WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7150
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Article Citation - WoS: 20Citation - Scopus: 24Lime-Activated One-Part Geopolymer Mortars From Construction, Demolition and Industrial Wastes(Elsevier, 2024) Kogbara, Reginald B.; Al-Zubi, Abdelrahman; Mortada, Youssef; Hammoud, Ahmad; Masad, Eyad A.; Khraisheh, Marwan K.This work focused on the production of one-part geopolymer mortars from construction and demolition wastes (CDW) blended with steel slag. Previous related studies on geopolymer production from CDW utilized conventional two-part geopolymers comprised of highly alkaline activator solutions and CDW materials. Thus, the study's significance consists in producing high-strength (≥35 MPa) ambient-cured mortars from CDW with predominantly concrete waste by replacing conventional highly alkaline activator solutions with an environmentally-friendly alkaline activator, Ca(OH)2 powder. Four mortar mixtures were produced with CDW contents ranging from 50 to 65 % dry weight, varying the brick waste content from 3 to 18 %. The effect of elevated temperature (40 °C) curing was also considered. The results showed that 55 % CDW content had optimum performance across all parameters studied such as compressive and flexural strengths, setting time, as well as changes in nuclear magnetic resonance (NMR)-determined pore structure (porosity and mean pore size) and x-ray diffraction (XRD)-determined degree of crystallinity over time. It had 28-day compressive and flexural strengths of 42 and 5.8 MPa, respectively, and initial and final setting times of 25 and 50 min. The importance of sufficient brick waste content in the geopolymer mixtures for effective mechanical performance is highlighted. The inclusion of concrete waste in powder form reduced compressive strength under ambient curing but improved performance at 40 °C curing. It is concluded that sustainable structural mortars can be produced by ‘just adding water’ to an optimized CDW mixture with predominantly concrete waste blended with brick waste and slag and activated by powdered Ca(OH)2. © 2023 The AuthorsArticle Citation - WoS: 101Citation - Scopus: 105Defect-Engineering Agsbte2 With High Thermoelectric Performance(Wiley, 2023) Zhang, Yu; Li, Zhi; Singh, Saurabh; Nozariasbmarz, Amin; Li, Wenjie; Genç, Aziz; Xia, YiThermoelectric (TE) generators enable the direct and reversible conversion between heat and electricity, providing applications in both refrigeration and power generation. In the last decade, several TE materials with relatively high figures of merit (zT) have been reported in the low- and high-temperature regimes. However, there is an urgent demand for high-performance TE materials working in the mid-temperature range (400–700 K). Herein, p-type AgSbTe2 materials stabilized with S and Se co-doping are demonstrated to exhibit an outstanding maximum figure of merit (zTmax) of 2.3 at 673 K and an average figure of merit (zTave) of 1.59 over the wide temperature range of 300–673 K. This exceptional performance arises from an enhanced carrier density resulting from a higher concentration of silver vacancies, a vastly improved Seebeck coefficient enabled by the flattening of the valence band maximum and the inhibited formation of n-type Ag2Te, and ahighly improved stability beyond 673 K. The optimized material is used to fabricate a single-leg device with efficiencies up to 13.3% and a unicouple TE device reaching energy conversion efficiencies up to 12.3% at a temperature difference of 370 K. These results highlight an effective strategy to engineer high-performance TE material in the mid-temperature range.Article Citation - WoS: 21Citation - Scopus: 23Engineering of Xylanases for the Development of Biotechnologically Important Characteristics(Wiley, 2023) Sürmeli, Yusuf; Şanlı Mohamed, GülşahXylanases are the main biocatalysts used for the reduction of the xylan backbone from hemicellulose, randomly splitting off β-1,4-glycosidic linkages between xylopyranosyl residues. Xylanase market has been annually estimated at 500 million US Dollars and they are potentially used in broad industrial process ranges such as paper pulp biobleaching, xylo-oligosaccharide production, and biofuel manufacture from lignocellulose. The highly stable xylanases are preferred in the downstream procedure of industrial processes because they can tolerate severe conditions. Almost all native xylanases can not endure adverse conditions thus they are industrially not proper to be utilized. Protein engineering is a powerful technology for developing xylanases, which can effectively work in adverse conditions and can meet requirements for industrial processes. This study considered state-of-the-art strategies of protein engineering for creating the xylanase gene diversity, high-throughput screening systems toward upgraded traits of the xylanases, and the prediction and comprehensive analysis of the target mutations in xylanases by in silico methods. Also, key molecular factors have been elucidated for industrial characteristics (alkaliphilic enhancement, thermal stability, and catalytic performance) of GH11 family xylanases. The present review explores industrial characteristics improved by directed evolution, rational design, and semi-rational design as protein engineering approaches for pulp bleaching process, xylooligosaccharides production, and biorefinery & bioenergy production.Article Citation - WoS: 77Citation - Scopus: 95Thermal, Daylight, and Energy Potential of Building-Integrated Photovoltaic (bipv) Systems: a Comprehensive Review of Effects and Developments(Elsevier, 2023) Taşer, Aybüke; Kundakçı Koyunbaba, Başak; Kazanasmaz, Zehra TuğçeAccording to energy consumption data of the European Union, buildings account for 40 % of overall energy consumption in all sectors. The rise in building energy demand seriously affects global warming. To reduce demand, buildings must be designed to be energy-efficient. As part of energy-efficiency initiatives, unique systems that employ renewable energy sources should be implemented in buildings. As a new technology, building-integrated photovoltaics is considered an essential technology to achieve this target. Several variables affect the thermal, daylight, and energy performance of building-integrated photovoltaic systems; related to environmental and photovoltaic-related parameters. Thus, the challenges and effects of these variables on the overall performance of these systems should be investigated. This research analyzes building-integrated photovoltaic implemented studies and presents a state-of-art review of recent developments. The study not only summarizes the existing studies developed in this field so far but also analyzes the variables and makes concrete generalizations and inferences. It enables finding gaps and deficiencies in the literature and provides a better understanding of all the variables that affect the performance of building-integrated photovoltaic systems by interpreting the results in detail and representing them graphically instead of only through textual analysis. Results show that building-integrated photovoltaics contribute to constructing a sustainable future for cities. Developments in this industry motivate researchers in this field, whose work will make it easier to cope with future ecological challenges. It helps to build a more sustainable future for society. With new developments, it will be possible to mitigate the effects of future environmental problems.Article Citation - WoS: 25Citation - Scopus: 38Biodiversity: the Overlooked Source of Human Health(Elsevier, 2023) Linhares, Yuliya; Kaganski, Alexander; Agyare, Christian; Aksan Kurnaz, Işıl; Neergheen, Vidushi; Kolodziejczyk, Bartlomiej; Baran, YusufBiodiversity is the measure of the variation of lifeforms in a given ecological system. Biodiversity provides ecosystems with the robustness, stability, and resilience that sustains them. This is ultimately essential for our survival because we depend on the services that natural ecosystems provide (food, fresh water, air, climate, and medicine). Despite this, human activity is driving an unprecedented rate of biodiversity decline, which may jeopardize the life-support systems of the planet if no urgent action is taken. In this article we show why biodiversity is essential for human health. We raise our case and focus on the biomedicine services that are enabled by biodiversity, and we present known and novel approaches to promote biodiversity conservation.Article Citation - WoS: 29Citation - Scopus: 33The Effect of Heat Transfer Characteristics of Macromolecule Fouling on Heat Exchanger Surface: a Dynamic Simulation Study(Wiley, 2023) Karimi Shoar, Zahra; Pourpasha, Hadi; Zeinali Heris, Saeed; Mousavi, Seyed Borhan; Mohammadpourfard, MousaAt the city gate gas pressure reduction stations (CGSs), to prevent natural gas from forming a hydrate in the throttle valve, the natural gas is heated by the heater before reaching the pressure relief valve. Heat exchangers are an essential component of industrial processes that contribute significantly to total system energy. Since the element impacting heat exchanger performance is the fouling process, all fouling processes and models were dynamically simulated in this study. Through coding in the C++ language and simultaneous use of fluent functions, or, in other words, user-defined function (UDF), fouling-related models were defined for this software. The dynamic simulation was performed, and parameters such as fouling strength and layer thickness were calculated. The effects of changing operating conditions, such as gas inlet velocity, surface temperature, and fouling species concentration on fouling growth, were also evaluated. As the concentration of fouling species increased, the fouling rate also increased. The amount of supersaturation and fouling rate increased as the surface temperature increased. Due to the operational limitations of the system, to reduce the fouling rate, the gas inlet velocity should be as high as possible, and the fluid inlet temperature, surface temperature, and concentration of fouling species should be as low as possible. In this study, the required time to reach the efficiency of 70% of the heat exchanger was calculated using the modelling of this chamber, which was equivalent to 190 days. Additionally, the critical thickness of the fouling layer at this time was 3.5 cm.Article Impact of Titania Phase Structure and Surface Reactivity on the Photocatalytic Degradation of Various Dyes and Textile Wastewater(National Institute of Science Communication and Policy Research, 2023) Yurtsever, Hüsnü Arda; İloğlu, Onur; Çiftçioğlu, MuhsinTitania (TiO2) powders have been prepared by precipitation method in different precipitation media which contain sulfate, nitrate or organic species. Photocatalytic degradation of different dyes and a real textile wastewater have been conducted with these powders along with commercial powder Degussa P25 for comparison. Ethyl alcohol (organic medium), sulfuric acid (sulfate medium) and nitric acid (nitrate medium) have been used to dissolve titanium precursor for the precipitation of TiO2 in ammonia solution. UV-Vis DRS and XPS results indicate that S doping in sulfate medium precipitated powder and N doping in nitrate medium precipitated powder has been occurred and the presence of S or N containing impurities on the grain boundaries have been improved light absorption of TiO2 significantly. However, these powders have exhibited low surface reactivities. The highest surface reactivity has been obtained with the powder precipitated in organic medium which also has the highest crystallite sizes (76 nm rutile and 34 nm anatase crystallites) with relatively low rutile weight percentage (10.0%). The surface-normalized rate constants of this powder are 0.02038 min-1.m-2 in real textile wastewater degradation and 0.0161 min-1.m-2 in methyl orange degradation, which are 0.01563 and 0.0091 min-1.m-2, respectively, for Degussa P25. Results have shown that this powder show 30-70% higher surface reactivities compared to Degussa P25. The main structural difference of organic medium precipitated powder and Degussa P25 has been found to be the anatase-rutile weight ratio and crystallite size of rutile phase whereas band gap energy of Degussa P25 is lower and other properties are not significantly different.Article Citation - WoS: 2Citation - Scopus: 2Tuning the Solid Phase Fluorescence Emission From Long Wavelength Visible To Near-Infrared in Oxazol-5 Derivatives: Structure–property Relationship, Theoretical and Experimental Studies(Springer, 2023) Nazlı, İbrahim Hanif; Yakalı, Gül; Topkaya, Derya; İzmirli, Merve; Uzun, Sema Demirci; Alp, SerapMost of the fluorescent molecules among organic π-conjugated materials show blue or green emission in the solid phase but few of them emit red-shifted visible and near-infrared light in the material science. To create molecules emitting for this feature, two π-conjugated oxazol-5-one derivatives containing donor (OCH3) and acceptor groups (NO2) were synthesized. Their optical and charge-transport properties were investigated through experimental and theoretical methods including the single crystal X-ray crystallography, Hirshfeld Surface Analysis, photophysical studies and Density Functional Theory (DFT), respectively. In addition, FT-IR, 1H-NMR, 13C-NMR spectroscopy, cyclic voltammetry (CV) measurements were performed. According to our results, both molecules may provide the significant pathway of development of long wavelength visible and red emissive features in solid phase with the aggregation induced enhanced emission (AIEE) properties particularly in the fields of OLEDs, optical communication, defence and bioimaging.Article Citation - WoS: 15Citation - Scopus: 15The Effect of Strain Rate on the Compression Behavior of Additively Manufactured Short Carbon Fiber-Reinforced Polyamide Composites With Different Layer Heights, Infill Patterns, and Built Angles(Springer, 2023) Zeybek, Mehmet Kaan; Güden, Mustafa; Taşdemirci, AlperPrevious studies on the fused deposition modelling (FDM) processed short carbon fiber/Polyamide 6 (PA6) matrix composites and neat PA6 have mostly concentrated on the quasi-static mechanical properties. Present study focused on the strain rate-dependent deformation behavior of a short carbon fiber-reinforced PA6 (Onyx) and neat PA6, produced in different layer heights, infill patterns and built angles. As compared with PA6, Onyx showed a higher compression stress at all strain rates investigated. A layer height of 0.2 mm in PA6 specimens promoted a better bonding between [0/90°] infill layers; hence, a higher flow stress than 0.2 mm layer height specimens, while 0.2 mm layer height induced a higher porosity in Onyx specimens, leading to a lower flow stress. The porosities in Onyx [0/90°] infill specimens were due to the constraining effect of 0/90° fiber layers. Changing infill pattern from a [0/90°] to a concentric one decreased porosity at the same layer height and hence increased the compressive flow stress. The highest compressive strength was found in the specimens with the loading axis 90 and 0° to [0/90°] infill plane. The lowest strength was, however, determined in the specimens with the loading axis 30 and 60o to [0/90°] infill plane in quasi-static loading. However, the specimens with the loading axis of 60, 45, 30 and 0° exhibited a brittle behavior in high strain rate loading (1500 s−1). The specimens with the loading axis of 45° had the lowest fracture stress and strain in the high strain rate loading. This signified the importance of loading angle at high strain rates. Finally, the rate sensitivities of PA6 and Onyx specimens were shown to be similar, showing a matrix dominated deformation. However, the strain rate jump tests indicated a slightly higher rate sensitivity of Onyx specimens at quasi-static strain rates (10−3-10−1 s−1).Article Citation - WoS: 1Citation - Scopus: 1Thermodynamic Re-Assessment of a Geothermal Binary Power Plant Operated in a Moderate-Temperature Geothermal Field(Inderscience, 2023) Özcan, Zeynep; Gökçen Akkurt, GüldenAn existing organic rankine cycle power plant which uses isobutane as working fluid is re-evaluated for different working fluids. The plant is first modelled by EES software; then the model is simulated for different working fluids obtaining heat transferred through the heat exchanger, net work output, energy and exergy efficiencies, and mass flowrate of the working fluid. Two parametric studies are conducted to evaluate the thermodynamic performance of the plant under a range of turbine inlet temperature (130°C–155°C) and geothermal resource temperature (152°C–161°C) for each working fluid. The study reveals that the highest cycle energy and exergy efficiencies are observed for R-152a at any geothermal resource temperature. R-152a resulted with 13.1% and 58.2% cycle energy and exergy efficiency, respectively at operation condition, whilst the lowest efficiency and net work output is calculated under n-butane presence.