Energy Systems Engineering / Enerji Sistemleri Mühendisliği

Permanent URI for this collectionhttps://hdl.handle.net/11147/4752

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Department: search.filters.department.İzmir Institute of Technology. Energy Systems EngineeringInstitution Author: search.filters.institutionAuthor.Çağlar, Başar

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Now showing 1 - 6 of 6
  • Conference Object
    Citation - Scopus: 2
    Co2 Capture by Pei-Impregnated Alumina Sorbents
    (ISRES Publishing, 2023) Turgut, Furkan; Kostik, Simge; Erdoğan, Barış; Çağlar, Başar
    Direct air capture (DAC) or direct CO2 extraction from ambient air is a promising approach to reduce greenhouse gas emissions caused by both distributed (location independent) and point sources (location specific). Solid sorbents have been considered as more effective for DAC compared to the liquid counterpart since they have a faster kinetic and avoid volatile and heat losses due to the absence of evaporation of liquids. In this study, the alumina-supported polyethyleneimine (PEI) material was chosen as solid sorbents and their CO2 capture performance for different PEI loadings (20, 35, 50 wt%), flow rate (15, 30, 45 L/h) and adsorption temperatures (30, 40, 50, 60 °C) was investigated. Sorbents were prepared by using wetness impregnation method and their physical and chemical properties were characterized by several techniques such as N2 adsorption-desorption (surface area, pore size and volume), Scanning Electron Microscopy-SEM (surface morphology, surface chemical composition). The CO2 capture performance of sorbents were analyzed under different CO2 concentrations and the cyclic (adsorption-desorption) behavior of the sorbents were tested. The results show that alumina-supported PEI adsorbents are promising materials for CO2 capture with high CO2 adsorption capacity and stability. © 2023 Published by ISRES.
  • Article
    Citation - WoS: 5
    Citation - Scopus: 5
    Exergetic Assessment of an Solar Powered Stand-Alone System Using Liquid Organic Hydrogen Carrier for Energy Storage
    (Elsevier, 2023) Palmero-Marrero, Ana I.; Zairov, Rüstem; Borge-Diez, David; Çağlar, Başar; Açıkkalp, Emin; Altuntaş, Önder
    The integration of energy storage technologies into renewable energy systems has gained increasing attention for continuous supply of the renewable-based enegy. Among different storage alternatives, the use of a Liquid Organic Hydrogen Carrier (LOHC) has a significant potential as a reversible energy carrier for short and longterm energy storage. In this study, the technical and economic performance of an stand-alone renewable energy systems using a LOHC for energy storage have been evaluated by exergy-based methods in addition to simple energy and economic analysis. The analysis of the LOHC-free system was also included to determine the effect of LOHC on the system performance. The system containing phovoltaic (PV) panels, an electrolyzer, a micro gas turbine and hydrogenation/dehydrogenation LOHC units was designed to meet the power, heating and cooling requirement of a residential building. The system modelling and performance evaluation were made by using TRNSYS and EES softwares. Results show that the LOHC-containing system has higher energy and exergy efficiencies and exergoeconomic performance than the LOHC-free system while the latter is economically more feasible than the former due to its low capital investment cost.
  • Article
    Citation - WoS: 15
    Citation - Scopus: 16
    Proposal of Novel Exergy-Based Sustainability Indices and Case Study for a Biomass Gasification Combine Cycle Integrated With Liquid Metal Magnetohydrodynamics
    (Elsevier, 2023) Canpolat Tosun, Demet; Açıkkalp, Emin; Çağlar, Başar; Altuntaş, Önder; Hepbaşlı, Arif
    Exergy is considered a way to sustainability. Exergy-based analyses have been recently widely used for performance assessment and comparison purposes of energy systems from production to end-user while different sustainability related indices or indicators including exergetic concepts have been developed in the literature. In this regard, the present study proposed five different indices: (i) Exergetic Fuel Based Environmental Remediation Index (X), (ii) Exergetic Product Based Environmental Remediation Index (delta), (iii) Exergetic Fuel Based Total Environmental Remediation Index (beta), (iv) Exergetic Product Based Total Environmental Remediation Index (alpha), and (v) Improved Sustainability Index (ISI). These indices were applied to a novel Biomass-integrated Gasification Combine Cycle (BIGCC) integrated with Liquid Metal Magnetohydrodynamics (LMMHD). They allowed to perform a more complete environmental analysis by considering the exergetic cost of environmental remediation of the process. The average exergy efficiency values for the BIGCC, LMMHD and the overall system were determined as 0.491, 0.222 and 0.688 under daily ambient temperatures for a year and different air to fuel ratio (AFR) conditions, respectively. The average values for.X, beta, delta, alpha and ISI were 1.636, 2.389, 1.949, 2.848 and 0.513, respectively.
  • Article
    Citation - WoS: 31
    Citation - Scopus: 33
    Energy and Exergy Analysis of a Pv-T Integrated Ethanol Pem Electrolyzer
    (Pergamon-Elsevier Science Ltd, 2021) Çağlar, Başar; Araz, Mustafa; Özcan, Hüseyin Günhan; Çalışan, Atalay; Hepbaşlı, Arif
    A photovoltaic-thermal (PV-T) integrated ethanol proton exchange membrane electrolyzer (PEME) was proposed as a low-energy consuming energy storage option for renewable-sourced electricity as well as a way for simultaneous chemical production in this study. Energy and exergy analyses were applied to each component of the system (e.g., pumps, heat exchanger, PV-T, PEME, and separation unit (SPU)) and the whole system to assess the system performance. The mathematical modelling of the whole system along with its main components except for the SPU was done using the Engineering Equation Solver (EES) software package while the SPU was modelled through the ASPEN Plus. A detailed modelling of the PEME was also included. The effects of the PV-T and PEME parameters on energy and exergy efficiencies of the system were evaluated while the improvement potentials and scale up options were discussed. Energy and exergy efficiencies of the proposed system at the optimum operation of the PEME and under average climatic conditions in the city of Izmir, Turkey were determined to be 27.8% and 3.1%, respectively. Energy and exergy efficiencies of the system were mainly regulated by the PV-T and PEME, whose energy and exergy efficiencies were 40.6%, 56.6% and 13.8%, 14.1%, respectively. Effective PEME parameters for energy and exergy efficiencies of the system were membrane conductivity, membrane thickness, anode catalyst and the operation temperature of the PEME. By changing the PV-T and PEME parameters and by scale-up, energy and exergy efficiencies of the system could be improved.
  • Article
    Citation - WoS: 22
    Citation - Scopus: 22
    Multiparameter-Based Product, Energy and Exergy Optimizations for Biomass Gasification
    (Elsevier, 2021) Çağlar, Başar; Tavşancı, Duygu; Bıyık, Emrah
    The thermodynamic modelling of biomass gasification was studied by using Gibbs free energy minimization approach. Different from the studies using the same approach, the simultaneous presence of all gasifying agents (air, H2O and CO2) was considered and a multiparameter optimization was applied to determine the synergetic effect of gasifying agents for hydrogen, syngas with a specific H2/CO ratio and methane production. The performance of gasification was assessed by using technical and environmental performance indicators such as product yields, cold gas efficiency, exergy efficiency, CO2 emission and the heat requirement of the gasifier. The results show that the simultaneous presence of gasifying agents does not create considerable changes in syngas yield, H2 yield, methane yield, CGE and exergy efficiency while it allows to tune the H2/CO ratio and the heat requirement of the gasifier. The highest syngas yield is observed at T > 1100 K and 1 bar and when SBR > 0.5 and/or CBR > 0.8 with the absence of air, at which CGE changes between 114% and 122% while exergy efficiency is between 77% and 86%. The results prove that CO2 offers several advantages as a gasifying agent and suggests that CO2 recycling from gasifier outlet is a useful option for the biomass gasification.
  • Article
    Citation - WoS: 4
    Citation - Scopus: 5
    Electrooxidation of Glycerol on Monometallic and Bimetallic Catalysts-Containing Porous Carbon Cloth Electrodes in an Alkaline Medium
    (Electrochemical Society, Inc., 2021) Çağlar, Başar; El Hassan, Youssef; Basak, Oğuzhan; Hepbaşlı, Arif
    The electrooxidation of glycerol was studied on monometallic (Pt/C, Co/C, Ni/C, Cu/C) and bimetallic catalysts (PtCo/C, PtNi/C, PtCu/C) - containing porous carbon cloth electrodes in an alkaline medium to gain insight about the potentials of electrodes for simultaneous hydrogen and chemical production. Physical and chemical properties of catalysts were characterized by using X-ray diffraction, X-ray photoemission spectroscopy, and transmission electron microscopy while electrochemical characteristics of electrodes were investigated by cyclic voltammetry, choronoamperometry, and electrochemical impedance spectroscopy. Bimetallic catalysts-containing electrodes showed higher glycerol electrooxidation activities and stabilities compared to monometallic catalysts-containing electrodes. The highest activity was observed on the PtCu/C-containing electrode due to its higher electrochemical active surface area and low kinetic and mass transfer resistance. It was also found that the presence of porous carbon cloth had a considerable effect on the glycerol electrooxidation activity.