Chemical Engineering / Kimya Mühendisliği
Permanent URI for this collectionhttps://hdl.handle.net/11147/14
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Article Ultrasound Assisted Extraction for the Recovery of Phenolic Compounds From Waste Hazelnut Shell(Yıldız Teknik Üniversitesi, 2020) Dal, Orkan; Şengün, Duygu; Yüksel Özşen, AslıHazelnut shell is the primary byproduct of hazelnut industry which has the potential source of antioxidants, and phenolics with interest of pharmaceutical, food, and cosmetic industries. The main goal of this study is to determine effects of extraction method, extraction time, solvent type, solid to liquid ratio, and particle size on extraction yield, antioxidant capacity, and total phenolic content of waste hazelnut shell. The highest extraction yield was found as 15.4% by using methanol as solvent, in combined extraction for 16 h total extraction time. As for the best antioxidant capacity, 0.0508 mg TE mL-1 was observed by using methanol as a solvent in ultrasonic extraction, whereas the highest phenolic content was found as 0.188 mg GAE mL-1 by Soxhlet extraction with acetone for 8 h. After extraction of hazelnut shell waste, major components were found as oleic and palmitic acids for all solvent types according to GC-MS results.Article Citation - WoS: 31Citation - Scopus: 38Liquefaction of Waste Hazelnut Shell by Using Sub- and Supercritical Solvents as a Reaction Medium(Elsevier, 2019) Demirkaya, Emre; Dal, Orkan; Yüksel, AslıDirect thermochemical biomass degradation to obtain bio-oil by using organic solvents is not a new process type, and it has some advantages over hydrothermal liquefaction technique. However, up to our best knowledge, in this study, hazelnut shell decomposition by using ethanol, acetone and their mixtures at sub/supercritical conditions was studied for the first time in literature. Experiments were carried out between 220-300 degrees C, at three different reaction times (30, 60 and 90 min) for five different solvent ratios. Highest solid conversion achieved at 300 degrees C by using pure ethanol was 64.2%, whereas highest bio-oil yield was found as 44.2% at 300 degrees C with 50/50 (EtOH/Ac: v/v). Ethanol and acetone showed different characteristics during the reactions and their effects on the conversion and bio-oil yield were discussed. Statistical analysis showed that time, temperature, ratio and synergy between temperature-time were affecting parameters for the conversion and bio-oil yield. (C) 2019 Elsevier B.V. All rights reserved.