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Heat and Mass Transfer Characteristics of Adsorbents in Heat Pump and Refrigerator
(01. Izmir Institute of Technology, 2023) Gündoğan, Şefika Çağla; Çakıcıoğlu Özkan, Seher Fehime
Due to increasing drought, pandemic and climate crisis in recent years, researchers have increased their studies on environmentally friendly energy use. Although there are technological developments in the production of energy from renewable energy sources, the storage of this produced energy is still a problem that awaits a solution. At this point, adsorption heat pumps with high primary energy efficiency come to the fore as a developing technology and attract the attention of researchers. However, low heat transfer properties in the adsorbent bed reduce the performance of adsorption heat pumps and limit their applications. The aim of this thesis was to improve the performance of the adsorption heat pump by increasing the effective thermal conductivity within the adsorbent bed. Two methods have been employed to enhance the effective thermal conductivity. In the first method, which was unconsolidated adsorbent bed design, it was aimed to increase the thermal conductivity of the bed with metal additives with a continuous structure. In the second method, which is known as consolidated bed design, the effective thermal conductivity of zeolite 13X was tried to be enhance with a high conductive material, reduced graphene oxide. In the experimental studies, it was observed that the thermal conductivity increased from 0.12 W/m.K to 0.28 W/m.K in unconsolidated bed design by means of fin-shaped metal additive. In consolidated adsorbent bed design, the effective thermal conductivity of the Graphene/Zeolite 13X (1 wt% Graphene) was determined as 0.1613 W/m.K. In theoretical studies, the effect of thermal conductivity in the temperature, pressure and adsorbate concentration was investigated. The indirect and direct effects of effective thermal conductivity on specific cooling/heating power (SCP/SHP) and coefficient of performance (COP) values were examined. Although the effect of thermal conductivity on COP was ignored in most of the studies in the literature, it was observed that COP increased from 0.01 to 0.10 when thermal conductivity increased from 0.12 W/m.K to 1 W/m.K.
An Experimental and Numerical Study on Heat and Mass Transfer in Adsorbent Bed of an Adsorption Heat Pump
(Izmir Institute of Technology, 2012) Gediz İliş, Gamze; Mobedi, Moghtada
Because of the limited conventional energy sources, the improvement of thermal heat pumps has gained attentions of researchers in recent years. Adsorption heat pump, which is a kind of thermal heat pump, can be directly operated with the low temperature heat sources such as waste heat, geothermal and solar energy. Although, adsorption heat pump has many advantages compared to the conventional heat pump, there are still many difficulties for its practical application. Adsorbent bed is one the most important component of adsorption heat pump. Heat and mass transfer in the adsorbent bed should be accelerated in order to attain a small sized, high powered adsorption heat pump. In this thesis, a theoretical and experimental study is performed on heat and mass transfer in an adsorbent bed. A detailed literature survey on the design of adsorbent bed is done. The designed adsorbent beds are classified, and their advantages and disadvantages are discussed. In order to analyze heat and mass transfer in an adsorbent bed, transport of adsorptive in an adsorbent particle should be well known. A theoretical study on heat and mass transfer in a single adsorbent particle located in an infinite adsorptive medium is performed to understand the effects of internal and external heat and mass transfer resistances. Heat and mass transfer equations for an annular adsorbent bed are derived for uniform and non-uniform pressure approaches and numerically solved to determine temperature and concentration profiles in the bed. These equations are also non-dimensionalized to reduce number of governing parameters. The non-dimensionalization of the equations yields important dimensionless parameters that can be used not only to describe heat and mass transfer in an adsorbent bed but also employ them during design of the bed. Furthermore, an experimental setup was designed and constructed to validate the obtained numerical results. The experimental results were compared with the solution of the numerical results and a good agreement was obtained between them.

Phd Degree / Doktora

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