Materials Science and Engineering / Malzeme Bilimi ve Mühendisliği

Permanent URI for this collectionhttps://hdl.handle.net/11147/4719

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Department: search.filters.department.İzmir Institute of Technology. Mechanical EngineeringInstitution Author: search.filters.institutionAuthor.Demir, Mustafa Muammer

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Now showing 1 - 2 of 2
  • Article
    Citation - WoS: 17
    Citation - Scopus: 17
    Monitoring the Doping and Diffusion Characteristics of Mn Dopants in Cesium Lead Halide Perovskites
    (American Chemical Society, 2018) Güner, Tuğrul; Akbalı, Barış; Özcan, Mehmet; Topçu, Gökhan; Demir, Mustafa Muammer; Şahin, Hasan
    Cesium lead perovskites, in the form of CsPbX3 or Cs4PbX6, have been widely used for various optoelectronic applications due to their exceptionally good optical properties. In this study, the effect of Mn doping on the structural and optical properties of cesium lead halide perovskite crystals are investigated from both experimental and theoretical points of view. It is found that adding MnCl2 during the synthesis not only leads to a Mn-driven structural phase transition from Cs4PbBr6 to CsPbCl3 but also triggers the Br- to Cl- halide exchange. On the other hand, it is observed that, under UV illumination, the color of Mn-doped crystals changes from orange to blue in approximately 195 h. While the intensity of Mn-originated photoluminescence emission exponentially decays in time, the intensity of CsPbCl3-originated emission remains unchanged. In addition, diffusive motion of Mn ions results in both a growing population of MnO2 at the surface and transition of the host into a cesium-rich Cs4PbCl6 phase.
  • Article
    Citation - WoS: 22
    Citation - Scopus: 28
    Mechanical Interlocking Between Porous Electrospun Polystyrene Fibers and an Epoxy Matrix
    (American Chemical Society, 2014) Demir, Mustafa Muammer; Horzum, Nesrin; Taşdemirci, Alper; Turan, Ali Kıvanç; Güden, Mustafa
    An epoxy matrix filled with nonwoven mats of porous polystyrene (PS) fibers processed by an electrospinning was compression tested at quasi-static (1 × 10–3 s–1) and high strain (315 s–1) rates. The electrospun PS fibers with a diameter between 6 and 9 μm, accommodated spherical pores on the surface with the sizes ranging from 0.1 to 0.2 μm. The filling epoxy matrix with 0.2 wt % PS fibers increased the compressive elastic modulus and compressive strength over those of neat epoxy resin. The microscopic observations indicated that the surface pores facilitated the resin intrusions into the fiber, enhancing the interlocking between resin and fibers, and increased the deformation energy expenditure of the polymer matrix.