TR Dizin İndeksli Yayınlar / TR Dizin Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7149
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Article Citation - WoS: 1Citation - Scopus: 2Lacoo3 Is a Promising Catalyst for the Dry Reforming of Benzene Used as a Surrogate of Biomass Tar(Tubitak Scientific & Technological Research Council Turkey, 2024) Çağlar, Başar; Üner, DenizTar build-up is one of the bottlenecks of biomass gasification processes. Dry reforming of tar is an alternative solution if the oxygen chemical potential on the catalyst surface is at a sufficient level. For this purpose, an oxygen-donor perovskite, $LaCoO_3$, was used as a catalyst for the dry reforming of tar. To circumvent the complexity of the tar and its constituents, the benzene molecule was chosen as a model compound. Dry reforming of benzene vapor on the $LaCoO_3$ catalyst was investigated at temperatures of 600, 700, and 800 °C; at $CO_2/C_6H_6$ ratios of 3, 6, and 12; and at space velocities of 14,000 and 28,000 h–1. The conventional Ni(15 wt.%)/$Al_2O_3$ catalyst was also used as a reference material to determine the relative activity of the $LaCoO_3$ catalyst. Different characterization techniques such as X-ray diffraction, $N_2$ adsorption-desorption, temperature-programmed reduction, and oxidation were used to determine the physicochemical characteristics of the catalysts. The findings demonstrated that the $LaCoO_3$ catalyst has higher $CO_2$ conversion, higher $H_2$ and CO yields, and better stability than the Ni(15 wt.%)/γ-$Al_2O_3$ catalyst. The improvement in activity was attributed to the strong capacity of $LaCoO_3$ for oxygen exchange. The transfer of lattice oxygen from the surface of the $LaCoO_3$ catalyst facilitates the oxidation of carbon and other surface species and leads to higher conversion and yields.Article Citation - WoS: 3Citation - Scopus: 3Β-Ketoenamine-linked covalent organic framework for efficient iodine capture(Tubitak Scientific & Technological Research Council Turkey, 2024) Büyükçakır, OnurExploring the materials that effectively capture radioactive iodine is crucial in managing nuclear waste produced from nuclear power plants. In this study, a β-ketoenamine-linked covalent organic framework (bCOF) is reported as an effective adsorbent to capture iodine from both vapor and solution. The bCOF’s high porosity and heteroatom-rich skeleton offer notable iodine vapor uptake capacity of up to 2.51g $g^{–1}$ at 75 °C under ambient pressure. Furthermore, after five consecutive adsorption-desorption cycles, the bCOF demonstrates high reusability performance with significant iodine vapor capacity retention. The adsorption mechanism was also investigated using various ex situ structural characterization techniques, and these mechanistic studies revealed the existence of a strong chemical interaction between the bCOF and iodine. The bCOF also showed good iodine uptake performance of up to 512 mg $g^{–1}$ in cyclohexane with high removal efficiencies. The bCOF’s performance in adsorbing iodine from both vapor and solution makes it a promising material to be used as an effective adsorbent in capturing radioactive iodine emissions from nuclear power plants.Article Citation - Scopus: 3Evaluation of Gis-Based Spatial Interpolation Methods for Groundwater Level: a Case Study of Türkiye(Tubitak Scientific & Technological Research Council Turkey, 2024) Kırçiçek, Nilüfer Tirol; Baba, Alper; Koçbay, Ayhan; Toklu, Murat MertGroundwater is a valuable and universally distributed resource on Earth. Understanding the spatial and temporal dynamics of groundwater is of utmost importance for effective management. Normally, groundwater levels are recorded at arbitrary points, but groundwater modeling requires interpolating the measured values at specific grid nodes. This study aims to dentify and evaluate the geographical variations of groundwater levels in Türkiye using three geostatistical interpolation techniques. Data from 355 groundwater wells from 1970 to 2019 were used for this purpose. In addition, an investigation of changes in annual average temperature and precipitation was conducted for two different time periods: 1985–2000 and 2001–2016. The results show an increase in the annual average temperature in Türkiye by 0.82 °C during the reference period (1985–2000). Despite regional differences in the precipitation regime, the average annual precipitation in Türkiye has not changed significantly overall. Especially in the Meriç-Ergene, Konya Closed (Konya Kapalı), and Euphrates-Tigris basins, a significant decrease in groundwater levels was observed, even though this decrease is less than 100 m in some wells. After a comprehensive analysis of all these data, possible explanations for the changes in groundwater levels were considered.Article Citation - WoS: 2Citation - Scopus: 2Enrichment of Turkish Question Answering Systems Using Knowledge Graphs(Tubitak Scientific & Technological Research Council Turkey, 2024) Ciftci, Okan; Soygazi, Fatih; Tekir, SelmaRecent capabilities of large language models (LLMs) have transformed many tasks in Natural Language Processing (NLP), including question answering. The state-of-the-art systems do an excellent job of responding in a relevant, persuasive way but cannot guarantee factuality. Knowledge graphs, representing facts as triplets, can be valuable for avoiding errors and inconsistencies with real-world facts. This work introduces a knowledge graph-based approach to Turkish question answering. The proposed approach aims to develop a methodology capable of drawing inferences from a knowledge graph to answer complex multihop questions. We construct the Beyazperde Movie Knowledge Graph (BPMovieKG) and the Turkish Movie Question Answering dataset (TRMQA) to answer questions in the movie domain. We evaluate our proposed question answering pipeline against a baseline study. Furthermore, we compare it with a question answering system built upon GPT-3.5 Turbo to answer the 1-hop questions from TRMQA. The experimental results confirm that link prediction on a knowledge graph is quite effective in answering questions that require reasoning paths. Finally, we provide insights into the pros and cons of the provided solution through a qualitative study.Article Stochastic 1-D Reactive Transport Simulations To Assess Silica and Carbonate Phases During the $co_2$ Reinjection Process in Metasediments(TÜBİTAK - Türkiye Bilimsel ve Teknolojik Araştırma Kurumu, 2024) Erol, SelçukOne proposed method to mitigate carbon emission is to mineralize the $CO_2$ in deep geothermal reservoirs while mixing the coproduced CO2 with the effluent fluid for reinjection. The injection fluid temperature fluctuates due to the mixing process between CO2-charged water and the effluent fluid, and compressor interruptions change the thermodynamic conditions that influence the fluid- rock interaction in the reservoir. Mineral dissolution or precipitations are associated with changes in permeability and porosity that affect the flow and, eventually, the lifespan of the reservoir. A combined stochastic–reactive transport simulation approach is useful for inspection purposes. Moreover, the stochastic algorithm validates the deterministic reactive transport simulation and demonstrates the time evolution of a chemically reacting system in the reservoir. This study examines a range of injection temperatures between 80 °C and 120 °C to evaluate silica and calcite precipitation along a flow path. One-dimensional (1-D) reactive transport and compartment- based stochastic reaction-diffusion-advection Gillespie algorithms are carried out. The 1-D model represents a reservoir feed zone of around 2300 m. Two common metasediment rock types are evaluated for inspection. The first one is the muscovite schist, which has approximately 60% quartz, and the second is the quartz schist, consisting of roughly 90% quartz. The stochastic method can be applied more effectively if the chemical system is completely defined with proper reaction rates as a function of temperature. The mixing ratio of the coproduced $CO_2$ over the effluent fluid is around 0.0028. Simulation results show that $CO_2$ is partially sequestrated as calcite within the first 10 m of the entrance to the reservoir and plugs the pores completely in the muscovite schist scenario. Chalcedony and α-cristobalite precipitate as secondary minerals evenly along the flow path. $CO_2$ injection into a quartz schist layer is more appropriate for geochemical interactions below 120 °C.Article Citation - WoS: 1Citation - Scopus: 2Integration of Daylight Use and Analysis in Double Skin Facades: a Literature Review(Gazi Universitesi, 2024) Kazanasmaz, Tugce; Ünlütürk, Mustafa SerhanDouble skin facades (DSF) aim to save energy reducing the heat losses in buildings. They are visually appeal while allowing to use daylight efficiently. Such facade systems can reduce glare and distribute daylight evenly in the interior when compared to conventional facade systems. That is a result of cavities between two glass facades and locating sun shading elements in them, although this system provides a high level of transparency. As their primary purpose of application is to ensure thermal performance and ventilation, most studies in literature have focused on these. This study started with the hypothesis that studies examining daylight performance in DSFs are more limited than studies examining thermal performance and that daylight optimization methods are not used sufficiently in DSFs. In this context, the study aims to analyze studies focusing on daylight performance of DSFs. The review targets results of such current studies to guide future ones providing feedback knowledge. This may help to better technical developments in such facades and make them prevail in constructions or in retrofitting So, it contributes to literature in this sense. Recent studies are shown in tabulated form and interpreted in detail with graphics. considering their methodologies, daylight parameters and findings. Results show that the daylight parameter is one of the most important issues that architects or designers should consider from the moment they start the design, and they should make their designs based on the optimum penetration of daylight into the building. Consequently, this review presents that the use of daylight optimization has started to be used in recent studies dealing with DSFs. A DSF design can optimally get daylight into the interior can be made by using this method more frequently.Article Citation - WoS: 4Citation - Scopus: 3Expression Patterns of M6a Rna Methylation Regulators Under Apoptotic Conditions in Various Human Cancer Cell Lines(TUBITAK, 2024) Alasar, Azime Akçaöz; Sağlam, Buket; Vatansever, İpek Erdoğan; Akgül, BünyaminBackground/aim: Cancer is a complex disease that involves both genetic and epigenetic factors. While emerging evidence clearly suggests that changes in epitranscriptomics play a crucial role in cancer pathogenesis, a comprehensive understanding of the writers, erasers, and readers of epitranscriptomic processes, particularly under apoptotic conditions remains lacking. The aim of this study was to uncover the changes in the expression of m6A RNA modifiers under apoptotic conditions across various cancer cell lines. Materials and methods: Initially, we quantified the abundance of m6A RNA modifiers in cervical (HeLa and ME180), breast (MCF7 and MDA-MB-231), lung (A549 and H1299), and colon (Caco-2 and HCT116) cancer cell lines using qPCR. Subsequently, we induced apoptosis using cisplatin and tumor necrosis factor-alpha (TNF-α) to activate intrinsic and extrinsic pathways, respectively, and assessed apoptosis rates via flow cytometry. Further, we examined the transcript abundance of m6A RNA modifiers under apoptotic conditions in cervical, breast, and lung cancer cell lines using qPCR. Results: Overall, treatment with cisplatin increased the abundance of m 6A modifiers, whereas TNF-α treatment decreased their expression in cervical, breast, and lung cancer cell lines. Specifically, cisplatin-induced apoptosis, but not TNF-α-mediated apoptosis, resulted in decreased abundance of METTL14 and FTO transcripts. Additionally, cisplatin treatment drastically reduced the abundance of IGF2BP2 and IGF2BP3 readers. Conclusion: These results suggest that the differential response of cancer cells to apoptotic inducers may be partially attributed to the expression of m6A RNA modifiers.Article Citation - Scopus: 1Lower Data Attacks on Advanced Encryption Standard(Turkiye Klinikleri, 2024) Kara, OrhunThe Advanced Encryption Standard (AES) is one of the most commonly used and analyzed encryption algorithms. In this work, we present new combinations of some prominent attacks on AES, achieving new records in data requirements among attacks, utilizing only $2^4 and 2^{16}$ chosen plaintexts (CP) for 6-round and 7-round AES- 192/256, respectively. One of our attacks is a combination of a meet-in-the-middle (MiTM) attack with a square attack mounted on 6-round AES-192/256 while another attack combines an MiTM attack and an integral attack, utilizing key space partitioning technique, on 7-round AES-192/256. Moreover, we illustrate that impossible differential (ID) attacks can be viewed as the dual of MiTM attacks in certain aspects which enables us to recover the correct key using the meet-in-the-middle (MiTM) technique instead of sieving through all potential wrong keys in our ID attack. Furthermore, we introduce the constant guessing technique in the inner rounds which significantly reduces the number of key bytes to be searched. The time and memory complexities of our attacks remain marginal.Article Accessibility in Intensive Care Units: a Qualitative Study on Exploring Architects’ Perspective(İstanbul Teknik Üniversitesi, 2023) Khoojıne, Negar Sioofy; Kasalı, Altuğ; Bayar, Mualla ErkılıçThisstudyaddresseshealthcaredesigners’perspectivesconcerningthearchitectural features within the Intensive Care Unit (ICU) environments that can impact visual and physical access to patients. In line with patient-centered approaches, providing accessible environments in ICUs is becoming increasingly critical for healthcare providers. The existing literature suggests various architectural features to influence levels of access to patients. How architects prioritize these features and translate them into the configuration of ICU environments has not been explored extensively. A series of semi-structured interviews were conducted to understand the perspectives of healthcare architects in the context of Turkey. The interviews were conducted with twelve participants with recent experiences in ICU design. The research followed a thematic analysis to link the qualitative data with the participants’ drawings that emerged during interviews. Five essential themes emerged, including: “Unit Model,” “Unit Layout,” “Unit Size,” “Bed Position,” and “Transparent Material.” The participants implied configurational models, including “open ward” and “single-patient room,” to facilitate high levels of accessibility. Beyond the key decisions concerning layouts, the participants also emphasized the strategic use of transparent materials, which was considered critical in establishing visual access within units. The findings suggest that healthcare architects mostly favor open wards as a suitable model to provide high levels of physical access by decreasing nurses’ walking distances during shifts and visual accessibility by enhancing nurses’ capacity to supervise the patients within ICU environments. The findings can advance our understanding of how the issue of access is formulated and implemented in ICU settings.Article Citation - Scopus: 3A Brief Overview on Geothermal Scaling(General Directorate of Mineral Research and Exploration (MTA), 2023) Isık, Tuğba; Baba, Alper; Chandrasekharam, Dornadula; Demir, Mustafa M.; Isık, Tuğba; Baba, Alper; Demir, Mustafa MuammerHot spring waters are rich in terms of minerals. Since there are dramatic changes in thermodynamic parameters in geothermal power plants, such as a decrease in temperature and pressure, severe precipitation occurs throughout the system components in an uncontrolled manner. There are three main chemistries in deposits: carbonates (mainly calcium carbonates), silicates (metal silicates), and sulphides (antimony sulphide-stibnite). Energy harvesting is remarkably reduced out of the insulating nature of the deposit. Various actions need to be taken to mitigate this undesirable issue of scaling in geothermal systems. Geothermal systems are in fact quite complex, and the composition of brine and, accordingly, the chemistry of the deposit are not identical. Therefore, each system should be studied individually, and a tailor-made remedy should be developed. In this overview, the types of deposits in terms of chemistry and the actions (pH modification or antiscalant dosing) that should be taken to reduce scaling are mentioned, and potential chemistries of antiscalants are given.
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