WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7150
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Article Citation - WoS: 20Citation - Scopus: 24Lime-Activated One-Part Geopolymer Mortars From Construction, Demolition and Industrial Wastes(Elsevier, 2024) Kogbara, Reginald B.; Al-Zubi, Abdelrahman; Mortada, Youssef; Hammoud, Ahmad; Masad, Eyad A.; Khraisheh, Marwan K.This work focused on the production of one-part geopolymer mortars from construction and demolition wastes (CDW) blended with steel slag. Previous related studies on geopolymer production from CDW utilized conventional two-part geopolymers comprised of highly alkaline activator solutions and CDW materials. Thus, the study's significance consists in producing high-strength (≥35 MPa) ambient-cured mortars from CDW with predominantly concrete waste by replacing conventional highly alkaline activator solutions with an environmentally-friendly alkaline activator, Ca(OH)2 powder. Four mortar mixtures were produced with CDW contents ranging from 50 to 65 % dry weight, varying the brick waste content from 3 to 18 %. The effect of elevated temperature (40 °C) curing was also considered. The results showed that 55 % CDW content had optimum performance across all parameters studied such as compressive and flexural strengths, setting time, as well as changes in nuclear magnetic resonance (NMR)-determined pore structure (porosity and mean pore size) and x-ray diffraction (XRD)-determined degree of crystallinity over time. It had 28-day compressive and flexural strengths of 42 and 5.8 MPa, respectively, and initial and final setting times of 25 and 50 min. The importance of sufficient brick waste content in the geopolymer mixtures for effective mechanical performance is highlighted. The inclusion of concrete waste in powder form reduced compressive strength under ambient curing but improved performance at 40 °C curing. It is concluded that sustainable structural mortars can be produced by ‘just adding water’ to an optimized CDW mixture with predominantly concrete waste blended with brick waste and slag and activated by powdered Ca(OH)2. © 2023 The AuthorsArticle Citation - WoS: 77Citation - Scopus: 95Thermal, Daylight, and Energy Potential of Building-Integrated Photovoltaic (bipv) Systems: a Comprehensive Review of Effects and Developments(Elsevier, 2023) Taşer, Aybüke; Kundakçı Koyunbaba, Başak; Kazanasmaz, Zehra TuğçeAccording to energy consumption data of the European Union, buildings account for 40 % of overall energy consumption in all sectors. The rise in building energy demand seriously affects global warming. To reduce demand, buildings must be designed to be energy-efficient. As part of energy-efficiency initiatives, unique systems that employ renewable energy sources should be implemented in buildings. As a new technology, building-integrated photovoltaics is considered an essential technology to achieve this target. Several variables affect the thermal, daylight, and energy performance of building-integrated photovoltaic systems; related to environmental and photovoltaic-related parameters. Thus, the challenges and effects of these variables on the overall performance of these systems should be investigated. This research analyzes building-integrated photovoltaic implemented studies and presents a state-of-art review of recent developments. The study not only summarizes the existing studies developed in this field so far but also analyzes the variables and makes concrete generalizations and inferences. It enables finding gaps and deficiencies in the literature and provides a better understanding of all the variables that affect the performance of building-integrated photovoltaic systems by interpreting the results in detail and representing them graphically instead of only through textual analysis. Results show that building-integrated photovoltaics contribute to constructing a sustainable future for cities. Developments in this industry motivate researchers in this field, whose work will make it easier to cope with future ecological challenges. It helps to build a more sustainable future for society. With new developments, it will be possible to mitigate the effects of future environmental problems.Article Citation - WoS: 25Citation - Scopus: 38Biodiversity: the Overlooked Source of Human Health(Elsevier, 2023) Linhares, Yuliya; Kaganski, Alexander; Agyare, Christian; Aksan Kurnaz, Işıl; Neergheen, Vidushi; Kolodziejczyk, Bartlomiej; Baran, YusufBiodiversity is the measure of the variation of lifeforms in a given ecological system. Biodiversity provides ecosystems with the robustness, stability, and resilience that sustains them. This is ultimately essential for our survival because we depend on the services that natural ecosystems provide (food, fresh water, air, climate, and medicine). Despite this, human activity is driving an unprecedented rate of biodiversity decline, which may jeopardize the life-support systems of the planet if no urgent action is taken. In this article we show why biodiversity is essential for human health. We raise our case and focus on the biomedicine services that are enabled by biodiversity, and we present known and novel approaches to promote biodiversity conservation.Article Citation - WoS: 5Citation - Scopus: 5Screening Diatom Strains Belonging To Cyclotella Genus for Chitin Nanofiber Production Under Photobioreactor Conditions: Chitin Productivity and Characterization of Physicochemical Properties(Elsevier, 2023) Özkan, AltanDiatom species belonging to Cyclotella and Thalassiosira genera have the unique and industrially relevant ability to biosynthesize and extrude pure chitin nanofibers. The current understanding of diatom-based chitin production is narrowed by the complete reliance on the performance of a single strain. This study aims to facilitate the development of a wider understanding for enhanced industrial utility. For this purpose, six Cyclotella strains were cultivated under standardized process conditions of a bubble column photobioreactor, and the resulting productions were characterized in terms of rate and physicochemical properties. A two-stage cultivation protocol was followed where the cells were cultivated under silicon replete and then following its complete consumption under silicon deplete conditions. All the strains produced chitin fibers of β-form with relatively constant average diameters, ranging from 48 to 58 nm. Chitin production rates and final concentrations as well as fiber number densities and length distributions were highly strain-dependent. Dissolved silicon availability controlled chitin biosynthesis: following its depletion, the productivity of all the strains increased drastically. Two strains of marine origin, C. cryptica CCMP 332 and C. cryptica CCMP 333, generated the most favorable outcomes for commercial-scale production and had final concentrations of 272 ± 9 mg/L and 316 ± 12 mg/L, and maximum production rates of 48 ± 2 mg/L-day and 51 ± 2 mg/L-day, respectively. The superior performance of these strains was due to (i) the extrusion of more fibers per fiber port, in the case of C. cryptica CCMP 333 as many as 20.7 ± 1.0. indicating free fiber accumulation in suspension, and (ii) the biosynthesis of longer fibers, mean fiber lengths varied from 15 to 20 μm during cultivation. This study demonstrates the importance of species selection and silicon availability for diatom-based chitin production in terms of rate, final concentration, and nanofiber fiber length distributions.Article Citation - WoS: 31Citation - Scopus: 34Insights Into Engineered Graphitic Carbon Nitride Quantum Dots for Hazardous Contaminants Degradation in Wastewater(Elsevier, 2023) Gören, Ayşegül Yağmur; Recepoğlu, Yaşar Kemal; Vatanpour, Vahid; Yoon, Yeojoon; Khataee, AlirezaIncreased environmental pollution is a critical issue that must be addressed. Photocatalytic, adsorption, and membrane filtration methods are suitable in environmental governance because of their high selectivity, low cost, environment-friendly nature, and excellent treatment efficiency. Graphitic carbon nitride (g-C3N4) quantum dots (QDs) have been considered as photocatalysts, adsorbents, and membrane materials for wastewater treatments, owing to their stability, adsorption capacity, photochemical properties, and low toxicity and cost. This review summarizes g-C3N4 QD synthesis techniques, operating parameters affecting the removal performance in the treatment process, modification effects with other semiconductors, and benefits and drawbacks of g-C3N4 QD-based materials. Furthermore, this review discusses the practical applications of g-C3N4 QDs as adsorbents, photocatalysts, and membrane materials for organic and inorganic contaminant treatments and their value-added product formation potential. Modified g-C3N4 QD-based material adsorbents, photocatalysts, and membranes present potentially applicable effects, such as removal of most waterborne contaminants. Excellent results were obtained for the reduction of methyl orange, bisphenol A, tetracycline, ciprofloxacin, phenol, rhodamine B, E. coli, and Hg. Overall, this paper provides comprehensive background on g-C3N4 QD-based materials and their diverse applications in wastewater treatment, and it presents a foundation for the enhancement of similar unique materials in the future.Article Citation - WoS: 7Citation - Scopus: 7Neo-Clerodanes From Teucrium Divaricatum Subsp. Divaricatum and Their Biological Activity Assessment(Elsevier, 2023) Aydoğan, Fadime; Ali, Zülfiqar; Zülfiqar, Fazila; Karaalp, Canan; Khan, Ikhlas A.; Bedir, ErdalFifteen neo-clerodane diterpenoids (1–15), including two undescribed glycosides, teudivaricosides A (1) and B (2), together with a known iridoid glycoside (16) and a phenylpropanoid glycoside (17) from the whole plant of Teucrium divaricatum subsp. divaricatum were isolated. Their structures were determined by spectral data analysis including 1D and 2D NMR and HRESIMS. Neo-clerodane diterpenoids were evaluated for their anti-inflammatory, and antimicrobial activities. None of them showed significant antimicrobial activity against various bacterial and fungal strains (up to 20 µg/mL). All tested compounds were inactive up to the highest tested concentration of 50 µM on iNOS inhibitory activity.Article Citation - WoS: 3Citation - Scopus: 3Stable Single Layer Structures of Aluminum Oxide: Vibrational and Electronic Characterization of Magnetic Phases(Elsevier, 2022) Özyurt, A. Kutay; Molavali, Deniz; Şahin, HasanThe structural, magnetic, vibrational and electronic properties of single layer aluminum oxide (AlO2) are investigated by performing state-of-the-art first-principles calculations. Total energy optimization and phonon calculations reveal that aluminum oxide forms a distorted octahedral structure (1T′-AlO2) in its single layer limit. It is also shown that surfaces of 1T′-AlO2 display magnetic behavior originating from the O atoms. While the ferromagnetic (FM) state is the most favorable magnetic order for 1T′-AlO2, transformation to a dynamically stable antiferromagnetic (AFM) state upon a slight distortion in the crystal structure is also possible. It is also shown that Raman activities (350–400 cm−1) obtained from the vibrational spectrum can be utilized to distinguish the possible magnetic phases of the crystal structure. Electronically, both FM and the AFM phases are semiconductors with an indirect band gap and they can form a type-III vdW heterojunction with graphene-like ultra-thin materials. Moreover, it is predicted that presence of oxygen defects that inevitably occur during synthesis and production do not alter the magnetic state, even at high vacancy density. Apparently, ultra-thin 1T′-AlO2 with its stable crystal structure, semiconducting nature and robust magnetic state is a quite promising material for nanoscale device applications.Article Citation - WoS: 4Citation - Scopus: 4Identification of a Magnetic Phase Via a Raman Spectrum in Single-Layer Mnse: an Ab Initio Study(Elsevier, 2022) Yayak, Yankı Öncü; Şahin, Hasan; Yağmurcukardeş, MehmetMotivated by the recent experimental realization of single-layer two-dimensional MnSe [ACS Nano2021, 15, 13794-13802], structural, magnetic, elastic, vibrational, and electronic properties of single-layer MnSe are investigated by using density functional theory-based calculations. Among four different magnetic phases, namely, ferromagnetic (FM) and Nẽel-, zigzag-, and stripy-antiferromagnetic (AFM) phases, the Nẽel-AFM structure is found to be the energetically most favorable phase. Structural optimizations show the formation of in-plane anisotropy within the structures of zigzag- and stripy-AFM phases in single-layer MnSe. For the dynamically stable four magnetic phases, predicted Raman spectra reveal that each phase exhibits distinctive vibrational features and can be distinguished from each other. In addition, the elastic constants indicate the mechanical stability of each magnetic phase in single-layer MnSe and reveal the soft nature of each phase. Moreover, electronic band dispersion calculations show the indirect band gap semiconducting nature with varying electronic band gap energies for all magnetic phases. Furthermore, the atomic orbital-based density of states reveals the existence of out-of-plane orbitals dominating the top valence states in zigzag- and stripy-AFM phases, giving rise to the localized states. The stability of different magnetic phases and their distinct vibrational and electronic properties make single-layer MnSe a promising candidate for nanoelectronic and spintronic applications.Article Citation - WoS: 2Citation - Scopus: 2Hellenistic Masonry Techniques in Southern and Western Anatolia(Elsevier, 2022) Gençer, Funda; Hamamcıoğlu Turan, MineVarious Hellenistic masonry wall classifications have been given for Egypt, Greece, Persia, Phoenicia, Anatolia, etc., in literature. However, it is hardly possible to classify all masonry types in Anatolia because it varies regionally and has unique qualities. An important subject of research is what causes this diversity. Thus, this study aims to identify the original wall configurations and facings as well as the factors that define these structures by examining the undocumented walls in Anatolia's western and southern regions. Anatolian-specific composite techniques will be deciphered. The masonry techniques used in the walls of Caria, Lycia, and Pamphylia Regions, which are rich in examples of Hellenistic city walls, in the Western and Southern coasts of Asia Minor are compared in terms of their arrangement of blocks, wall profiles, and finishing of the faces. The first step of the method is a literature survey for determining the distribution of Hellenistic masonry walls in Anatolia. This was followed by a preliminary site survey. The dry-joint masonry walls that have sustained their authenticity and remain that have traces of their original composition were selected for accurate examination. Walls in Latmos, Alinda, Alabanda, Tekekale, Myndos in Caria; Sillyum, Side, and Perge in Pamphylia; and Oenoando and Isium in Lycia were examined. Their construction techniques and material usage were determined with the measured survey, visual analysis, and laboratory analysis. Also, the documented masonry patterns were compared with the masonry arrangements in different geographies of the world. Consequently, this study demonstrates that different masonry arrangements emerged in Anatolia as a result of varieties in the local environment. There are unique composite examples of integrating polygonal and ashlar leaves with headers and squat blocks in Anatolia.Article Citation - WoS: 4Citation - Scopus: 4Destratification of Thermally Stratified Water Columns by Air Diffusers(Elsevier, 2023) Elçi, Şebnem; Hazar, Oğuz; Bahadıroğlu, Nisa; Karakaya, Derya; Bor, AslıThis study aims at improving the understanding in order to optimise an aeration system for artificial destratification to control cyanobacteria growth in the reservoirs. Previous applications for artificial destratification in reservoirs were based on installations based on computational methods, where neither the effect of air bubble size and configuration nor the effect of air density in the bubble plume could be investigated. This study seeks for an optimized design with the help of experimental and numerical analyses. In order to perform experimental studies, a novel water tank enabling the heating/cooling of the water column as desired and a diffuser system were manufactured. During the experimental studies, effect of bubble size, bubble slip velocity, and other parameters of air diffuser on destratification efficiency were investigated. Based on the nondimensional parameters, a new destratification efficiency formula is obtained by the Genetic Algorithm (GA) approach. Additionaly, the hydrodynamics of the water tank during the mixing process by air diffuser was simulated via 3D numerical model and validated with experimental results. The Eulerian multiphase model with the ‘degassing’ boundary condition and k-ω turbulence model are found to be suitable for the purposes of the study. Based on the error analysis of comparisons of the model and observations, the best configuration of air diffuser is proposed, and the numerical model is found to be successful in simulating the destratification of thermally stratified water columns by air diffuser.