WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7150
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Article Citation - WoS: 1Citation - Scopus: 1Innovative Active and Intelligent Packaging Film Based on Pectin/Gelatin Biocomposites With Zein Nanoparticles and Anthocyanin: Quality Monitoring in Mandarin and Cucumber(Elsevier, 2025) Takma, Dilara Konuk; Bozkurt, Semra; Koc, Mehmet; Korel, Figen; Nadeem, Hilal SahinWith increasing demand for active and intelligent packaging to extend the shelf life of fresh produce and monitor its freshness, this study focused on developing a nanocomposite film. The film incorporates anthocyanin and bioactive chestnut shell extract-loaded zein nanoparticles, and its applications as coatings and packaging material for mandarin and cucumber fruits were investigated. Extracts derived from waste materials including chestnut shell, cedar tree bark and sweetgum (styrax liquidus) shell, chestnut shell extract-loaded active and intelligent nanocomposite films exhibited excellent properties, including low water vapor permeability (0.325 +/- 0.055 g.mm/m(2).h.kPa), high total phenolic content (77.20 +/- 5.64 mg GAE/g dry matter), and strong antioxidant capacity (220.04 +/- 2.70 mg Trolox equivalent /100 g dry weight). The film demonstrated sufficient tensile strength (29.35 +/- 3.40 MPa) and elongation at break (100.86 +/- 2.25 %) for its conversion into a practical packaging material. To evaluate its effectiveness, coating and packaging applications were carried out on mandarin and cucumber fruits, serving as non-climacteric model fresh produce. Coating and packaging significantly (p < 0.05) inhibited the growth of total aerobic mesophilic bacteria and yeast and mold in mandarins, though the effect on yeast and mold in cucumbers was limited. At the end of storage, packaged mandarin and cucumber fruits exhibited the highest total phenolic content, measuring 423.77 +/- 17.68 and 96.47 +/- 10.52 mg GAE/100 g dry matter, respectively. Coated fruits demonstrated significantly (p < 0.05) higher total phenolic content (382.57 +/- 18.32 mg GAE/100 g dry matter for mandarin and 91.52 +/- 7.63 mg GAE/100 g dry matter for cucumber) compared to control samples (281.22 +/- 10.49 mg GAE/100 g dry matter for mandarin and 69.56 +/- 8.99 mg GAE/100 g dry matter for cucumber). Color and textural properties of mandarin fruit were effectively maintained through coating and packaging. However, cucumber fruits, due to their high respiration rate and thin peel structure, did not show the same extent of improvements. The anthocyanin indicator in intelligent packaging exhibited more visible and effective color changes in cucumbers compared to mandarin fruits.Article Citation - WoS: 21Citation - Scopus: 22Characterization and Encapsulation Efficiency of Zein Nanoparticles Loaded With Chestnut Fruit Shell, Cedar and Sweetgum Bark Extracts(Elsevier, 2023) Konuk Takma, Dilara; Bozkurt, Semra; Koç, Mehmet; Korel, Figen; Şahin Nadeem, HilalZein nanoparticles (ZNPs) loaded with bioactive extracts of chestnut (Castanea sativa Mill.) shell, cedar (Cedrus libani) and sweetgum (Liquidambar orientalis) bark wastes were produced using different methods. Nanoprecipitation, high-speed homogenization and ultrasonic homogenization allowed the fabrication of ZNPs with particle sizes smaller than 202.40 nm, 430.25 nm and 325.50 nm, respectively. The smallest nanoparticle size was achieved at 132.81 nm for sweetgum bark extract-loaded ZNPs obtained by the nanoprecipitation method. Encapsulation efficiency (EE) was between 34.03 and 96.83% for all zein nanoparticles fabricated under different mixtures and process conditions. Zein concentration and extract ratio played an essential role in the EE of nanoparticles. The best conditions were determined to obtain the desired properties of ZNPs based on particle size, polydispersity index and EE by using a central composite rotatable design. The nanoprecipitation method was more appropriate for producing chestnut and cedar shell/bark extract-loaded nanoparticles. In contrast, the high-speed homogenization method was suitable for producing sweetgum bark extract-loaded nanoparticles. As a result of the encapsulation of various shell/bark extracts within zein nanoparticles, value-added products were generated from wastes having bioactive compounds. The developed zein nanoparticles for each extract type would offer eco-friendly, simple and safe food processing and packaging systems. © 2023Article Citation - WoS: 7Citation - Scopus: 9A Screen-Printed Electrode Modified With Gold Nanoparticles/ Cellulose Nanocrystals for Electrochemical Detection of 4,4'-methylene Diphenyl Diamine(Elsevier, 2023) Büyüktaş, Duygu; Ghaani, Masoud; Rovera, Cesare; Carullo, Daniele; Olsson, Richard T.; Korel, Figen; Farris, StefanoDeveloping simple, cost-effective, easy-to-use, and reliable analytical devices if of utmost importance for the food industry for rapid in-line checks of their products that must comply with the provisions set by the current legislation. The purpose of this study was to develop a new electrochemical sensor for the food packaging sector. More specifically, we propose a screen -printed electrode (SPE) modified with cellulose nanocrystals (CNCs) and gold nanoparticles (AuNPs) for the quantification of 4,4'-methylene diphenyl diamine (MDA), which is one of the most important PAAs that can transfer from food packaging materials into food stuffs. The electrochemical performance of the proposed sensor (AuNPs/CNCs/SPE) in the presence of 4,4'- MDA was evaluated using cyclic voltammetry (CV). The modified AuNPs/CNCs/SPE showed the highest sensitivity for 4,4'-MDA detection, with a peak current of 9.81 mu A compared with 7.08 mu A for the bare SPE. The highest sensitivity for 4,4'-MDA oxidation was observed at pH = 7, whereas the detection limit was found at 57 nM and the current response of 4,4'-MDA rose linearly as its concentration increased from 0.12 mu M to 100 mu M. Experiments using real packaging materials revealed that employing nanoparticles dramatically improved both the sensitivity and the selectivity of the sensor, which can be thus considered as a new analytical tool for quick, simple, and accurate measurement of 4,4 '-MDA during converting operations.Article Citation - WoS: 7Citation - Scopus: 6Development of a Nano-Modified Glassy Carbon Electrode for the Determination of 2,6-Diaminotoluene (tda)(Elsevier, 2021) Büyüktaş, Duygu; Ghaani, Masoud; Rovera, Cesare; Olsson, Richard T.; Korel, Figen; Farris, StefanoThe objective of this study was to improve the overall performance of a glassy carbon electrode (GCE) for the detection of 2,6-diaminotoluene (TDA), a possibly carcinogenic primary aromatic amines (PAAs) that poses a serious risk for the consumer' health because they can transfer from multilayer food packages including adhesives based on aromatic polyurethane (PU) systems, to the food. The modification of the electrode surface was made by means of multi-walled carbon nanotubes (MWCNTs) and mesopomus carbon nanoparticles (MCNs). The MWCNTs-MCNs/GCE allowed achieving the best performance in terms of sensitivity, as revealed by cyclic voltammetry - CV, with an oxidation peak of 20.95 mu A over 0.079 mu A of the bare GCE. The pH of the medium influenced the oxidation of 2,6-TDA, with highest sensitivity at pH similar to 7. Amperometry experiments led to an estimated detection limit of 0.129 mu M, and three linear ranges were obtained for 2,6-TDA: 0.53-11.37 mu M, 11.37-229.36 mu M, and 229.36-2326.60 mu M. Chronoamperometry experiments combined with Cottrell's theory allowed estimating a diffusion coefficient of 2,6-TDA of 1.34 x 10(-4) cm(2) s(-1). The number of electrons (n similar to 1) involved in the catalytic oxidation of 2,6-TDA was determined according to the Lavimn's theory. Real sample tests demonstrated that the modification of the sensor using nanoparticls allowed to obtain a highly sensitive and selective sensor, which can possibly used as an alternative analytical device for the rapid, easy, and reliable determination of 2,6-TDA.Conference Object Citation - WoS: 14Citation - Scopus: 16Drying of Olive Leaves in a Geothermal Dryer and Determination of Quality Parameters of Dried Product(Elsevier, 2019) Helvacı, Hüseyin Utku; Menon, Abhay; Aydemir, Levent Yurdaer; Korel, Figen; Gökçen Akkurt, GüldenIn this study, a cabinet type geothermal dryer was designed, operated and tested for drying olive leaves with minimum losses of phenolic content and antioxidant capacity by optimization of drying conditions. Two factors; face centered central composite design was applied and response surface methodology was used to optimize the drying conditions of olive leaves. The results indicate that phenolic content stability were mainly affected by air temperature, whereas antioxidant capacity is affected by both air temperature and velocity (p<0.05). The optimal drying conditions were found to be at 50°C of air temperature and 1 m/s of air velocity for the minimum losses of determined quality parameters, where 88.8% of phenolic content and 95.3% of antioxidant capacity were recovered.