Chemical Engineering / Kimya Mühendisliği

Permanent URI for this collectionhttps://hdl.handle.net/11147/14

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  • Article
    Citation - WoS: 10
    Citation - Scopus: 10
    Morphology, Order, Light Transmittance, and Water Vapor Permeability of Aluminum-Coated Polypropylene Zeolite Composite Films
    (John Wiley and Sons Inc., 2011) Balköse, Devrim; Oğuz, Kaan; Özyüzer, Lütfi; Tarı, Süleyman; Arkış, Esen; Özmıhçı Ömürlü, Filiz
    In this study, the polypropylene-zeolite composite films having 2-6 wt % natural zeolite were coated with a thin film of aluminum (Al) by magnetron sputtering, and the contribution of the Al coating on film properties was investigated. The samples were characterized by EDX, X-ray diffraction, SEM, AFM, UV-visible spectroscopy, and water vapor permeation analyses. The surface of the films coated with a smooth Al film having 98-131 nm thickness. EDX revealed that Al percentage on the surface appeared to be as 8-10 wt % indicating contribution of polymer surface under Al film to analysis. XRD analysis showed that the grain size of Al at the surface was 22-29 nm. The surface roughness increased after Al-coating process. The transmission of coated films was very low for both UV and visible regions of the light spectrum. Permeation analysis indicated that water vapor permeation was lower for Al-coated material.
  • Article
    Citation - WoS: 20
    Citation - Scopus: 23
    Effect of Humidity on Electrical Conductivity of Zinc Stearate Nanofilms
    (Elsevier Ltd., 2007) Öztürk, Serdar; Balköse, Devrim; Okur, Salih; Umemura, Junzo
    In this work, stearic acid (StAc) and zinc stearate (ZnSt2) nanofilms were deposited on glass and silver substrates using Langmuir-Blodgett (LB) film technique and their structural and electrical properties were investigated. X-ray diffraction and IR techniques revealed that more crystalline and better films were obtained from ZnSt2 compare to StAc. Electrical conductivity of ZnSt2 LB films with 13 layers having 28 nm thickness were measured in the range of humidity of 20-60% and it is seen that the conductivity was very sensitive to relative humidity (RH) above 40% at 25 °C and showed no hysteresis during adsorption and desorption of water vapor. Water vapor adsorption isotherm of ZnSt2 powders was determined and conductivity increase with humidity was attributed to water vapor adsorption. Constant electrical conductivity of the ZnSt2 films at low relative humidities and at low voltage values is an advantageous property which allows using them as organic nanofilms with insulating properties.