Materials Science and Engineering / Malzeme Bilimi ve Mühendisliği

Permanent URI for this collectionhttps://hdl.handle.net/11147/4719

Browse

Filters

20222

Settings

Access Right: Embargoed AccessSubject: search.filters.subject.Tribocorrosion

Search Results

Now showing 1 - 2 of 2
  • Article
    Citation - WoS: 6
    Citation - Scopus: 6
    Tribocorrosion-Resistant Ti40nb-Tin Composites Havingtio(2)-Based Nanotubular Surfaces
    (American Chemical Society, 2022) Çaha, İhsan; Alves, Alexandra Cruz; Chirico, Caterina; Pinto, Ana Maria; Tsipas, Sophia; Gordo, Elena; Toptan, Fatih
    A novel multifunctional material was developed byhard TiN particle reinforcement addition to a beta-type Ti40Nb alloy,followed by surface functionalization, yielding the formation of ananotubular layer. Corrosion and tribocorrosion behaviors wereinvestigated in a phosphate-buffered saline solution at bodytemperature. The results revealed that the Ti40Nb-TiNcomposites presented similaripassandE(i=0)values together withrelatively similarRoxandCox. However, its tribocorrosion resistancedrastically improved (wear volume is almost 15 times lower than anunreinforced alloy) as a consequence of the load-carrying effectgiven by the reinforcement phases. The corrosion and tribocorro-sion behaviors were further improved through surface functionaliza-tion as observed by significantly loweripassand higherRoxvalues andalmost undetectable wear volume loss from tribocorrosion tests dueto the formation of a well-adhered anatase-rutile TiO2-based nanotubular layer.
  • Article
    Citation - WoS: 20
    Citation - Scopus: 20
    Preliminary Tribo-Electrochemical and Biological Responses of the Ti-Tib In-Situ Composites Intended for Load-Bearing Biomedical Implants
    (Elsevier, 2022) Sousa, Lia; Toptan, Fatih; Alves, Alexandra C.; Costa, N. A.; Gemini Piperni, Sara; Rossi, Andre Linhares; Ribeiro, Ana R.; Simöes, Sönia; Toptan, Fatih
    Poor tribocorrosion resistance of Ti and its alloys remains as a concern for load-bearing biomedical implants. Despite being an effective method to improve tribocorrosion resistance, titanium matrix composites (TMCs) have yet to be used in this type of applications. In-situ TiB (titanium boride) and TiC (titanium carbide) reinforcement phases have been considered as one of the best options to produce TMCs once these phases present high compatibility and strong interfacial bonding with Ti. Although the effect of these phases on the mechanical properties of Ti has been thoroughly researched in the last years, their effect on corrosion, tribocorrosion and biocompatibility of Ti is yet to be fully understood. In this work, in-situ Ti-TiB-TiCx composites obtained by reactive hot pressing showed identical corrosion response compared to the unreinforced Ti but displayed improved tribocorrosion behaviour. Under 0.5 N load, composites presented as average a reduction of 51% in wear volume loss and under 10 N the reduction was up to 93%. Early biological tests showed promising results, as composites were biocompatible and induced osteoblasts spreading and possibly proliferation most probably due to composite chemistry and surface hardness.