ketoenamine-linked covalent organic framework (bCOF) is reported as an effective adsorbent to capture iodine from both vapor and solution. The bCOF’s high porosity and heteroatom-rich skeleton offer notable iodine vapor uptake capacity of up to 2.51g $g^{–1}$ at 75 °C under ambient pressure. Furthermore, after five consecutive adsorption-desorption cycles, the bCOF demonstrates high reusability performance with significant iodine vapor capacity retention. The adsorption mechanism was also investigated using various ex situ structural characterization techniques, and these mechanistic studies revealed the existence of a strong chemical interaction between the bCOF and iodine. The bCOF also showed good iodine uptake performance of up to 512 mg $g^{–1}$ in cyclohexane with high removal efficiencies. The bCOF’s performance in adsorbing iodine from both vapor and solution makes it a promising material to be used as an effective adsorbent in capturing radioactive iodine emissions from nuclear power plants.Article Citation - Scopus: 3Evaluation of Gis-Based Spatial Interpolation Methods for Groundwater Level: a Case Study of Türkiye(Tubitak Scientific & Technological Research Council Turkey, 2024) Baba, Alper; Tirol Kırçiçek, Nilüfer; Koçbay, Ayhan; Toklu, Murat Mert; 03.03. Department of Civil Engineering; 03. Faculty of Engineering; 01. Izmir Institute of Technology; 03.07. Department of Environmental EngineeringGroundwater is a valuable and universally distributed resource on Earth. Understanding the spatial and temporal dynamics of groundwater is of utmost importance for effective management. Normally, groundwater levels are recorded at arbitrary points, but groundwater modeling requires interpolating the measured values at specific grid nodes. This study aims to dentify and evaluate the geographical variations of groundwater levels in Türkiye using three geostatistical interpolation techniques. Data from 355 groundwater wells from 1970 to 2019 were used for this purpose. In addition, an investigation of changes in annual average temperature and precipitation was conducted for two different time periods: 1985–2000 and 2001–2016. The results show an increase in the annual average temperature in Türkiye by 0.82 °C during the reference period (1985–2000). Despite regional differences in the precipitation regime, the average annual precipitation in Türkiye has not changed significantly overall. Especially in the Meriç-Ergene, Konya Closed (Konya Kapalı), and Euphrates-Tigris basins, a significant decrease in groundwater levels was observed, even though this decrease is less than 100 m in some wells. After a comprehensive analysis of all these data, possible explanations for the changes in groundwater levels were considered.Article Citation - WoS: 2Citation - Scopus: 2Enrichment of Turkish Question Answering Systems Using Knowledge Graphs(Tubitak Scientific & Technological Research Council Turkey, 2024) Tekir, Selma; Soygazi, Fatih; Tekir, Selma; 03.04. Department of Computer Engineering; 03. Faculty of Engineering; 01. Izmir Institute of TechnologyRecent capabilities of large language models (LLMs) have transformed many tasks in Natural Language Processing (NLP), including question answering. The state-of-the-art systems do an excellent job of responding in a relevant, persuasive way but cannot guarantee factuality. Knowledge graphs, representing facts as triplets, can be valuable for avoiding errors and inconsistencies with real-world facts. This work introduces a knowledge graph-based approach to Turkish question answering. The proposed approach aims to develop a methodology capable of drawing inferences from a knowledge graph to answer complex multihop questions. We construct the Beyazperde Movie Knowledge Graph (BPMovieKG) and the Turkish Movie Question Answering dataset (TRMQA) to answer questions in the movie domain. We evaluate our proposed question answering pipeline against a baseline study. Furthermore, we compare it with a question answering system built upon GPT-3.5 Turbo to answer the 1-hop questions from TRMQA. The experimental results confirm that link prediction on a knowledge graph is quite effective in answering questions that require reasoning paths. Finally, we provide insights into the pros and cons of the provided solution through a qualitative study.Article Selective Catalytic Hydrogenation of Cellulose Into Sorbitol With Ru-Based Catalysts(Tubitak Scientific & Technological Research Council Turkey, 2022) Orak, Ceren; Orak, Ceren; Yüksel Özsen, Aslı; 01. Izmir Institute of TechnologySorbitol is one of the platform chemicals and can be produced from various renewable and sustainable sources via different processes. Hydrothermal liquefaction is an effective and promising approach to produce sorbitol, since the subcritical reaction media and appropriate catalysts provide a selective production of platform chemicals. In this study, sorbitol was produced from different renewable sources (cellulose and glucose) in the presence of Ru-based catalysts (Ru/SiO2, Ru/AC, Ru/SBA-15, and Ru/SBA-15-SO3) under subcritical conditions. The highest cellulose conversion was achieved as 90% in the presence of Ru/SBA-15-SO3 for 1 h of reaction duration. The highest sorbitol yield (%) by hydrothermal liquefaction of cellulose was obtained as 6.2% by using Ru/AC for 1 h of reaction duration. A total of 99.9% of glucose conversion was achieved in the presence of all catalysts. The highest sorbitol yield (%) by hydrothermal liquefaction of glucose was found as 3.8% for 1 h of reaction duration. Owing to the results of GC-MS analysis, the intermediate products were identified, and, thus, a reaction pathway was proposed.