WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

Permanent URI for this collectionhttps://hdl.handle.net/11147/7150

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Institution Author: search.filters.institutionAuthor.Artok, LeventSubject: search.filters.subject.Carbonylation

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Now showing 1 - 3 of 3
  • Article
    Citation - WoS: 13
    Citation - Scopus: 14
    Rhodium(i)-Catalyzed Carbonylative Arylation of Alkynes With Arylboronic Acids Using Formaldehyde as a Carbonyl Source
    (Georg Thieme Verlag, 2014) Wang, Chuang; Morimoto, Tsumoru; Kanashiro, Hiroyuki; Tanimoto, Hiroki; Nishiyama, Yasuhiro; Kakiuchi, Kiyomi; Artok, Levent
    The rhodium(I)-catalyzed reaction of alkynes with arylboronic acids in the presence of formaldehyde resulted in a carbon monoxide gas-free carbonylative arylation to yield α,β-enones. The simultaneous loading of phosphine-ligated and phosphine-free rhodium(I) complexes is required for efficient catalysis, which catalyze the abstraction of a carbonyl moiety from formaldehyde (decarbonylation) and its subsequent introduction into the substrate (carbonylation), respectively.
  • Article
    Citation - WoS: 11
    Citation - Scopus: 2
    Synthesis of Α,β-Unsaturated Ketones by Rhodium-Catalyzed Carbonylative Arylation of Internal Alkynes With Arylboronic Acids
    (Georg Thieme Verlag, 2008) Kuş, Melih; Aksın Artok, Özge; Ziyanak, Fırat; Artok, Levent
    The Rh-catalyzed reaction of arylboronic acids with internal alkynes under a CO atmosphere in the presence of an acid additive afforded α,β-unsaturated ketones as the major products. Hydroacylation of internal alkynes, except in the case of diaryl acetylenes, proceeded in syn fashion, yielding the E-configured isomer. A mixture of E- and Z-isomers was obtained with diphenyl acetylene. Reactions were also highly regioselective for various nonsymmetric alkynes.
  • Article
    Citation - WoS: 27
    Citation - Scopus: 30
    Rhodium Catalyzed Reaction of Internal Alkynes With Organoborons Under Co Atmosphere: a Product Tunable Reaction
    (Elsevier Ltd., 2009) Artok, Levent; Kuş, Melih; Aksın, Özge; Dege, Fatma Nurcan; Özkılınç, Fatma Yelda
    Alkynes react with organoborons under a CO atmosphere in the presence of a rhodium(I) catalyst to afford mainly 5-aryl-2(5H)-furanones, α,β-unsaturated ketones, and indanones. The product selectivity can be tuned by modifying the reaction conditions.