Materials Science and Engineering / Malzeme Bilimi ve Mühendisliği

Permanent URI for this collectionhttps://hdl.handle.net/11147/4719

Browse

Filters

2017 - 2019152020 - 20228

Settings

Author: search.filters.author.Topçu, GökhanHas files: Yes

Search Results

Now showing 1 - 10 of 23
  • Article
    Citation - WoS: 7
    Citation - Scopus: 10
    Enhanced Light–matter Interaction in a Hybrid Photonic–plasmonic Cavity
    (Springer, 2021) Gökbulut, Belkıs; İnanç, Arda; Topçu, Gökhan; Özçelik, Serdar; Demir, Mustafa Muammer; İnci, Mehmet Naci
    Strongly concentrated optical fields around a metal nanoparticle in the close vicinity of a dipole noticeably facilitate dramatic changes in the localized density of states due to hybrid photonic–plasmonic mode couplings as compared to that of the pure cavity mode fields. Significant variations of the field intensity in the presence of the metal nanoparticle elucidate enhanced light–matter interaction in a hybrid structure. The enhancement factor of the light–matter interaction is studied through the single-atom cooperativity parameter, which is directly proportional to the ratio of the fluorescence lifetimes of the off-resonant and on-resonant emission. A compact and cost-effective hybrid device, which includes a microfiber cavity, supporting whispering gallery modes, and a well-defined solid nanostructure, consisting of a gold nanoparticle core, overcoated by a silica shell, and decorated with CdS/CdSe quantum dots, is demonstrated to offer an outstanding potential for the enhancement of light–matter interaction. Surface plasmons of a gold nanoparticle, placed inside a hollow cylindrical nanostructure at the surface of a microfiber, are activated upon excitation of the dipoles of the quantum emitters, which are on-resonance with the whispering gallery mode. Time-resolved experiments demonstrate that the single-atom cooperativity parameter of the quantum dots is enhanced by a factor of about 4.8 in the presence of the gold nanoparticle being simultaneously in strong interaction with the cavity mode field and the metal nanoparticle’s surface plasmons.
  • Correction
    Correction To: Enhanced Light–matter Interaction in a Hybrid Photonic–plasmonic Cavity
    (Springer, 2022) Gökbulut, Belkıs; İnanç, Arda; Topçu, Gökhan; Özçelik, Serdar; Demir, Mustafa Muammer; İnci, Mehmet Naci
    In this article the statement in the Funding information section was incorrect. The correct Funding information is as follows. ‘Dr Belkıs Gökbulut acknowledges TUBITAK for the financial support provided under Contract Number 120F323’.
  • Article
    Citation - WoS: 3
    Citation - Scopus: 6
    Hybrid Photonic-Plasmonic Mode-Coupling Induced Enhancement of the Spontaneous Emission Rate of Cds/Cdse Quantum Emitters
    (Elsevier, 2022) Gökbulut, Belkıs; İnanç, Arda; Topçu, Gökhan; Özçelik, Serdar; Demir, Mustafa Muammer
    n this paper, a hybrid photonic-plasmonic resonator, which comprises an electrospun polymer fiber with a micrometer diameter and a core/shell nanostructure with a gold nanoparticle core, is constructed to investigate the dynamics of the coupled spontaneous emission of CdS/CdSe quantum dots (QDs). The gold nanoparticle core; covered with a silica shell, anchored with individual CdS/CdSe QDs, is placed inside a hollow cylindrical nanocavity formed on the surface of the microfiber to enable integration of the optical mode with the plasmonic effect, which is induced by the localized surface plasmons of the metal nanoparticle being present in the vicinity of the dipoles. The spontaneous emission rate of the QDs, coupled into the hybrid photonic-plasmonic mode, is measured to enhance by a factor of 23 via a time-resolved experimental technique. This result suggests that the regeneration of the optical mode-field inside the photonic-plasmonic resonator through the interaction of the dipoles with the localized surface plasmons of a metal nanoparticle strongly enhances the density of the electromagnetic states of the quantum emitters to facilitate an enhanced spontaneous emission within the host medium of the proposed polymer based-photonic structure.
  • Article
    Citation - WoS: 5
    Citation - Scopus: 7
    Effect of High Salinity and Temperature on Water-Volcanic Rock Interaction
    (Springer, 2021) Gören, Ayşegül Yağmur; Gören, Ayşegül Yağmur; Topçu, Gökhan; Demir, Mustafa Muammer; Demir, Mustafa M.; Baba, Alper; Baba, Alper
    In order to understand the processes occurring in natural hydrothermal systems, it was carried out a series of water-volcanic rock interaction studies in the laboratory and an intermediate volcanic rock samples from geothermal production wells in Tuzla geothermal field (TGF) in western Turkey. A high-pressure autoclave was used to conduct water-rock interaction experiments under similar conditions of the field. Rainwater and seawater were treated with volcanic rocks at 140 degrees C (reservoir temperature) and 4.5 bar pressure. The change in the ionic content of the resulting fluids was examined in terms of the type of volcanic rocks and mineral saturation index. The results indicate that talc and diopside minerals in geothermal systems may cause scaling at high temperatures depending on the geothermal fluid and pH.
  • Article
    Citation - WoS: 3
    Citation - Scopus: 5
    Plasmon-Induced Spectral Tunability of Perovskite Nanowires
    (Elsevier, 2021) Gökbulut, Belkıs; Topçu, Gökhan; Demir, Mustafa Muammer; İnci, Mehmet Naci
    In this paper, plasmon-assisted spectral tunability in random media, composed of Perovskite (CsPbBr3) nanowires surrounded by Au nanoparticle clusters in polystyrene matrix, is achieved. The interaction between the surface plasmons and the quantum sources is observed to generate photoluminescence from the higher excited state energy levels of the excited semiconductor nanowires, which results in a blueshifted fluorescence emission of 50 nm. The localized surface plasmon properties are also determined to be tuned by plasmonic pumping of the quantum sources at different resonant frequencies. Thus, the first observation of the tunable blueshifted fluorescence emission of the semiconductor nanocrystals surrounded by plasmonic nanoparticle aggregates is achieved. The dramatic changes in the spectral profiles of the fluorescent nanowires are attributed to be due to the fast dynamics surface enhanced fluorescence mechanism.
  • Article
    Citation - WoS: 36
    Citation - Scopus: 39
    Recent Developments of Colorimetric Mechanical Sensors Based on Polymer Composites
    (Royal Society of Chemistry, 2020) İnci, Ezgi; Topçu, Gökhan; Güner, Tuğrul; Demirkurt, Merve; Demir, Mustafa Muammer
    Colorimetric mechanical (force, pressure, strain, and impact) sensors allow naked-eye visualization of existing structural deformations of a system occurring upon application of a mechanical action. The combination of mechanochromic materials with polymers offers a practical approach to designing and fabricating these sensors. Polymers as matrices can tolerate a wide range of forces and permits reusability of the sensors. On the other hand, mechanochromic materials provide unique colour properties depending on the type of mechanical action. They have also been frequently employed for the quantification of mechanical forces. As an example, non-centrosymmetric crystals are combined with polymers for sensing impact forces. Structures with photoluminescence and scattering and plasmonic resonances can be used to fabricate strain and pressure responsive composite materials, respectively. This study reviews recent advances in colorimetric mechanical sensor systems prepared using polymers and inorganic and organic mechanochromic materials working under a wide range of forces.
  • Article
    Citation - WoS: 3
    Citation - Scopus: 4
    Experimental and First-Principles Investigation of Cr-Driven Color Change in Cesium Lead Halide Perovskites
    (American Institute of Physics, 2019) Özen, Sercan; Güner, Tuğrul; Topçu, Gökhan; Özcan, Mehmet; Demir, Mustafa Muammer; Şahin, Hasan
    Herein, we report room temperature Cr-doping for all-inorganic perovskites that have attracted great attention in recent years due to their extraordinary optical properties, low cost, and ease of synthesis. Incorporation of Cr 3 + ions into the perovskite crystal lattices is achieved by following a facile route involving an antisolvent recrystallization method at room temperature. It is shown that both Cr-doping and formation of crystals in the CsPbBr x Cl 3 - x phase are provided by increasing the concentration of the CrCl 3 solution. It is also observed that the doping procedure leads to the emergence of three types of distinctive peaks in the PL spectrum originating from CsPbBr x Cl 3 - x domains (476-427nm), Cr-strained host lattices (515nm), and midgap states formed by Cr dopants (675-775nm). It is also found that the Cr-doped perovskites emitting a dark violaceous color change their color to white with a high color rendering index (88) in 30-day time intervals. Easy-tunable optical properties of all-inorganic Cs perovskites indicate their great potential for future optoelectronic device applications.
  • Article
    Citation - WoS: 4
    Citation - Scopus: 4
    Color-Tunable All-Inorganic Cspbbr3 Perovskites Nanoplatelet Films for Photovoltaic Devices
    (American Chemical Society, 2019) Özcan, Mehmet; Özen, Sercan; Topçu, Gökhan; Demir, Mustafa Muammer; Şahin, Hasan
    Herein, we demonstrate a novel coating approach to fabricate CsPbBr3 perovskite nanoplatelet film with heat-free process via electrospraying from precursor solution. A detailed study is carried out to determine the effect of various parameters such as ligand concentration, electric field, flow rate, etc. on the optical properties. By controlling the volume ratios of the oleylamine (OAm) and oleic acid (OA), the coalescing and thickness of the resulting nanoplatelets can be readily tuned that results in control over emission in the range of 100 nm without any antisolvent crystallization or heating processes. The varying electrical field and flow rate was found as inefficient on the emission characteristics of the films. In addition, the crystal films were obtained under ambient conditions on the ITO coated glass surfaces as in the desired pattern. As a result, we demonstrated a facile and reproducible way of synthesizing and coating of CsPbBr3 perovskite nanoplatelets which is suitable for large-scale production. In this method, the ability of tuning the degree of quantum confinement for perovskite nanoplatelets is promising approach for the one-step fabrication of crystal films that may enable the use in optoelectronics.
  • Article
    Citation - WoS: 6
    Citation - Scopus: 8
    Enhanced Spontaneous Emission Rate in a Low-Q Hybrid Photonic-Plasmonic Nanoresonator
    (American Chemical Society, 2019) Gökbulut, Belkıs; İnanç, Arda; Topçu, Gökhan; Ünlütürk, Seçil Sevim; Özçelik, Serdar; Demir, Mustafa Muammer; İnci, Mehmet Naci
    In this paper, CdTe quantum dots (QDs)-doped single electrospun polymer nanofibers are partially coated with gold nanoparticles to form distinct hybrid photonic-plasmonic nanoresonators to investigate the critical role of the cavity-confined hybrid mode on the modification of the spontaneous emission dynamics of the fluorescent emitters in low-Q photonic cavities. A total enhancement factor of 11.2 is measured via a time-resolved experimental technique, which shows that there is an increase of about three times in the spontaneous emission rate for the QDs-doped gold nanoparticle-decorated nanofibers as they are compared with those uncoated ones. The physical mechanism affecting the spontaneous emission rate of the encapsulated QDs in such a hybrid photonic-plasmonic nanoresonator is explained to be due to regeneration of the mode field in the nanofiber cavity upon the interaction of the dipoles with the surface plasmons of distinctive gold nanoparticles that surround the outer surface of the nanofiber.
  • Article
    Citation - WoS: 25
    Citation - Scopus: 28
    Colorimetric and Plasmonic Pressure Sensors Based on Polyacrylamide/Au Nanoparticles
    (Elsevier, 2019) Topçu, Gökhan; Güner, Tuğrul; İnci, Ezgi; Demir, Mustafa Muammer
    Colorimetric stimuli-responsive nanomaterials have emerged as an eminent tool for sensor applications. Among this class of sensing elements, gold nanoparticle-based (Au NP) nanostructures are promising materials due to their plasmonic features. In this study, free-standing flexible polymeric films having intense optical response upon application of mechanical pressure were fabricated based on polyacrylamide (PAAm) and Au NPs. Pressure may cause plasmonic shift most probably due to the disassembly of the clusters from blue to reddish individual particles depending on the extent of pressure. Temperature, time, and extent of pressure were examined in terms of spectral change of Au particles. The sensor films depict working range up to 160 MPa, which shows minor change at elevated temperatures probably due to the stress induced crystallization of PAAm. For practical applications, a simple red-green-blue (RGB) space-based algorithm was presented for smartphone-assisted detection of applied pressure. Moreover, the PAAm/Au composite structure shows self-healing without any additive under ambient conditions even after divided into pieces. (C) 2019 Elsevier B.V. All rights reserved.