WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7150
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Article Citation - WoS: 76Citation - Scopus: 95Development of Flexible Zein-Wax Composite and Zein-Fatty Acid Blend Films for Controlled Release of Lysozyme(Elsevier Ltd., 2013) Arcan, İskender; Yemenicioğlu, AhmetThe aim of this study was controlled release of lysozyme by modification of hydrophobicity and morphology of zein films using composite and blend film making methods. The incorporation of beeswax, carnauba or candelilla wax into films at 5% (w/w) of zein gave composite films containing amorphous wax particles, while incorporation of oleic acid into film at 5% of zein caused formation of blend films containing many spherical zein capsules within their matrix. The lysozyme release rates of composites reduced as the melting point of waxes increased. The composites and blends showed 2.5 to 17 fold lower lysozyme release rates than controls. The films were effectively plasticized by using catechin. The catechin also provided antioxidant activity of films (up to 69 mu mol Trolox/cm(2)) and contributed to their controlled release properties by reducing film porosity. The films showed antimicrobial activity against Listeria innocua. This work showed the possibility of obtaining advanced edible films having flexibility, antimicrobial and antioxidant activity and controlled release properties.Article Citation - WoS: 80Citation - Scopus: 107Application of Active Zein-Based Films With Controlled Release Properties To Control Listeria Monocytogenes Growth and Lipid Oxidation in Fresh Kashar Cheese(Elsevier Ltd., 2013) Uysal Ünalan, İlke; Arcan, İskender; Korel, Figen; Yemenicioğlu, AhmetThe antimicrobial and antioxidant potential of zein and zein-wax composite films having different release profiles for lysozyme and mixture of lysozyme, catechin and gallic acid were tested on cold-stored fresh Kashar cheese inoculated with Listeria monocytogenes ATCC 7644. All lysozyme containing films prevented the increase of L. monocytogenes counts in Kashar cheese for 8 weeks at 4°C, but it was only the zein-wax composite films with sustained lysozyme-release rates which caused a significant reduction (- 0.4 decimals) in initial microbial load of inoculated cheese samples. The mixture of catechin and gallic acid improved the in vitro antimicrobial effect of films against L. monocytogenes, but showed no considerable antimicrobial effect in cheese. However, the films containing catechin and gallic acid were effective in preventing oxidative changes in cheese. This study showed the possibility of increasing safety and quality of fresh cheeses by use of active packaging employing natural antimicrobial compounds and controlled release technology. Industrial relevance There has been a growing interest to develop the functional properties of packaging materials and to obtain packed foods with better shelf-life and quality. Active packaging incorporating antimicrobials is one of the most promising areas since application of this method can improve safety of foods by inhibiting pathogenic bacteria or controlling spoilage flora by using minimum amounts of active compounds. Recently, health concerns of consumers and environmental problems related to plastics increased the popularity of using natural antimicrobial substances in edible films and coatings. This work employs a GRAS status natural antimicrobial lysozyme and zein a major by-product of rapidly growing oil and bioethanol industries which can form self-standing films, coatings or casings. The results of this study showed the possibility of using flexible antimicrobial and antioxidant films with controlled release properties in diary industry.Article Citation - WoS: 19Citation - Scopus: 21Effect of Strain Rate on the Compressive Mechanical Behavior of a Continuous Alumina Fiber Reinforced Ze41a Magnesium Alloy Based Composite(Elsevier Ltd., 2006) Güden, Mustafa; Akil, Övünç; Taşdemirci, Alper; Çiftçioğlu, Muhsin; Hall, Ian W.The compressive mechanical response of an FP™ continuous fiber (35 vol.%) Mg composite has been determined in the transverse and longitudinal directions at quasi-static and high strain rates. It was found that the composite in the transverse direction exhibited strain rate sensitivity of the flow stress and maximum stress within the studied strain-rate range of 1.3 × 10−4 to 1550 s−1. The failure strain in this direction, however, decreased with increasing strain rate. Microscopic observations on the failed samples have shown that the composite failed by shear banding along the diagonal axis, 45° to the loading axis. Twinning was observed in the deformed cross-sections of the samples particularly in and near the shear band region. The strain rate sensitivity of the fracture stress of the composite in transverse direction is attributed to the matrix strain rate sensitivity. In the longitudinal direction, the composite failed by kink formation at quasi-static strain rates, while kinking and splitting were observed at the high strain rates. The maximum stress in the longitudinal direction was, however, found to be strain rate insensitive within the strain rate regime of 1.3 × 10−4 to 500 s−1. In this direction, similar to transverse direction, twinning was observed in the highly deformed kink region. Several different reasons are proposed for the strain rate insensitive compressive strength in this direction.Article Citation - WoS: 26Citation - Scopus: 40Effect of Strain Rate on the Compression Behaviour of a Woven Glass Fiber/Sc-15 Composite(Elsevier Ltd., 2004) Güden, Mustafa; Yıldırım, Uygar; Hall, Ian W.Strain rate dependent compression behavior of a plain-weave S-2 glass fabric SC-15 epoxy (rubber toughened resin) composite plate, currently studied as the backing plate for composite armor applications, was determined in the through-thickness direction (normal to the fiber plane) in the strain rate regime of 1×10−4 to 1.1×103 s−1. In the studied strain rate regime, the modulus and failure strength of the composite were found to be rate sensitive and increased with increasing strain rate. Microscopic observations showed that the composite failed by ductile failure, involving matrix cracks and, later, cracking through and between the fiber layers. Crack deflections at rubber particle/matrix interface and particle pull-out were observed in the failed samples, contributing to the toughness of the composite.