Chemical Engineering / Kimya Mühendisliği

Permanent URI for this collectionhttps://hdl.handle.net/11147/14

Browse

Search Results

Now showing 1 - 2 of 2
  • Article
    Citation - WoS: 12
    Citation - Scopus: 14
    Extraction of Monophenols and Fractionation of Depolymerized Lignin Oil With Nanofiltration Membranes
    (Elsevier, 2023) Croes, Tim; Dutta, Abhishek; De Bie, Robin; Van Aelst, Korneel; Sels, Bert; Van der Bruggen, Bart
    Organic solvent nanofiltration membranes were employed to fractionate birch derived reductive catalytic fractionated (RCF) lignin oil. This lignin oil is highly depolymerized, with most, if not all chemical compounds lighter than 3 kDa. Sixteen commercially available membranes were investigated for the fractionation, in combination with methanol and ethyl acetate as solvents. Membrane performances were quantified using Gaussian fits of gel permeation chromatograms and separation factor calculations. The separation factor was found to be primarily based on affinities instead of size-exclusion. The silicon-based membranes from Borsig (Germany) and PuraMem S600 from Evonik (UK) proved best at separating lignin into different functional fractions, showing monomer separation factors up to 7.4 and providing a permeate fraction with 88 % phenolic monomer purity. These membranes were further examined in batch diafiltration and two-stage filtration. This increased the separation factor from 7.4 to 25.4, and the monomer purity of the permeate to 95 %, proving that membrane purification of the lignin-derived monophenols is technically feasible.
  • Article
    Citation - WoS: 31
    Citation - Scopus: 38
    Resource Recovery From and Management of Wastewater in Rural South Africa: Possibilities and Practices
    (Elsevier, 2021) Montwedi, Masego; Munyaradzi, Mujuru; Pinoy, Luc; Dutta, Abhishek; Ikumi, David S.; Motoasca, Emilia; Van der Bruggen, Bart
    The continuous reduction in water resource availability is one of the major global societal challenges. Wastewater treatment plants (WWTP) play an important role in this, as they can provide water recovery. Furthermore, effective sanitation services lead to a significant reduction of health risks and protect the environment. However, WWTPs consume large amounts of energy to comply with discharge standards. At the same time, wastewater contains resources, which can be recovered for secondary uses, if treated properly. This is particularly useful for rural South Africa where challenges associated with water-based pollution, declining nutrients and water shortage, require a paradigm shift. This involves the transition of wastewater treatment plants into water, sanitation and resource (nutrients and energy) recovery facilities, leading further to social, economic and environmental sustainability. This process will involve the implementation of engineering tools for predictive modelling of the waste resource recovery systems. This review identifies the conceptual need for such a systematic shift from wastewater treatment to waste recovery facilities in rural South Africa. The targeted impact is to promote and help the uptake of the conversion of wastewater treatment systems into low cost and environmentally sustainable water and resource recovery facilities. Overall, the outlook is positive for the future use of these systems in South-Africa.