WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7150
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Article Citation - WoS: 1Citation - Scopus: 1Profiling the Bacterial Diversity in Historic Limestone From Anazarbos Archaeological Site by Advanced Molecular and Spectroscopic Techniques(University of the Aegean, 2022) Aydın, Rozelin; İpekci, Emre; Daday, Mine Taykurt; Yüceer, Hülya; Böke, HasanThe architectural remains as well as sculptures, mosaics, and other artifacts in the archaeological sites are mostly made of stone and susceptible to biodeterioration by microorganisms. Bacterial communities are known to have the most effective role in biological deterioration in stones. The ancient city of Anazarbos (Anavarza), chosen as the study area, is the 1st Degree Archaeological Site in the vicinity of Dilekkaya Village, Kozan District, about 70 km north of Adana. The microbiological, chemical, mineralogical, and microstructural properties of stone samples taken from different places were studied in this research. Samples were taken from i) where no deterioration occurred, ii) where different forms of deterioration were observed, iii) archaeological deposits, iii) archaeological deposits that came from deteriorated stone samples area. Spectroscopic, thermal, and microscopic techniques applied included: X-Ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy-Energy Dispersive System (SEM-EDS), Thermogravimetric Analysis/Differential Thermal Analysis (TG/DTA). The bacterial biodiversity was analyzed by the application of Illumina-based next-generation sequencing methods. Results show intense biological colonisations with clay minerals on limestone surfaces. A patina of clay minerals was observed on newly excavated stone surfaces, while biological colonisations have not yet intensified. The metabarcoding analysis showed 15 bacterial phyla. The Proteobacteria and Actinobacteria were the most abundant phyla in both stones and archaeological deposits samples. Human activity (intensive agriculture, animal husbandry), accumulation of rainwater in excavated areas adversely affects stones, which leads to acceleration of biological deterioration in stones. Thus, all features of the site require multi-faceted studies prior to unearthing of archaeological remains.Article Citation - WoS: 27Citation - Scopus: 28Lime Mortar Technology in Ancient Eastern Roman Provinces(Elsevier, 2021) Uğurlu Sağın, Elif; Duran, Hasan Engin; Böke, HasanNatural pozzolanic aggregates were discovered during the Roman era and have been widely used in hydraulic mortar production. Despite the claims of ancient treatises, the properties of pozzolans and the technology of hydraulic lime mortars were well known and applied in the eastern provinces of the Roman Empire. In this study, the characteristics of lime mortar at the ancient sites of Aigai and Nysa located in Western Anatolia were investigated to elicit the technology applied. The raw material compositions of the mortars, the hydraulic properties of the binders, and the mineralogical and chemical compositions of the natural pozzolans used were determined via X-ray diffraction, X-ray fluorescence spectroscopy, scanning electron microscopy coupled with energy dispersive spectroscopy, and thermogravimetric analysis. The major and trace element compositions of the natural pozzolans were evaluated via multivariate statistical analysis to determine whether the same local raw material resources were used in their manufacture. The analytical results indicated that the Roman mortars were hydraulic, stiff, and durable materials due to the use of natural pozzolanic aggregates mostly comprising dacite. Although the aggregates had similar mineralogical compositions, multivariate statistical analysis revealed that their chemical compositions were clearly distinguishable, indicating the use of different sources of raw materials. Thus, it was inferred that similar pozzolan resources were known and deliberately used to produce hydraulic mortars in the eastern ancient Roman provinces.Article Citation - WoS: 171Characteristics of Brick Used as Aggregate in Historic Brick-Lime Mortars and Plasters(Elsevier Ltd., 2006) Böke, Hasan; Akkurt, Sedat; İpekoğlu, Başak; Uğurlu, ElifMortars and plasters composed of a mixture of brick powder and lime have been used since ancient times due to their hydraulic properties. In this study, raw material compositions, basic physical, mineralogical, microstructural and hydraulic properties of some historic Ottoman Bath brick-lime mortars and plasters were determined by XRD, SEM-EDS, AFM, TGA and chemical analyses. The mineralogical and chemical compositions, microstructures, morphologies and pozzolanicities of the brick powders and fragments used as aggregates in the mortars and plasters were examined to find out the relationship between hydraulic properties of the mortars and the bricks. The characteristics of bricks used in the bath domes were also determined to investigate whether the brick aggregates used in mortar and plasters were prepared from these bricks. The results indicated that the mortars and plasters were hydraulic owing to the presence of crushed brick powders that have good pozzolanicity. The brick powders bad high pozzolanicity because they contained high amounts of calcium-poor clay minerals in their raw materials that were fired at low temperatures. On the other hand, bricks used in the domes had poor pozzolanicity with different mineralogical and chemical compositions from bricks used in mortars and plasters. Based on the results of the analysis, it was thought that the bricks manufactured with high amounts of clays were consciously chosen in the preparation of hydraulic mortars and plasters. (C) 2006 Elsevier Ltd. All rights reserved.Article Citation - WoS: 20Citation - Scopus: 21Long Term Stability of Biodegradable Polymers on Building Limestone(Elsevier Ltd., 2019) Kaplan, Zişan; Böke, Hasan; Sofuoğlu, Aysun; İpekoğlu, BaşakSynthetic polymers can be replaced by biodegradable ones as adhesives, water repellents and consolidants on the stone surfaces and facades of the historic buildings in their conservation to minimize future deterioration. In this study, the long-term stability of two biodegradable polymers, polyhydroxybutyrate (PHB) and poly-L-lactide (PLA), and an acrylic polymer (Paraloid B72) which is commonly used in conservation works of artefacts, were evaluated on limestone using a UV lamp-weathering chamber (up to 104 days) for future protection studies. Chemical and morphological changes induced by an accelerated weathering test were examined by Fourier Transform Infrared spectroscopy (FT-IR) and Scanning Electron Microscopy (SEM) analyses. Protection efficiency of the polymers was determined by the changes in color, capillary water absorption, static contact angle on limestone. Paraloid B72, PHB, and PLA coatings significantly increased hydrophobicity while decreasing capillarity water absorption and caused negligible change in the color of the limestone. Protection efficiencies of PLA and PHB polymers were almost the same as that of Paraloid B72, a widely used acrylic polymer. However, PLA and PHB seemed to be favorable polymers as protective agents due to their reversibility and biodegradability, low chromatic changes, good hydrophobic behavior and good stability to weathering in reducing the effects of outdoor exposure on limestone surfaces.Article Citation - WoS: 8Citation - Scopus: 10Interior Plastering of Ottoman Bath Buildings(Elsevier Ltd., 2019) İpekci, Emre; Uğurlu Sağın, Elif; Böke, HasanOttoman baths were peculiar buildings with their function in community life, architectural characteristics and material use. Their interior spaces were exposed to high humidity and temperatures that made the building structure vulnerable to physical, chemical, physicochemical and biological degradations. Plasters used on the interior wall surfaces were the most important agents to protect the structure from deterioration and provide durability. This study aims to exhibit the plaster characteristics of Çinili Bath in İstanbul which was an outstanding example of Ottoman baths and built by Great Architect Sinan. Basic physical properties, raw material compositions, mineralogical, microstructural and hydraulic properties of original brick-lime plasters called as horasan (khorasan) plasters used on the walls were determined by XRF, XRD, SEM-EDS and TGA. Multilayered plaster application together with the use of glazed tiles were observed on the wall surfaces of all interior spaces. The plasters were produced from pure lime and pozzolanic crushed brick or tile aggregates and hydraulic because of the pozzolanic properties of aggregates. They are stiff, compact and durable in hot and humid conditions of bath buildings due to their self-healing properties and the formation of calcium silicate hydrates and calcium aluminate hydrates at the lime-brick interfaces and in the pores of the pozzolanic brick aggregates by the reaction of lime. Characteristics of brick aggregates were compared with the construction bricks used in the building. Their chemical and mineralogical compositions revealed that the aggregates had not been produced from construction bricks. All the results indicated that brick-lime plasters were the most suitable materials for bath buildings to protect the structure from the effect of water. © 2019 The AuthorsArticle Citation - WoS: 19Citation - Scopus: 20Execution Technique and Pigment Characteristics of Byzantine Wall Paintings of Anaia Church in Western Anatolia(Elsevier Ltd., 2018) Demir, Serap; Şerifaki, Kerem; Böke, HasanIn this study, material characteristics of wall paintings executed in 11th Century Byzantine Church located in archaeological site of Anaia (Turkey) were investigated to provide historical information of the painting techniques. For this purpose, physical, chemical and mineralogical compositions of the paintings were determined by X-Ray Diffraction, Fourier Transform Infrared spectroscopy, Scanning Electron Microscopy coupled with Energy Dispersive spectroscopy and Thermo-Gravimetric Analysis. Analysis results indicated that the paintings were executed using lime-secco technique. In this technique, pigments were mixed with lime and applied on a smooth plaster layer. Pigments used were mainly iron oxides for red, yellow and purple paintings, aluminosilicates such as celadonite for green paintings and lazurite for dark blue paintings.Article Citation - WoS: 9Citation - Scopus: 10Physicochemical Properties of Glass Tesserae in Roman Terrace House From Ancient Antandros (base Glass, Opacifiers and Colorants)(Ege Üniversitesi, 2017) Kaplan, Zişan; İpekoğlu, Başak; Böke, HasanIn this study, material characteristics of glass mosaic tesserae from Antandros ancient city, western Turkey, were investigated. The main objective of this study was to determine the compositional group of the glass tesserae. Their color, mineralogical, chemical and microstructural characteristics were determined using colorimeter, x-ray diffraction, x-ray fluorescence and scanning electron microscope. The results show that all the Antandros glasses were produced by using coastal sand as Levantine I glasses and exhibit similar compositions with natron type glasses (Roman type glasses), except for lower natron levels. Lower natron levels indicate that Antandros mosaic glass may have been produced in 7th century AD or natron may have been provided from a new flux source due to the shortage of Egyptian mineral soda or due to economic reasons glass manufacturers succeeded to produce same glass with low flux addition. Antandros glass tesserae were all opacified with antimony oxides and colored with transition metal oxides which are common used in Roman Period.Article Citation - WoS: 18Citation - Scopus: 21Evaluation of Heat Treated Clay for Potential Use in Intervention Mortars(Elsevier Ltd., 2010) Budak, Meral; Akkurt, Sedat; Böke, HasanIn this study, raw material compositions, basic physical, mineralogical, microstructural and hydraulic properties of lime mortars used in two selected historic buildings were determined by XRD, SEM-EDS and TGA analyses. The results showed that the mortars were hydraulic due to the use of pozzolanic aggregates. Taking into account the hydraulic characteristics of mortars due to the use of pozzolanic aggregates, the possibility of obtaining hydraulic mortars by using pozzolanic aggregates produced from heated commercial clays was investigated. For this purpose, four clay samples used in the ceramic industry in Turkey were heated at varying temperatures of 400, 450, 500, 550, 600, 800, and 1200°C with a heating rate of 10°C/min. Pozzolanic properties of heated clay samples were determined. The results showed that commercial clays studied are well suited for use as pozzolanic aggregates when they are heated between 500 and 700. °C. This is also confirmed by testing the compressive strengths of the three month aged laboratory-produced mortars that contained thermally treated clay (at 600°C) as pozzolanic aggregates. Compressive strength of this mortar was around 5. MPa which is satisfactorily high. © 2009 Elsevier B.V.Article Citation - WoS: 41Citation - Scopus: 42Characterization of Materials Used in the Execution of Historic Oil Paintings by Xrd, Sem-Eds, Tga and Libs Analysis(Elsevier Ltd., 2009) Şerifaki, Kerem; Böke, Hasan; Yalçın, Şerife; İpekoğlu, BaşakIn this study, material characteristics of historic oil paintings in a 19th century church in Ayvali{dotless}k/Turkey were investigated to propose the treatments to be used in their conservation and protection. For this purpose, physical, chemical and mineralogical compositions and the microstructure of the paintings were determined by X-ray Diffraction, Scanning Electron Microscope, Thermo Gravimetric Analyzer, Differential Scanning Calorimeter, Infrared Spectroscopy and Laser Induced Breakdown Spectroscopy. Analysis results showed that the paintings were composed of very thin binding and white priming layers on which the pigments were applied. Binding layers were composed of polymerized vegetable oil with Zinc Oxide. Priming layers were composed of anglesite mineral in polymerized vegetable oil. Pigments used in paintings were mainly green earth, red chrome and iron oxide.Article Citation - WoS: 50Citation - Scopus: 51The Use of Brick-Lime Plasters and Their Relevance To Climatic Conditions of Historic Bath Buildings(Elsevier Ltd., 2009) Uğurlu Sağın, Elif; Böke, HasanBrick-lime mortars and plasters have been widely used as water-proof materials in aqueducts, bridges and cisterns since early Hellenistic time. In this study, the characteristics of brick-lime plasters used in some Ottoman bath buildings were investigated in order to understand their relevance as plasters in hot and humid environmental conditions of the baths. For this purpose, basic physical properties, raw material compositions, mineralogical, microstructural and hydraulic properties of brick-lime plasters of some historic bath buildings in İzmir (Turkey) were determined by XRD, SEM-EDX, AFM and chemical analyses. The results indicated that their survival without loosing their strength and adhesion in hot and humid conditions of the baths was explained by their hydraulic characters due to the consciously use of porous and pozzolanic crushed bricks as aggregate in the manufacturing of plasters.