Chemical Engineering / Kimya Mühendisliği

Permanent URI for this collectionhttps://hdl.handle.net/11147/14

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End date: 1999Institution Author: search.filters.institutionAuthor.Çakıcıoğlu Özkan, Seher Fehime

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  • Article
    Citation - WoS: 12
    Citation - Scopus: 17
    Dynamics of Water Vapor Adsorption on Humidity-Indicating Silica Gel
    (Elsevier Ltd., 1998) Balköse, Devrim; Ulutan, Sevgi; Çakıcıoğlu Özkan, Seher Fehime; Çelebi, Sedat; Ülkü, Semra
    Well-defined CoCl2-containing silica gels were prepared by impregnation of the aqueous solution of the salt to silica hydrogel, drying and aging methods. Silica gels having 392-437 m2 g-1 surface area and 0.21-0.37 cm3 g-1 pore volume and having an average particle size of 3 mm were obtained. Aging in CoCl2 solutions decreased the surface area of silica gels from 540 cm2 g-1 to 392-430 m2 g-1 and pore volume from 0.27 to 0.21-0.23 cm3 g-1 for CoCl2 concentration smaller than 0.28 mol dm-3 in silica gel. Adsorbed water desorbed from the gels absorbing 1917-2555 J g-1 energy as determined by differential scanning calorimetry. The CoCl2-containing gels were successfully used in dynamic column experiments, with linear relation between velocities of inlet air and movement of blue to pink boundary. The colour change also makes the detection of the defects in column filling which causes air channelling
  • Article
    Citation - WoS: 19
    Flexible Poly(vinyl Chloride)-Zeolite Composites for Dye Adsorption From Aqueous Solutions
    (Taylor and Francis Ltd., 1996) Balköse, Devrim; Ulutan, Sevgi; Çakıcıoğlu Özkan, Seher Fehime; Ülkü, Semra; Köktürk, Uğur
    Flexible poly(vinyl chloride) (PVC) composites having natural zeolite clinoptillolite were prepared by plastisol-plastigel technology. Adsoption of methylene blue on each raw material and on composites was studied both from an equilibrium and a rate approach. It was observed that the adsorption capacity of zeolite decreased when it was embedded in composites. The equilibrium uptake of methylene blue increased with an increasing zeolite fraction in composites. Methylene blue was adsorbed from a 0.02 g·cm-3 aqueous solution slowly, but was nearly adsorbed completely with a composite having a 0.3 volume fraction of zeolite. The effective diffusion coefficient of methylene blue in composites was of the order of 10-13 m2·s-1 and decreased with increasing filler fraction.