Energy Systems Engineering / Enerji Sistemleri Mühendisliği
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Article Citation - WoS: 2Citation - Scopus: 2Bayesian Uncertainty Quantification in Temperature Simulation of Borehole Heat Exchanger Fields for Geothermal Energy Supply(Pergamon-Elsevier Science Ltd, 2025) Mohammadi, Hesam Soltan; Ringel, Lisa Maria; Bott, Christoph; Erol, Selcuk; Bayer, PeterAccurate temperature prediction is crucial for optimizing the performance of borehole heat exchanger (BHE) fields. This study introduces an efficient Bayesian approach for improving the forecast of temperature changes in the ground caused by the operation of BHEs. The framework addresses the complexities of multi-layer subsurface structures and groundwater flow. By utilizing an affine invariant ensemble sampler, the framework estimates the distribution of key parameters, including heat extraction rate, thermal conductivity, and Darcy velocity. Validation of the proposed methodology is conducted through a synthetic case involving four active and one inactive BHE over five years, using monthly temperature changes around BHEs from a detailed numerical model as a reference. The moving finite line source model with anisotropy is employed as the forward model for efficient temperature approximations. Applying the proposed methodology at a monthly resolution for less than three years reduces uncertainty in long-term predictions by over 90%. Additionally, it enhances the applicability of the employed analytical forward model in real field conditions. Thus, this advancement offers a robust tool for stochastic prediction of thermal behavior and decision-making in BHE systems, particularly in scenarios with complex subsurface conditions and limited prior knowledge.Article Stochastic 1-D Reactive Transport Simulations To Assess Silica and Carbonate Phases During the $co_2$ Reinjection Process in Metasediments(TÜBİTAK - Türkiye Bilimsel ve Teknolojik Araştırma Kurumu, 2024) Erol, SelçukOne proposed method to mitigate carbon emission is to mineralize the $CO_2$ in deep geothermal reservoirs while mixing the coproduced CO2 with the effluent fluid for reinjection. The injection fluid temperature fluctuates due to the mixing process between CO2-charged water and the effluent fluid, and compressor interruptions change the thermodynamic conditions that influence the fluid- rock interaction in the reservoir. Mineral dissolution or precipitations are associated with changes in permeability and porosity that affect the flow and, eventually, the lifespan of the reservoir. A combined stochastic–reactive transport simulation approach is useful for inspection purposes. Moreover, the stochastic algorithm validates the deterministic reactive transport simulation and demonstrates the time evolution of a chemically reacting system in the reservoir. This study examines a range of injection temperatures between 80 °C and 120 °C to evaluate silica and calcite precipitation along a flow path. One-dimensional (1-D) reactive transport and compartment- based stochastic reaction-diffusion-advection Gillespie algorithms are carried out. The 1-D model represents a reservoir feed zone of around 2300 m. Two common metasediment rock types are evaluated for inspection. The first one is the muscovite schist, which has approximately 60% quartz, and the second is the quartz schist, consisting of roughly 90% quartz. The stochastic method can be applied more effectively if the chemical system is completely defined with proper reaction rates as a function of temperature. The mixing ratio of the coproduced $CO_2$ over the effluent fluid is around 0.0028. Simulation results show that $CO_2$ is partially sequestrated as calcite within the first 10 m of the entrance to the reservoir and plugs the pores completely in the muscovite schist scenario. Chalcedony and α-cristobalite precipitate as secondary minerals evenly along the flow path. $CO_2$ injection into a quartz schist layer is more appropriate for geochemical interactions below 120 °C.Erratum Author Correction: the Influence of Nano Filter Elements on Pressure Drop and Pollutant Elimination Efficiency in Town Border Stations(Nature Research, 2023) Heris, S.Z.; Ebadiyan, H.; Mousavi, S.B.; Nami, S.H.; Mohammadpourfard, MousaThe original version of this Article contained an error in the order of the author names, which was incorrectly given as Hamed Ebadiyan, Saeed Zeinali Heris, Seyed Borhan Mousavi, Shamin Hosseini Nami & Mousa Mohammadpourfard. Consequently, in the Author Contributions section, “H.E. Investigation. S.Z.H. Supervision, Conceptualization, Methodology, Validation. S.B.M. Formal analysis, Writing original draft. S.H.N. Formal analysis, Writing original draft. M.M. Validation.” now reads: “S.Z.H. Supervision, Conceptualization, Methodology, Validation. H.E. Investigation. S.B.M. Formal analysis, Writing original draft. S.H.N. Formal analysis, Writing original draft. M.M. Validation.” The original Article has been corrected. © 2023, The Author(s).Conference Object Citation - Scopus: 2Co2 Capture by Pei-Impregnated Alumina Sorbents(ISRES Publishing, 2023) Turgut, Furkan; Kostik, Simge; Erdoğan, Barış; Çağlar, BaşarDirect air capture (DAC) or direct CO2 extraction from ambient air is a promising approach to reduce greenhouse gas emissions caused by both distributed (location independent) and point sources (location specific). Solid sorbents have been considered as more effective for DAC compared to the liquid counterpart since they have a faster kinetic and avoid volatile and heat losses due to the absence of evaporation of liquids. In this study, the alumina-supported polyethyleneimine (PEI) material was chosen as solid sorbents and their CO2 capture performance for different PEI loadings (20, 35, 50 wt%), flow rate (15, 30, 45 L/h) and adsorption temperatures (30, 40, 50, 60 °C) was investigated. Sorbents were prepared by using wetness impregnation method and their physical and chemical properties were characterized by several techniques such as N2 adsorption-desorption (surface area, pore size and volume), Scanning Electron Microscopy-SEM (surface morphology, surface chemical composition). The CO2 capture performance of sorbents were analyzed under different CO2 concentrations and the cyclic (adsorption-desorption) behavior of the sorbents were tested. The results show that alumina-supported PEI adsorbents are promising materials for CO2 capture with high CO2 adsorption capacity and stability. © 2023 Published by ISRES.Article Citation - WoS: 30Citation - Scopus: 30A Novel Data-Driven Model for the Effect of Mood State on Thermal Sensation(MDPI, 2023) Turhan, Cihan; Özbey, Mehmet Furkan; Ceter, Aydın Ege; Gökçen Akkurt, GüldenThermal comfort has an important role in human life, considering that people spend most of their lives in indoor environments. However, the necessity of ensuring the thermal comfort of these people presents an important problem, calculating the thermal comfort accurately. The assessment of thermal comfort has always been problematic, from past to present, and the studies conducted in this field have indicated that there is a gap between thermal comfort and thermal sensation. Although recent studies have shown an effort to take human psychology into account more extensively, these studies just focused on the physiological responses of the human body under psychological disturbances. On the other hand, the mood state of people is one of the most significant parameters of human psychology. Thus, this paper investigated the effect of occupants' mood states on thermal sensation; furthermore, it introduced a novel Mood State Correction Factor (MSCF) to the existing thermal comfort model. To this aim, experiments were conducted at a mixed-mode building in a university between 15 August 2021 and 15 August 2022. Actual Mean Vote (AMV) and Profile of Mood States (POMS) were used to examine the effect of mood state on thermal sensation. The outcomes of this study showed that in the mood states of very pessimistic and very optimistic, the occupants felt warmer than the calculated one and the MSCFs are calculated as -0.125 and -0.114 for the very pessimistic and very optimistic mood states, respectively. It is worth our time to note that the experiments in this study were conducted during the COVID-19 Global Pandemic and the results of this study could differ in different cultural backgrounds.Article Citation - WoS: 7Citation - Scopus: 8Update for Reactive Transport Modeling of the Kızıldere Geothermal Field To Reduce Uncertainties in the Early Inspections(TÜBİTAK - Türkiye Bilimsel ve Teknolojik Araştırma Kurumu, 2023) Erol, Selçuk; Akın, Taylan; Akın, SerhatThe development of carbon capture and storage techniques has become essential to reduce and mitigating CO2 emissions to the atmosphere. CarbFix1 and CarbFix2 projects carried out in Iceland demonstrated that the emissions of waste CO2 gas from geothermal power plants can be captured and mixed with the effluent geofluid and subsequently injected back into the geothermal reservoir. This experience gained in the CarbFix projects expanded into other geothermal fields around Europe, and one of the demonstration sites is the geothermal field in Turkey, Kızıldere. This paper focuses on the results of an updated study on early field evaluations with reactive transport simulations. In the new three-dimensional numerical model, the geological formations and fault zones were updated according to the well-logs data. Based on the tracer tests performed in the field, the anisotropic permeabilities between the wells were evaluated and imposed into the model. Geofluid chemistry, mineral components, and the volume fractions used as input in the simulations are modified depending on the performed laboratory experiments on the metamorphic schists taken from the geothermal site (i.e. X-ray diffraction (XRD), energy dispersive X-ray (EDX), scanning-electron microscope (SEM), and batch reactor tests). Different thermodynamic databases such as Lawrance Livermore National Laboratory (LLNL) and Thermoddem databases were tested using PHREEQC and TOUGHREACT programs for consistency with experiments. The thermodynamic conditions and the geofluid-rock-CO2 interactions prevent the mineralization of CO2 in the reservoir. This outcome differs from CarbFix projects in terms of the carbonization process, but the CO2 injection is still reliable with solubility-trapping in a geothermal reservoir to partially mitigate the emission. Roughly, 200 kt of CO2 in 10 years can be safely injected into the geothermal reservoir. According to the new analysis, the ratio of magnesium, sodium, and potassium varies in solid solution series of feldspars and clay minerals as albite end-member and montmorillonite/illite end-members, respectively. The evaluations of solid solution reactions are relatively limited in the law of mass action approach used by PHREEQC and TOUGHREACT. © TÜBİTAK.Article Citation - WoS: 15Citation - Scopus: 18An Integrated Decision-Making Framework for Mitigating the Impact of Urban Heat Islands on Energy Consumption and Thermal Comfort of Residential Buildings(MDPI, 2023) Turhan, Cihan; Atalay, Ali Serdar; Gökçen Akkurt, GüldenUrban heat island (UHI) is a zone that is significantly warmer than its surrounding rural zones as a result of human activities and rapid and dense urbanization. Excessive air temperature due to the UHI phenomenon affects the energy performance of buildings and human health and contributes to global warming. Knowing that most of the building energy is consumed by residential buildings, therefore, developing a framework to mitigate the impact of the UHI on residential building energy performance is vital. This study develops an integrated framework that combines hybrid micro-climate and building energy performance simulations and multi-criteria decision-making techniques. As a case study, an urban area is analyzed under the Urban GreenUP project funded by the European Union's Horizon 2020 Programme. Four different strategies to mitigate the UHI effect, including the current situation, changing the low-albedo materials with high-albedo ones, nature-based solutions, and changing building facade materials, are investigated with a micro-climatic simulation tool. Then, the output of the strategies, which is potential air temperature, is used in a dynamic building energy simulation software to obtain energy consumption and thermal comfort data of the residential buildings in the case area. Finally, a multi-criteria decision-making model, using real-life criteria, such as total energy consumption, thermal comfort, capital cost, lifetime and installation flexibility, is used to make a decision for decreasing the UHI effect on residential energy performance of buildings. The results showed that applying NBSs, such as green roofs and changing existing trees with high leaf area density ones, have the highest ranking among all mitigation strategies. The output of this study may help urban planners, architects, and engineers in the decision-making processes during the design phase of urban planning.Article Citation - WoS: 7Citation - Scopus: 7Dynamic Development of Geochemical Reaction Fronts During Hydraulic Stimulation of Shale(Elsevier, 2023) Noel, Vincent; Druhan, Jennifer L.; Gündoğar, Aslı; Kovscek, Anthony R.; Brown Jr, Gordon E.; Bargar, John R.Injection of acidic hydraulic fracture fluid (HFF) into shale formations for unconventional oil/gas production results in chemical reactions in the shale matrix that can alter fluid transport. Here, we report the results of set of experiments designed to evaluate the impact of calcite dissolution as a function of carbonate mineral content on matrix chemical reactivity and pore-space modification concomitant with imbibition. We tracked acidic HFF transport in four samples of Wolfcamp shale with calcite contents varying from 4% to 59% by monitoring the rate and spatial extent of bromide tracer transport using synchrotron-based X-ray fluorescence microprobe (XFM) imaging. Concurrently, we also carried out XFM imaging of the spatial distribution of Ca in the Wolfcamp shale cores (as a proxy of calcite distribution). Our approach thus yields a direct record of time-resolved selective ion transport resulting from the penetration of acidic HFF and the associated mineral transformations in the shale cores. We show that the variability in calcite content of Wolfcamp shale samples can directly affect the rate and spatial extent of imbibition. Although reaction of the acidic HFF with carbonates in shales enhances calcite dissolution and increases porosity, the spatial extent of calcite dissolution in the shale matrix is limited due to a rapid neutralization of pH. The relative abundance and spatial distribution of calcite control the chemical saturation state of the HFF progressing into the matrix. As a result, calcite has a major impact on the spatial extent and rate of matrix alteration and thus on HFF transport during subsurface reservoir stimulation. Consequently, increased calcite content in the shale matrix inhibits the spatial extent of the pore-volume increase and, by extension, the spatial extent and rate of imbibition. Our results thus show that the overall rates of calcite dissolution approach the rates of acidic HFF transport (i. e., Damko spacing diaeresis hler number similar to 1), which could contribute to the efficiency of subsurface reservoir stimulation. A better understanding of HFF-calcite reaction rates is crucial for improving the prediction and optimization of fluid transport across HFF-shale interfaces during hydraulic fracturing.Article Citation - WoS: 23Citation - Scopus: 27The Influence of Meteorological Parameters on Pm10: a Statistical Analysis of an Urban and Rural Environment in İzmir/Turkiye(MDPI, 2023) Birim, Necmiye Gulin; Turhan, Cihan; Atalay, Ali Serdar; Gökçen Akkurt, GüldenAir pollution is a substantial menace, especially in industrialized urban zones, which affects the balance of the environment, life of vital organisms and human health. Besides the main causes of air pollution such as dense urbanization, poor quality fuels and vehicle emissions, physical environment characteristics play an important role on air quality. Therefore, it is vital to understand the relationship between the characteristics of the natural environment and air quality. This study examines the correlations between the PM10 pollutant data and meteorological parameters such as temperature (T-air), relative humidity (RH), and wind speed (WS) and direction (WD) under the European Union's Horizon 2020 project. Two different zones (Vilayetler Evi as an urban zone and Sasali Natural Life Park as a rural zone) of Izmir Province in Turkiye are used as a case study and the PM10 data is evaluated between 1 January 2017 and 31 December 2021. A one-tailed t-test is used in order to statistically determine the relationships between the PM10 pollutant data and meteorological parameters. As a further study, practical significance of the parameters is investigated via the effect size method and the results show that the RH is found to be the most influencing parameter on the PM10 for both zones, while T-air is found to be statistically non-significant.Article Citation - WoS: 45Citation - Scopus: 51Experimental Investigation of the Effect of Graphene/Water Nanofluid on the Heat Transfer of a Shell-And Heat Exchanger(Wiley-Hindawi, 2023) Zolfalizadeh, Mehrdad; Heris, Saeed Zeinali; Pourpasha, Hadi; Mohammadpourfard, Mousa; Meyer, Josua P. P.The most common type of heat exchanger used in a variety of industrial applications is the shell-and-tube heat exchanger (STHE). In this work, the impact of graphene nanoplate (GNP)/water nanofluids at 0.01 wt.%, 0.03 wt.%, and 0.06 wt.% on the thermal efficiency, thermal performance factor, pressure drop, overall heat transfer, convective heat transfer coefficient (CVHTC), and heat transfer characteristics of a shell-and-tube heat exchanger was examined. For these experiments, a new STHE was designed and built. The novelty of this study is the use of GNPs/water nanofluids in this new STHE for the first time and the fully experimental investigation of the attributes of nanofluids. GNP properties were analysed and confirmed using analyses including XRD and TEM. Zeta potential, DLS, and camera images were used to examine the stability of nanofluids at various periods. The zeta potential of the nanofluids was lower than -27.8 mV, confirming the good stability of GNP/water nanofluids. The results illustrated that the experimental data for distilled water had a reasonably good agreement with Sieder-Tate correlation. The maximum enhancement in the CVHTC of nanofluid with 0.06 wt.% of GNP, was equal to 910 (W/m(2)K), an increase of 22.47%. Also, the efficiency of the heat exchanger for nanofluid at 0.06 wt.% improved by 8.88% compared with that of the base fluid. The heat transfer rate of the nanofluid at maximum concentration and volume flow rate was 3915 (J/kg.K), an improvement of 15.65% over the base fluid. The pressure drops increased as the flow rate and concentration of the nanofluid increased. Although increasing the pressure drop in tubes would increase the CVHTC, it would also increase the power consumption of the pump. In conclusion, nanofluid at 0.06 wt.% had good performance.