Phd Degree / Doktora
Permanent URI for this collectionhttps://hdl.handle.net/11147/2869
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Doctoral Thesis Modulation of terahertz waves by VO2 based metamaterials(01. Izmir Institute of Technology, 2023) Noori, Aileen; Aygün Özyüzer, GülnurTerahertz (THz) waves, being a form of electromagnetic radiation have frequen-cies ranging from 0.1 THz to 10 THz. Due to the lack of suitable radiation sources and detectors, this region is not well known. Interaction with THz waves becomes more effective by introducing the metamaterials (MM) and metasurfaces (MS) (3D and 2D, respectively), which are made up of artificially subwavelength compositions arranged in periodic arrays. MMs provide a unique control on the propagation of (EM) waves and their geometries determine their properties. Recently, coding MM has made it possible to regulate the far-field scattering pattern of EM waves. In other words, it is possible to shape the THz wavefront by changing the sequence of the coding unit cells into a 2D surface pattern. The reflection phase of the two types of unit cells in 1-bit coding MM is 0 and π. In this thesis, two different types of coding MMs were designed and fabricated. One type is hard-coded (metal-based), while the other is based on VO2 thin film. Both types of samples share a similar structure, which includes a sapphire substrate, a gold patch, a PET layer serving as a dielectric spacer, and a ground gold layer. However, there is an additional layer of VO2 beneath the gold patch and on top of the sapphire substrate in one of the fabricated MMs. The coding MM consists of two identical unit cells, with the only distinction being the size of the gold patch's side. This size determines whether the unit cell is considered as 0-bit or 1-bit. When the side size is 90 µm, the unit cell is 0-bit. On the other hand, when the side sizes are 60 µm and 70 µm (for different samples), the unit cell is 1-bit. Two different sets of hard-coded MM were fabricated. One set is composed of the 60-90 µm unit cells arranged in the form of checkerboard and stripe designs. The other set is made of 70-90 µm unit cells arranged in the form of checkerboard and stripe designs. The samples were measured with a custom-built setup and the THz full spectrum (0.50-0.75 THz) was obtained at each reflection angle. The results indicate that the checkerboard samples' reflection angle for each frequency has a good consistency with the calculations. Since the detector was obstructing the incoming beam, the measurable angle range begins at 23 degrees from normal incidence. This issue limits the ability to obtain the maximum scattering pattern of the strip design samples. At the final section of the thesis, the VO2-based MM, was fabricated and mea-sured. VO2 layer was used in this structure, due to its phase-changing characteristic. It undergoes a reversible transformation from an insulator to a metallic state at about 68◦C. The initial concept was to design and fabricate the MM just entirely out of 1-bit (60 µm) unit cells. After that, using a CW laser pump and a digital micromirror (DMD), convert this 1-bit into the 0-bit unit cell by modifying the conductivity of the VO2 layer of each individual unit cell. Using this idea, it was possible to develop a tunable digital MM. However, the CST simulation results demonstrated that the proposed MM is ineffective due to the significant amplitude difference between the 0 and 1-bit unit cells. Due to that, using the VO2-based unit cells (0 and 1-bit) the striped and checkerboarded pattern of MMs was designed and fabricated. The VO2 conductivity was modulated using a CW 915 nm laser beam. The measurement results show that VO2-based MM can be used for THz beam splitting at room temperature, and the scattering pattern weakens when the laser is illuminated over the sample, causing the VO2 layer to turn conductive. CST Studio Suite simulation software was used to determine the unit cells' geo-metrical dimensions, amplitudes, and phases. The analytical calculations were performed using MATLAB. The investigated MM has the potential to be used in THz communica-tions.Doctoral Thesis Bose-Einstein Condensation and Black Holes in Dark Matter and Dark Energy(01. Izmir Institute of Technology, 2023) Gültekin, Kemal; Erdem, RecaiThe main aim of this study is to reveal curved space and particle physics effects on the formation of Bose-Einstein condensate scalar fields in cosmology and around a black hole. Cosmological scalar fields for dark energy and dark matter may be considered as a result of Bose-Einstein condensation. In this regard, our main attention will be devoted to Bose-Einstein condensates in curved space. By considering the dynamics of a scalar Bose-Einstein condensation at a microscopic level, we first study the initial phase of the formation of condensation in cosmology. To this end, we initially introduce an effective Minkowski space formulation that enables considering only the effect of particle physics processes, excluding the effect of gravitational particle production and enabling us to see cosmological evolution more easily. Then, by using this formulation, we study a model with a trilinear coupling that induces the processes. After considering the phase evolution of the produced particles, we find that they evolve towards the formation of a Bose-Einstein condensate if some specific conditions are satisfied. In principle, the effective Minkowski space formulation introduced in this study can be applied to particle physics processes in any sufficiently smooth spacetime. In this regard, we also analyse if a condensate scalar field is realized in the spacetime around a Reissner - Nordstrøm black hole. We find that the produced particles of particle physics processes are localized in a region around the black hole and have a tendency toward condensation if the emerged particles are much heavier than ingoing particles. We also find that such a configuration is phenomenologically viable only if the scalars and the black hole have dark electric charges. Finally, we consider gravitational collapse around Schwarzschild black holes and form a first step towards a study in future about the effects of gravitational collapse on Bose-Einstein condensation.Doctoral Thesis Photonic Crystal Textiles(Izmir Institute of Technology, 2022) Çetin, Zebih; Sözüer, Hüseyin SamiPhotonic crystals are man-made structures that can be used to manipulate the flow of light. They are classified as one-, two- and three-dimensional photonic crystals according to the periodic variation of the dielectric profile in space. Apart from artificial photonic crystals there are numerous examples of naturally occurring photonic crystals which have evolved mostly for structural coloration, such as wings of butterflies, natural opal gem stone, peacock feathers to name a few. Using photonic crystal structures the propagation of electromagnetic waves can entirely be prohibited by means of photonic band gap. Considering the fact that approximately two thirds of the heat loss of the human body occurs through electromagnetic radiation with a wavelength around 10 microns, it becomes important to consider photonic crystals for the purpose of reducing heat loss in textiles. We observe that the textile, by virtue of the fact that it has been produced by weaving, already has a periodic structure, and thus is a potential candidate for a photonic crystal. With the right fiber that the textile is woven and the right weave pattern, the textile itself would be a photonic crystal. The most common weave patterns used in the textile industry are plain weave, basket weave, dutch weave and twill weave. In this thesis, we used the finite-difference time-domain method to search for the optimum weave pattern to minimize heat loss by the human body.Doctoral Thesis Performance Enhancement of Graphene/Silicon Based Near-Infrared Schottky Photodiodes(Izmir Institute of Technology, 2022) Fidan, Mehmet; Çelebi, CemThis thesis presents an experimental investigation on the performance enhancement of graphene/silicon based near-infrared Schottky photodiodes. The photodiode devices were fabricated by transferring CVD graphene layers onto n-type silicon (n-Si) substrates. The samples exhibited strong Schottky diode character and had high spectral sensitivity at 905 nm peak wavelength. The Schottky contact characteristics of the samples (e.g., barrier height, ideality factor and sheet resistance) were determined by analyzing the current-voltage measurement data. All the samples demonstrated a clear photovoltaic activity under light illumination. The Schottky barrier height (SBH) in Gr/n-Si photodiodes was tuned as a function of light power density. Light power density driven modification of the SBH was correlated with the variation in the measured open-circuit voltage. The impact of junction area and number of graphene layers on the spectral responsivity and response speed of Gr/n-Si based Schottky photodiodes were also investigated. Firstly, three batches of Gr/n-Si photodiode samples with junction area of 4 mm2, 12 mm2 and 20 mm2 were produced by transferring monolayer CVD graphene on individual n-Si substrates. The sample with 20 mm2 junction area reached a spectral response of 0.76 AW-1, which is the highest value reported in the literature for self-powered Gr/n-Si Schottky photodiodes without the modification of graphene electrode. In contrast to their spectral responsivities, the response speed of the samples was found to be lowered as a function of the junction area. After that, we increased the number of graphene layers on n-Si. Wavelength-resolved and time-dependent photocurrent measurements demonstrated that both spectral responsivity and response speed are enhanced as the number of graphene layers is increased from 1 to 3 on n-Si substrates. This thesis showed that the device performance of Gr/n-Si Schottky photodiodes can be modified simply by changing the size of graphene electrode and/or as well as the number of graphene layers on n-Si without need of external doping of graphene layer or engineering Gr/n-Si interface.Doctoral Thesis Electronic, Magnetic and Transport Properties of Graphene Quantum Dots With Charged Impurities(Izmir Institute of Technology, 2020) Polat, Mustafa; Güçlü, Alev DevrimIn this thesis, electronic, magnetic, and transport properties of armchair edged hexagonal and zigzag edged triangular graphene quantum dots (GQDs) are investigated in the presence of charged impurities. In this manner, a special attention has been paid to the Coulomb impurity problem in these structures. The collapse of the wave functions starting from the 1S$_{1/2}$ state is studied in the presence of not only the Coulomb impurity but also in the presence of a Coulomb charged vacancy with the help of tight-binding and extended mean-field Hubbard (MFH) models. Here, we report an interaction induced renormalization of the critical coupling constant ($\beta_{c}$). In addition, our results suggest that the induced charge for the interacting fermions is smaller than that of the non-interacting fermions. Furthermore, the transport coefficients reveal two different characteristics of the subcritical ($\beta$ $<$ $\beta_{c}$) and supercritical ($\beta$ $>$ $\beta_{c}$) regimes. As for the charged vacancy, the bare carbon vacancy induces a local magnetic moment in the hexagonal GQDs, but it is suppressed when the vacancy is charged with the subcritical Coulomb potential. Except the pristine cases of the GQDs, we numerically study a Coulomb impurity problem for the interacting fermions restricted in disordered hexagonal GQDs. In the presence of randomly distributed lattice defects and spatial potential fluctuations induced by Gaussian impurities, the response of $\beta_{c}$ for atomic collapse is mainly investigated by local density of states (LDOS) calculations within the MFH model. We find that both types of disorder cause an amplification of the critical threshold. As for the zigzag edged triangular GQDs, in the presence of the bare vacancy, we exactly obtain the spin splitting with the help of LDOS calculations in the energy spectrums, which are dominated by the edge states around the Fermi level. Similar to the hexagonal GQDs, if the vacancy is charged, the local magnetic moment disappears in these GQDs.Doctoral Thesis Physics of Higher Spin Fields(Izmir Institute of Technology, 2020) Sargın, Ozan; Güçlü, Alev DevrimSpin-3/2 fields are the next spin multiplet we look for in the general particle search. Although these fields can be either fundamental vector-spinors or just excited leptons and quarks we assume that they are fundamental throughout this thesis. These higher-spin fields, described by the Rarita-Schwinger equations have to obey certain constraints to have correct degrees of freedom when they are on the physical shell. \par In the first chapter after the introduction, we introduce these spinor-vector fields to the reader by first going through the different representations that can be employed to describe them. We then recapitulate some facts on the most general free lagrangian and the propagator for these fields. \par In the next chapters we investigate different phenomenological implications. We start out in chapter \ref{chap:1} with a massive spin-3/2 field hidden in the standard model (SM) spectrum thanks to the form of the special interaction that vanishes when the field falls into the mass shell. Different collider signatures are investigated through analytical computations and numerical predictions. \par In chapter \ref{chap:2}, we assume that the Higgs boson stays stable via a finely tuned hidden sector which involves a spin-3/2 field that is split from the SM and whose sole contact with it at the renormalizable level is through the neutrino portal. Then, the total mass correction to the Higgs mass is used as a constraint to calculate the mass scale of the spin-3/2 field. \par Lastly, we investigate the possible role that a spin-3/2 field could play in leptogenesis. Our model incorporates a spin-3/2 field in addition to the type-I see-saw fields in inducing the CP asymmetry and mitigating the naturalness problem of the Higgs boson. We investigate the plausibility in regard to successful leptogenesis with no side effects, specifically the naturalness of the Higgs boson and correct prediction of the active neutrino masses.Doctoral Thesis Gauged and Geometric Vector Fields at the Mev Scale(Izmir Institute of Technology, 2020) Puliçe, Beyhan; Demir, Durmuş AliIn this thesis, we have studied gauged and geometric vector fields at the MeV scale in two main parts. The basic framework of these two parts are given briefly as follows. In the first part (Chapter \ref{chapter-U(1)}), we have built a family-nonuniversal $U(1)^\prime$ model populated by an MeV-scale sector with a minimal new field content which explains the recent anomalous beryllium decays. Excited beryllium has been observed to decay into electron-positron pairs with a $6.8~\sigma$ anomaly. The process is properly explained by a $17$ MeV proto-phobic vector boson. In this thesis, we consider a family-nonuniversal $U(1)^{\prime}$ that is populated by the $U(1)^{\prime}$ gauge boson $Z^\prime$ and a scalar field $S$. The kinetic mixing of $Z^\prime$ with the hypercharge gauge boson, as we show by a detailed analysis, generates the observed beryllium anomaly. We show that beryllium anomaly can be explained by an MeV-scale sector with a minimal new field content. In the second part (Chapter \ref{chapter-GDM}), we have shown how a light vector particle can arise from metric-affine gravity and how this particle fits the current data and constraints on the dark matter. We show that, metric-affine gravity , which involves metric tensor and affine connection as two independent fields, dynamically reduces, in its minimal form, to the usual gravity plus a massive vector field. The vector $Y_\mu$ is neutral and long-living when its mass range lies in the range $9.4\ {\rm MeV} < M_Y < 28.4\ {\rm MeV}$. Its scattering cross section from nucleons, which is some 60 orders of magnitude below the current bounds, is too small to facilitate direct detection of the dark matter. This property provides an explanation for whys and hows of dark matter searches. We show that due to its geometrical origin the $Y_\mu$ couples only to fermions. This very feature of the $Y_\mu$ makes it fundamentally different than all the other vector dark matter candidates in the literature. The geometrical dark matter we present is minimal and self-consistent not only theoretically but also astrophysically in that its feebly interacting nature is all that is needed for its longevity.Doctoral Thesis Electronic Struture of Organic Molecules Containing Transition-Metal Atoms(Izmir Institute of Technology, 2019) Kandemir, Zafer; Bulut, NejatHemoglobin including iron atom, vitamin B12 containing cobalt atom and ruthenium- based dye molecules are examples of organic molecules. We explore whether electron correlations arising from transition-metal atoms have any special role in the functioning of organic molecules using the effective multi-orbital Anderson model. We choose deoxy and oxy-heme molecules which are examples of hemoglobin derivatives because they have many experimental and theoretical studies. The experimental magnetic susceptibility measurements find that deoxy and oxy-heme molecules exhibit a high-spin to low-spin transition. We use four different computational methods: density functional theory (DFT), DFT+U, DFT+mean-field approximation (DFT+MFA) and DFT+quantum Monte Carlo (DFT+QMC) to study this transition. In this thesis, we compare the results of these methods with each other and the experimental results. DFT and DFT+U methods do not yield the high-spin state for deoxy-heme. DFT method correctly does not find the location of impurity bound state (IBS) known as correlated new electronic states. These methods obtain low-spin for oxy-heme, but they find that magnetic correlations are very small. DFT+MFA works well for high-spin, but this technique does not obtain low-spin because it does not find the location of IBS correctly. DFT+QMC gives the high(low)- spin state for deoxy-heme (oxy-heme) and finds IBS and magnetic correlations. We obtain that DFT+QMC works better among these methods for deoxy and oxy-heme molecules. Moreover, we investigate whether we can observe the IBS and magnetic correlations for vitamin B12, dye molecules and single-atom catalysts by using these computational approaches.Doctoral Thesis Optical and Electronic Properties of Atomically Thin Layered Materials: First Principles Calculations(Izmir Institute of Technology, 2019) İyikanat, Fadıl; Senger, Ramazan Tuğrul; Şahin, HasanThe extraordinary interest in two-dimensional (2D) materials is increasing day by day. Thanks to advances in the experimental techniques, monolayer form of another material is synthesized every day with features not seen in the bulk form. Ab initio methods provide useful tools for characterizing and functionalizing the various properties of these materials. The results obtained through first principles quantum-mechanical calculations can help to predict and understand the experimental data, such as the position and source of the spectroscopic peaks in the Raman or optical absorption spectra. The aim of this thesis is to predict and functionalize the optical and electronic properties of atomically thin layered materials using density functional theory and approaches beyond. Within the scope of this thesis, possible technological applications of various 2D materials ranging from perovskite crystals to transition metal dichalcogenites are investigated by using several functionalization methods. In order to accurately predict the optical properties of these materials, it is very important to use approaches that take into account the many-body effects. Recent studies have shown that many-body perturbation theory in the form of GW approximation is highly reliable to calculate the quasiparticle properties of materials. By solving the Bethe Salpeter equation on top of GW calculation, the quasiparticle energies and excitonic properties, which have dominant effect in the optical properties of ultra-thin materials are examined in detail.Doctoral Thesis Thermoelectric Effect in Layered Nanostructures(Izmir Institute of Technology, 2019) Özbal Sargın, Gözde; Senger, Ramazan Tuğrul; Sevinçli, HaldunIn this thesis, ballistic transport and thermoelectric (TE) properties of semiconducting and dynamically stable two-dimensional materials are investigated by combining first-principles calculations with Landauer formalism. Motivated by finding novel promising TE materials, transition metal dichalcogenides (TMDs) and oxides (TMOs) (namely MX2 with M = Cr, Mo, W, Ti, Zr, Hf; X = O, S, Se, Te) are studied systematically in their 2H- and 1T-phases in Chapter 3. Having computed structural, as well as ballistic electronic and phononic transport properties for all structures, we analyze the thermoelectric properties of the semiconducting ones. We report for the first time that, 2H-phases of four of the studied structures have very promising thermoelectric properties, unlike their 1T-phases. Next, ballistic transport and thermoelectric (TE) properties of group IIImonochalcogenides (group III-VI) are presented in a wide range temperature from 100 K to 1000 K. This large family composed of 25 compounds which stands out with their unique electronic band structures. In addition to Mexican hat shaped (quartic energy-momentum relation) valence band character, some of the structures exhibit valley degeneracies which can occur either in their conduction and valence bands. Moreover, TE and transport calculations are performed for BO and BS monolayers which consist of lightest species in group III-monochalcogenides. Surprisingly, BO and BS monolayers exhibit high TE efficiency at low temperatures. Low thermal conductance at low temperatures and stepwise electronic transmission at the valence band edge are the physical mechanisms behind achieving large ZT.