Chemical Engineering / Kimya Mühendisliği
Permanent URI for this collectionhttps://hdl.handle.net/11147/14
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Research Project İzmir ilinde içme suyu kaynaklı maruziyet ve risk değerlendirmesi(TÜBİTAK - Türkiye Bilimsel ve Teknolojik Araştırma Kurumu, 2005) Sofuoğlu, Sait Cemil; Kavcar, PınarBu çalışmada İzmir ilinde yarı-ihtimal tabanlı bir örnekleme uygulanarak seçilen hanelerden içme suyu örnekleri toplanmış, her haneden bir kişiye uygulanan anketlerle demografik bilgiler ve içme suyu tüketim oranlarını belirlemek üzere bilgi toplanmıştır. Bunu takiben, elde edilen veriler kullanılarak örnekte yer alan bireyler ve İzmir ili halkı için, sırasıyla, bireysel ve kitlesel maruziyet, kanser harici risk, ve kanser riski seviyeleri uçucu organik maddeler, iz metaller, ve pestisitier için belirlenmiştir.Article Citation - WoS: 20Citation - Scopus: 26Pops in a Major Conurbation in Turkey: Ambient Air Concentrations, Seasonal Variation, Inhalation and Dermal Exposure, and Associated Carcinogenic Risks(Springer Verlag, 2016) Ugranlı, Tuğba; Güngörmüş, Elif; Kavcar, Pınar; Demircioğlu, Eylem; Odabaşı, Mustafa; Sofuoğlu, Sait Cemil; Lammel, Gerhard; Sofuoglu, AysunSemi-volatile organic compounds were monitored over a whole year, by collection of gas and particle phases every sixth day at a suburban site in Izmir, Turkey. Annual mean concentrations of 32 polychlorinated biphenyls (∑32PCBs) and 14 polycyclic aromatic hydrocarbons (∑14PAHs) were 348 pg/m3 and 36 ng/m3, respectively, while it was 273 pg/m3 for endosulfan, the dominant compound among 23 organochlorine pesticides (OCPs). Monte Carlo simulation was applied to the USEPA exposure-risk models for the estimation of the population exposure and carcinogenic risk probability distributions for heating and non-heating periods. The estimated population risks associated with dermal contact and inhalation routes to ∑32PCBs, ∑14PAHs, and some of the targeted OCPs (α-hexachlorocyclohexane (α-HCH), β-hexachlorocyclohexane (β-HCH), heptachlor, heptachlor epoxide, α-chlordane (α-CHL), γ-chlordane (γ-CHL), and p,p′-dichlorodiphenyltrichloroethane (p,p′-DDT)) were in the ranges of 1.86 × 10−16–7.29 × 10−9 and 1.38 × 10−10–4.07 × 10−6, respectively. The inhalation 95th percentile risks for ∑32PCBs, ∑14PAHs, and OCPs were about 6, 3, and 4–7 orders of magnitude higher than those of dermal route, respectively. The 95th percentile inhalation risk for ∑32PCBs and OCPs in the non-heating period were 1.8- and 1.2–4.6 folds higher than in the heating period, respectively. In contrast, the 95th percentile risk levels for ∑14PAHs in the heating period were 4.3 times greater than that of non-heating period for inhalation, respectively. While risk levels associated with exposure to PCBs and OCPs did not exceed the acceptable level of 1 × 10−6, it was exceeded for 47 % of the population associated with inhalation of PAHs with a maximum value of about 4 × 10−6.Article Citation - WoS: 8Citation - Scopus: 8Olive Tree, Olea Europaea L., Leaves as a Bioindicator of Atmospheric Pcb Contamination(Springer Verlag, 2013) Sofuoğlu, Sait Cemil; Yayla, Burak; Kavcar, Pınar; Ateş, Duygu; Turgut, Cafer; Sofuoğlu, AysunOlive tree leaf samples were collected to investigate their possible use for biomonitoring of lipophilic toxic substances. The samples were analyzed for 28 polychlorinated biphenyls (PCB) congeners. Twelve congeners were detected in the samples. PCB-60, 77, 81, 89, 105, 114, and 153 were the most frequently detected congeners ranging from 32 % for PCB-52 to 97 % for PCB-81. Σ12PCBs concentration varied from below detection limit to 248 ng/g wet weight in the sampling area, while the mean congener concentrations ranged from 0.06 ng/g (PCB-128 + 167) to 64.2 ng/g wet weight (PCB-60). Constructed concentration maps showed that olive tree leaves can be employed for the estimation of spatial distrubution of these congenersArticle Citation - WoS: 38Citation - Scopus: 43The Use of Olive Tree (olea Europaea L.) Leaves as a Bioindicator for Environmental Pollution in the Province of Aydın, Turkey(Springer Verlag, 2011) Turan, Dilek; Kocahakimoglu, Cemre; Kavcar, Pınar; Gaygısız, Handan; Atatanır, Levent; Turgut, Cafer; Sofuoğlu, Sait CemilIntroduction: In this study, olive tree leaves, collected from 50 sampling sites throughout the Province of Aydi{dotless}n, Turkey, were used to estimate level of pollution by measuring Al, As, B, Ba, Ca, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Na, Ni, Pb, Sr, and Zn concentrations and calculating pollution factor (PF) values. Materials and methods: After sample preparation, collected leaves were microwave digested, and extracts were analyzed by an inductively coupled plasma-mass spectrometer. Results and discussion: The maximum PF values were ≥10 for a number of elements ranging from 11-13 (Al, As, Cr, Fe, Mn, Ni) to >100 for Cu, Li, and Na. Urban-rural and roadside-nonroadside concentration comparisons showed that some of the elements (As, Cu, and Pb) were at significantly higher levels on urban and/or roadside sampling sites. Summary and conclusion: Correlations and factor analysis showed that there may be common sources for some elements, which included several soil types and anthropogenic activities. Based on the results of the statistical source apportionment, possible sources were narrowed down with help of the constructed elemental concentration maps. In conclusion, utilization of olive tree leaves for biomonitoring and assessment of environmental pollution was shown to be possible in the Mediterranean region where they are indigenous and cultivated.Article Citation - WoS: 30Citation - Scopus: 34Polycyclic and Nitro Musks in Indoor Air: a Primary School Classroom and a Women's Sport Center(Blackwell Publishing, 2010) Sofuoğlu, Aysun; Kıymet, N.; Kavcar, Pınar; Sofuoğlu, Sait CemilIndoor air gas and particulate-phase samples (PM2.5) were collected from a primary school classroom and a women's sport center because children are one of the sensitive population subgroups and women are frequent users of personal care products in addition to the high level of activity in this specific microenvironment. PM2.5 was collected with a Harvard impactor, and polyurethane foam was used for the gas phase. Samples were ultrasonically extracted, concentrated, and analyzed with a GC-MS. The mean gas-phase concentrations in the classroom ranged from 0.12 ± 0.2 ng/m3 for MK to 267 ± 56 ng/m3 for HHCB, while it was from 0.08 ± 0.10 ng/m3 for AHMI to 144 ± 61 ng/m3 for HHCB in the sports center. Particulate-phase average concentrations in the sports center ranged from 0.22 ± 0.11 ng/m3 for ATII to 1.34 ± 071 ng/m3 for AHTN, while it ranged from 0.05 ± 0.02 ng/m3 (musk xylene) to 2.50 ± 0.94 ng/m3 (HHCB) in the classroom. Exposure-risk assessment showed that inhalation route is most probably far less significant than the dermal route; however, it should be noted that the exposure duration covered in this study was not the larger fraction of the dayArticle Citation - WoS: 303Citation - Scopus: 336A Health Risk Assessment for Exposure To Trace Metals Via Drinking Water Ingestion Pathway(Elsevier Ltd., 2009) Kavcar, Pınar; Sofuoğlu, Aysun; Sofuoğlu, Sait CemilA health risk assessment was conducted for exposure to trace metals via drinking water ingestion pathway for Province of İzmir, Turkey. Concentrations of 11 trace metals were measured in drinking waters collected from 100 population weighted random sampling units (houses). The samples were analyzed in atomic absorption spectrometry for arsenic, and inductively coupled plasma-optical emission spectrometry for Be, Cd, Co, Cr, Cu, Mn, Ni, Pb, V, and Zn. Questionnaires were administered to a participant from each sampling unit to determine drinking water consumption related information and demographics. Exposure and risks were estimated for each individual by direct calculation, and for İzmir population by Monte Carlo simulation. Six trace metals (As, Cr, Cu, Mn, Ni, and Zn) were detected in >50% of the samples. Concentrations of As and Ni exceeded the corresponding standards in 20% and 58% of the samples, respectively. As a result, arsenic noncarcinogenic risks were higher than the level of concern for 19% of the population, whereas carcinogenic risks were >10-4 for 46%, and >10-6 for 90% of the population.Article Citation - WoS: 104Citation - Scopus: 115An Exposure and Risk Assessment for Fluoride and Trace Metals in Black Tea(Elsevier Ltd., 2008) Sofuoğlu, Sait Cemil; Kavcar, PınarExposure and associated health risks for fluoride and trace metals in black tea were estimated. Fifty participants were randomly recruited to supply samples from the tea that they drink, and self-administer a questionnaire that inquired about personal characteristics and daily tea intake. Analyzed trace metals included aluminum, arsenic, barium, cadmium, cobalt, chromium, copper, manganese, nickel, strontium, and zinc. Fluoride and four metals (Al, Cr, Mn, Ni) were detected in all samples while barium was detected only in one sample. The remaining metals were detected in >60% of the samples. Fluoride and aluminum levels in instant tea bag samples were greater than in loose tea samples (p < 0.05) while the differences in elemental concentrations of loose and pot bag tea samples were not significant. Median and 90th percentile daily tea intake rates were estimated as 0.35 and 1.1 l/day, respectively. Neither fluoride nor aluminum levels in black tea were found to associate with considerable risks of fluorosis and Alzheimer's disease, respectively. However, carcinogenic risk levels for arsenic were high; R > 1.0 × 10-6 even at the median level. According to sensitivity analysis, daily tea intake was the most influencing variable to the risk except for arsenic for which the concentration distribution was of more importance.