WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7150
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Article Citation - WoS: 1Citation - Scopus: 1Effect of Compaction and Fluoride Content on the Remelting Efficiency of Pure Magnesium Chips(Taylor & Francis, 2023) Yörük, Pınar; Gökelma, Mertol; Derin, BoraMagnesium is widely used in industries, such as automotive, aerospace, and medical fields. The demand on magnesium has been growing, although the production and melt treatment is complex due to strong oxidation tendency. Recycling of magnesium scraps is crucial due to the criticality of magnesium-containing raw materials in Europe as well as increasing environmental concerns. Remelting of magnesium is typically conducted under a salt flux which absorbs the impurities and protects the melt against oxidation. This study investigates the effect of compaction, fused salt flux, and salt composition on remelting behavior of magnesium chips. Metal yield and coagulation efficiency were calculated after remelting, and samples were characterized by using Scanning Electron Microscope and X-ray Diffraction. The liquidus temperature and density of fluxes were analyzed by FactSage software. Remelting of compacted chips under a fused salt flux with 5 wt.% CaF2 showed the highest magnesium recovery with a yield of 97.7%. Le magnesium est largement utilise dans une variete d'industries, telles que les domaines de l'automobile, de l'aerospatiale et de la medecine. La demande en magnesium s'est accrue, bien que la production et le traitement du bain soient complexes en raison de sa forte tendance a l'oxydation. Le recyclage des dechets de magnesium est crucial en raison de la criticite des matieres premieres contenant du magnesium en Europe ainsi que des preoccupations environnementales croissantes. La refusion du magnesium est effectuee typiquement sous un flux de sel qui absorbe les impuretes et protege le bain contre l'oxydation. Cette etude examine l'effet du compactage, du flux de sel fondu et de la composition du sel sur le comportement a la refusion des copeaux de magnesium. On a calcule le rendement en metal et l'efficacite de la coagulation apres des experiences de refusion, et l'on a caracterise les echantillons a l'aide d'un microscope electronique a balayage et de la diffraction des rayons X. On a analyse la temperature du liquidus (Tliq) et la densite des flux de sel avec le logiciel FactSage. La refusion des copeaux compactes sous un flux de sel fondu avec 5% en poids de CaF2 a montre la recuperation de magnesium la plus elevee avec un rendement de 97.7%Conference Object Citation - WoS: 1Citation - Scopus: 1Assessment of Separation and Agglomerationt Tendency of Non-Metallic Inclusions in an Electromagnetically Stirred Aluminum Melt(Springer international Publishing Ag, 2023) Li, Cong; Dang, Thien; Gokelma, Mertol; Zimmermann, Sebastian; Mitterecker, Jonas; Friedrich, BerndPresence of non-metallic inclusions (NMIs) reduces surface quality and mechanical properties of aluminum products. The development of good NMIs removal practices relies on the understanding of inclusion behaviors with respect to separation and agglomeration particularly in the turbulent flow. In the scenario of electromagnetically induced recirculated turbulent flow, the concerned behaviors of inclusions with different sizes have rarely been investigated experimentally. In the presented study funded by AMAP Open Innovation Research Cluster, reference materials were prepared with uniformly distributed NMIs (SiC and MgAl2O4) via an ultrasoundinvolved casting route. Reference materials were charged into an aluminum melt where turbulent flow was promoted via electromagnetic force. Microscopical analysis shows non-significant agglomeration tendency of SiC, MgAl2O4, and TiB2 inclusion. Time-weight filtration curve, PoDFA, and Spark Spectrometer results suggest a strong dependence of separation rate on particle size. Analytical models were established to estimate the collision rate of particles and to evaluate separation probability of different sized particles.Article Citation - WoS: 10Citation - Scopus: 7Assessment of Melt Cleanliness of Secondary 5000 Aluminum Alloy Via Non-Metallic Inclusions Characterization(Springer, 2023) Li, Cong; Dang, Thien; Huang, Jinxian; Huang, Chunfa; Li, Jianguo; Friedrich, Bernd; Gökelma, MertolThe extensive energy consumption of primary aluminum production stimulates increasing need of producing primary-quality alloys with secondary sources, during which process amount of non-metallic inclusions (NMIs) in the alloy must be strictly controlled. In the present study funded by AMAP Open Innovation Research Cluster, NMIs generated during remelting a 5000 Al-Mg alloy was investigated to offer benchmarking characters of NMIs with respect to type, morphology, size, composition, and concentration. Under different remelting conditions NMIs formed in the melt ahead of solidification were concentrated using Porous Disc Filtration Apparatus (PoDFA) and characterized microstructurally and quantitatively. Investigated conditions included heating cycle, organic contaminations, and refractory materials. Results suggested oxide films and cuboid particles as typical oxides with, respectively, different compositions. The amount of formed oxides declined with the increase of heating rate. With respect to aluminum carbide (Al4C3), organic contaminations were confirmed to lead to an increased amount of its formation. The carbon-containing refractory material contributed more significantly than organic contaminations on the formation of Al4C3 at melt temperatures over 760 & DEG;C. Formulas were derived based on trial results to enable translation of NMIs PoDFA value [mm(2)/kg] into their mass fraction [ppm] in the melt.Article Citation - WoS: 1Citation - Scopus: 1Investigating Triple Superphosphate for Lead Removal From Aqueous Solutions(Taylor & Francis, 2022) Souley Garba, Mahamane Chapiou; Kaya, Erol; Gökelma, Mertol; Seyrankaya, AbdullahThe aim of this research is to investigate monocalcium phosphate monohydrate [Ca(H2PO4)2. H2O] also called triple superphosphate (TSP) for the removal of lead (Pb) from aqueous solutions. In this study, TSP was selected amongst various phosphate-based materials and fertilizers to act as the source of orthophosphate (PO43-) which is a powerful tool for metal fixation in soil and water. Thermodynamic equilibrium dissolution-precipitation relationships for the systems of Pb-H2O and Pb-PO43--H2O were drawn with the aid of Eh-pH stability diagrams to determine the predominance areas of different species. The lead phosphate compounds, identified through the stability area diagrams, were verified with the batch precipitation tests performed with standard solutions of lead and TSP at different conditions. It was observed that, depending upon solution conditions, TSP can precipitate 99.9% of the lead from the solution. Lead precipitates, analyzed by x-ray diffraction, showed the formation of lead phosphate compounds. The mechanism of TSP for the removal of lead from aqueous solutions is discussed.Conference Object Pre-Study of the Dissolution Behavior of Silicon Kerf Residue in Steel(Springer, 2022) Lazou, Adamantia; Nilssen, David; Gökelma, Mertol; Wallin, Maria; Tranell, GabriellaSilicon kerf residue is generated during the wafering process of pure silicon in the photovoltaic value chain. The generated by-product has a high volume, and the particle size is typically below 1 μm. Although the fine particles are partly oxidized, the material may be beneficial in different metallurgical applications such as grain refining and alloy composition adjustments. This work studies the dissolution behavior of silicon kerf in low alloy steel melts with the aim to upcycle the kerf material in the steel industry for different purposes. In this study, a steel alloy and the kerf residue were melted (at 1580 °C) in an alumina crucible placed in an induction furnace. The amount of added kerf residue was varied. The behavior of the particles in the solidified alloy was characterized by using an optical microscope, electron probe microscope (EPMA), and wavelength-dispersive X-ray spectroscopy (WDS) in order to study the dissolution behavior of the Si-kerf residue in the steel.Article Citation - WoS: 10Citation - Scopus: 11Behavior of Al4c3 Particles During Flotation and Sedimentation in Aluminum Melts(Springer, 2021) Gökelma, Mertol; Storm Aarnaes, Trygve; Maier, Juergen; Renkel, Maria F.; Ekstrom, Kai Erik; Friedrich, Bernd; Tranell, GabriellaAl4C3 particles form during the primary production of aluminum via molten salt electrolysis due to the carbon solubility and direct contact between bath, metal, and carbon anodes. Additional Al4C3 may form during melt processing through direct contact between the melt and carbonaceous materials. As a result of their small size and similar density to aluminum, removal of aluminum carbide particles can be challenging. If not removed, carbides can produce inclusion defects or poor surface condition in aluminum products. The current work studies the removal and behavior of Al4C3 particles during flotation with different gas mixtures, as well as sedimentation. The interaction between carbide particles and Al2O3 films during the melt treatment processes was also studied and reported. Factsage thermochemical software was used to model the interactions at the interface of inclusions and bubbles covered by films. The highest degree of carbide removal was obtained after flotation with an H2O-containing argon gas mixture, where the carbide concentration dropped below the measured solubility limit of carbon at the corresponding temperature. Strong interaction between Al4C3 particles and Al2O3 films was observed during sedimentation which worked as an efficient removal method for the particles. Oxidation of carbides and formation of oxycarbides were suggested as the mechanisms promoting the attachment of carbides on oxide films.Article Citation - WoS: 4Citation - Scopus: 4Rewas 2022: Developing Tomorrow's Technical Cycles(Springer, 2021) Fleuriault, Camille; Gökelma, Mertol; Anderson, Alexandra; Olivetti, Elsa A.REWAS, a sustainability driven conference within The Minerals, Metals & Materials Society (TMS), has a long history of bringing together academia and industry to exchange and reflect on the latest technology developments in the process optimization and waste management fields. The first edition of REWAS (REcycling and WASte symposium) took place in 1999. The scope of the conference has since then broadened to include environmental sustainability, resource management and manufacturing efficiency, liaising these developments to the metallurgical industry in a broader societal and systemic context. The 2022 edition of REWAS which will be hosted at the TMS 2022 Annual Meeting & Exhibition in Anaheim, California, provides a resolute outlook towards Developing Tomorrow's Technical Cycles. Within the metals and materials industry, technical cycles refer to the ensemble of strategies and processes applied to the development of sustainable product loops with the intent to eliminate waste and instead rethink, reuse and upcycle products. The success of technical cycles requires strengthening our circular approach for product life cycle design by providing guidelines and implementation examples to the developers, designers, policy makers and business managers. REWAS promotes such strategies within a priority sector identified for Circular Economy enablement: raw materials supply and management. REWAS 2022 consists of six symposia, and abstract submissions are expected in summer 2021. Topics include recycling and sustainability within the aluminum industry, specifically on casting technologies, recovery of metals from complex products and systems, decarbonization of the metallurgical and manufacturing industry, sustainable production and development perspectives, as well as automatization and digitalization for advanced manufacturing. REWAS 2022 will also include an honorary symposium for Dr. Diran Apelian, whose contributions in metals processing, aluminum and battery recycling, sustainability, education in materials science and more have shaped the path for sustainable materials processing.Article Citation - WoS: 25Citation - Scopus: 27Characteristic Properties and Recyclability of the Aluminium Fraction of Mswi Bottom Ash(Elsevier, 2021) Gökelma, Mertol; Vallejo-Olivares, Alicia; Tranell, GabriellaThe increasing use of aluminimum in packaging applications results in many different aluminium-based products ending up in consumer mixed-waste bins. This waste is typically incinerated, generating an aluminium-containing bottom ash. The current work investigates the recyclability of the aluminium fraction in the bottom ash from waste incineration plants in the USA, UK and Denmark. Incinerated Al samples from different size fractions (2-6 mm, 6-12 mm and 12-30 mm) were characterized in terms of inherent oxide thickness, re-melting yield/coagulation and composition. The measured average oxide thickness on Al particles was 68 mm (SD=100), with the metal yield and coagulation efficiency measured to between 76 and 92% and 87-99% respectively. Larger particle size fractions resulted in a higher metal yield due to their higher mass to surface ratio. A simplified model correlating metal yield and particle size was proposed. The aluminium content of the melted material was determined to between 95.6 and 98.5% with main impurities being Fe, Si, Mn, Zn, Mg and Cu, corresponding to major aluminium alloying elements and waste charge components. (c) 2021 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).Conference Object Citation - WoS: 2Citation - Scopus: 1The Influence of the Casting Speed in Horizontal Continuous Casting of Aluminium Alloy En Aw 6082(Springer, 2021) Obalı, Akın; Dilek, Kerem Ahmet; Akdi, Seracettin; Ürk, Deniz Kavrar; Gökelma, MertolVertical direct chill (VDC) casting is commonly used to produce slabs and billets from wrought aluminium alloys. The fact that the VDC is not a continuous process and moulds must be prepared for the next batch decreases the productivity of the process. Alternatively, horizontal direct chill (HDC) casting simplifies the process and allows a continuous production. The casting speed in the HDC casting is easier to control and can be optimized for different alloys by changing the speed. This study focuses on investigating the effects of casting speed on the macrostructure of 6082 aluminium billets with 60 mm diameter. A demo-scale casting unit was used and the casting speed was changed from 310 to 385 mm/min. Changes in surface condition, macrocracks, microporosity, and diameter of the billets were investigated. Surface quality of the billets became better with the increasing casting speed, while diameter of the billet expands. Furthermore, centreline cracks appear at the casting speed of 355 mm/min. © 2021, The Minerals, Metals & Materials Society.