WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7150
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Article Citation - WoS: 21Citation - Scopus: 21A Promising Catalyst for the Dehydrogenation of Perhydro-Dibenzyltoluene: Pt/Al2 O3 Prepared by Supercritical Co2 Deposition(MDPI, 2022) Modisha, Phillimon; Garidzirai, Rudaviro; Güneş, Hande; Bozbağ, Selmi Erim; Rommel, Sarshad; Uzunlar, Erdal; Aindow, Mark; Erkey, Can; Bessarabov, DmitriPt/Al2 O3 catalysts prepared via supercritical deposition (SCD), with supercritical CO2, wet impregnation (WI) methods and a selected benchmark catalyst, were evaluated for the dehydrogenation of perhydro-dibenzyltoluene (H18-DBT) at 300◦ C in a batch reactor. After ten dehydrogenation runs, the average performance of the catalyst prepared using SCD was the highest compared to the benchmark and WI-prepared catalysts. The pre-treatment of the catalysts with the product (dibenzyltoluene) indicated that the deactivation observed is mainly due to the adsorbed H0-DBT blocking the active sites for the reactant (H18-DBT). Furthermore, the SCD method afforded a catalyst with a higher dispersion of smaller sized Pt particles, thus improving catalytic performance towards the dehydrogenation of H18-DBT. The particle diameters of the SCD-and WI-prepared catalysts varied in the ranges of 0.6–2.2 nm and 0.8–3.4 nm and had average particle sizes of 1.1 nm and 1.7 nm, respectively. Energy dispersive X-ray spectroscopy analysis of the catalysts after ten dehydrogenation runs revealed the presence of carbon. In this study, improved catalyst performance led to the production of more liquid-based by-products and carbon material compared to catalysts with low catalytic performance.Article Citation - WoS: 33Citation - Scopus: 33Review-Supercritical Deposition: a Powerful Technique for Synthesis of Functional Materials for Electrochemical Energy Conversion and Storage(Electrochemical Society, Inc., 2020) Barım, Şansım Bengisu; Uzunlar, Erdal; Bozbağ, Selmi Erim; Erkey, CanSupercritical fluid-based technologies are increasingly being used to develop novel functional nanostructured materials or improve the properties of existing ones. Among these, supercritical deposition (SCD) is an emerging technique to incorporate metals on supports. It has been used to deposit a wide variety of single or multi-metallic morphologies such as highly dispersed species, nanoparticles, nanorods and conformal films on high surface area supports, polymers and crystalline substrates. SCD is also attracting increasing attention for preparation of micro or nano-architectured functional materials in a highly controllable manner for electrochemical energy conversion and storage systems. Increasing number of studies in the literature demonstrates that materials synthesized using SCD are comparable or superior in performance as compared to their conventional counterparts. In this review, an overview of the fundamentals of the SCD technique is presented. Properties of a wide variety of nanostructured functional materials such as supported nanoparticles and films prepared using SCD for electrochemical applications are summarized. The electrochemical performance of these materials in electrochemical tests and also in fuel cells, electrolyzers and Li-ion batteries are also presented. (C) 2020 The Author(s). Published on behalf of The Electrochemical Society by IOP Publishing Limited.