Materials Science and Engineering / Malzeme Bilimi ve Mühendisliği
Permanent URI for this collectionhttps://hdl.handle.net/11147/4719
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Review Citation - WoS: 41Citation - Scopus: 42Review on the Parameters of Recycling Ndfeb Magnets Via a Hydrogenation Process(American Chemical Society, 2023) Habibzadeh, Alireza; Küçüker, Mehmet Ali; Gökelma, MertolRegarding the restrictions recently imposed by China on the export of rare-earth elements (REEs), the world may face a serious challenge in supplying some REEs such as neodymium and dysprosium soon. Recycling secondary sources is strongly recommended to mitigate the supply risk of REEs. Hydrogen processing of magnetic scrap (HPMS) as one of the best approaches for magnet-to-magnet recycling is thoroughly reviewed in this study in terms of parameters and properties. The processes of hydrogen decrepitation (HD) and hydrogenation-disproportio-nation-desorption-recombination (HDDR) are two common methods for HPMS. Employing a hydrogenation process can shorten the production route of new magnets from the discarded magnets compared to other recycling routes such as the hydrometallurgical route. However, determining the optimal pressure and temperature for the process is challenging due to the sensitivity to the initial chemical composition and the interaction of temperature and pressure. Pressure, temperature, initial chemical composition, gas flow rate, particle size distribution, grain size, and oxygen content are the effective parameters for the final magnetic properties. All these influencing parameters are discussed in detail in this review. The recovery rate of magnetic properties has been the concern of most research in this field and can be achieved up to 90% by employing a low hydrogenation temperature and pressure and using additives such as REE hydrides after hydrogenation and before sintering.Article Citation - WoS: 22Citation - Scopus: 25Effect of Solution Heat Treatment on the Microstructure and Crystallographic Texture of In939 Fabricated by Powder Bed Fusion-Laser Beam(Elsevier, 2023) Doğu, Merve Nur; Özer, Seren; Yalçın, Mustafa Alp; Davut, Kemal; Bilgin, Guney Mert; Obeidi, Muhannad Ahmed; Brodin, Hakan; Gu, Hengfeng; Brabazon, DermotThe effect of various solution heat treatment temperatures (i.e., 1120, 1160, 1200 and 1240 & DEG;C) on the microstructure, grain morphology and crystallographic texture of IN939 fabricated by powder bed fusion-laser beam (PBF-LB) was investigated. Microstructural analyses showed that the high-temperature gradient and rapid solidification of the PBF-LB processing caused different resulting microstructures compared to conventionally pro-duced counterparts. The melt pool morphologies and laser scanning paths were examined in the as-fabricated samples in the XZ-and XY-planes, respectively. After the application of solution heat treatment at 1120 & DEG;C, the as-fabricated PBF-LB initial microstructure was still apparent. For solution heat treatments of 1200 & DEG;C and above, the melt pool and scanning path morphologies disappeared and converted into a mixture of columnar grains in the XZ-plane and equiaxed grains in the XY-plane. On the other hand, large equiaxed grains were observed when the samples were solutionized at 1240 & DEG;C. Additionally, g' phase precipitated within the matrix after all solution heat treatment conditions, which led to increase in the microhardness values. According to electron backscatter diffraction (EBSD) analyses, both as-fabricated and solution heat-treated samples had intense texture with {001} plane normal parallel to the building direction. The first recrystallized grains began to appear when the samples were subjected to the solution heat treatment at 1160 & DEG;C and the fraction of the recrystallized grains increased with increasing temperature, as supported by kernel average misorientation (KAM) and grain spread orientation (GOS) analyses.& COPY; 2023 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).Article Citation - WoS: 5Citation - Scopus: 6Effect of Coiling Temperature on the Structure and Properties of Thermo-Mechanically Rolled S700mc Steel(Technical Faculty in Bor, 2022) Di Nunzio, P. E.; Cesile, M. C.; Oktay, S.; Davut, Kemal; Şeşen, M. K.The boron-free S700MC steel is usually produced by exploiting the properties of a ferrite-bainite mixed microstructure formed by coiling the strips at a temperature of about 450 degrees C, i.e.below the bainite starting temperature. With the aim of further enhancing the mechanical properties of 6 to 10 mm thick strips, industrial tests were carried out at a coiling temperature of 600 degrees C to promote the formation of a structure of ferrite and carbides, which is also acceptable for this type of steel. Unexpectedly, a microstructure composed of ferrite and martensite was obtained. Compared to the ferritic-bainitic grade, the new structure is characterized by a slight decrease of the yield point but by an increase of the ultimate tensile strength by no less than 80 MPa, with a transition from a quasi-discontinuous to a clearly continuous yielding behaviour. Accordingly, the ratio of yield strength to tensile strength decreases from 0.90 to 0.75 and the impact energy decreases by 35 J and 60 J for the two gauge levels, respectively. The mechanical behaviour of the strips coiled at high temperature is explained as a direct consequence of the dual phase structure with a hard phase interspersed in a soft ferrite matrix. The presence of martensite is explained by the so-called incomplete bainite reaction. The partial transformation into ferrite after coiling and the long time required for the coil to cool down stabilize the untransformed austenite due to the carbon enrichment making bainite formation at lower temperatures impossible.