Sürdürülebilir Yeşil Kampüs Koleksiyonu / Sustainable Green Campus Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7755
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Master Thesis Temperature Dependence of Resistivity and Hall Coefficient in Cu2znsns4 Absorbers for Thin Film Solar Cells(Izmir Institute of Technology, 2017) Akça, Fatime Gülşah; Aygün, Gülnur; Özyüzer, Lütfi; Aygün Özyüzer, Gülnur; Özyüzer, Lütfi; 04.05. Department of Pyhsics; 04. Faculty of Science; 01. Izmir Institute of Technologyenergy is the most powerful clean energy source to act on the current energy needing all over the world. The utilization of green energy systems should be promoted since these energy systems benefit consumers, industry and the environment effectively for the developing countries. This advancement can be solely achieved if renewable energy sources become more accessible. It means that not only cheaper but also handy clean energy systems are needed. In spite of relatively high efficiency obtained by using c-Si, Si solar modules require high budget for manufacturing. The high production cost of c-Si, PV industry is lead to search for cheaper candidate materials like Cu2ZnSnS4 (CZTS) as absorber layer in solar cells. The aim of the thesis is to investigate electrical properties of CZTS p-type intrinsic semiconductor compound on soda lime glass substrates, including the temperature dependent electrical conductivity, carrier concentrations and mobility extracted from Hall Effect measurements. Firstly, the metal precursor films were fabricated in multi-target sputtering system, then they were sulfurized inside the tubular furnace in order to obtain the CZTS compound. X-ray diffraction and Raman spectroscopy measurements revealed the formation of kesterite structure. A good crystallinity and grain compactness of the films were determined by scanning electron microscopy (SEM). Electrical properties were measured by van der Pauw techniques. Hall effect measurements showed the p-type semiconductor behavior for all samples at room temperature. Also, optical properties including absorption coefficient, spectral transmission, and optical band gap were determined to characterize CZTS thin films.Master Thesis Co Gas Sensor Applications of Fe Doped Calix[4] Arene Molecules(Izmir Institute of Technology, 2013) Özbek, Cebrail; Aygün, Gülnur; Aygün Özyüzer, Gülnur; 04.05. Department of Pyhsics; 04. Faculty of Science; 01. Izmir Institute of TechnologyInvisible and odourless carbon monoxide (CO) is one of the most toxic gas for respiratory systems. Therefore, the concentration level of carbon monoxide in the environment is extremely vital. In this thesis study, Calixarene molecules have been synthesized and the carbon monoxide selectivity and sensitivity of bare and iron doped calixarene molecules were measured by quartz crystal microbalance QCM technique and interdigitated electrodes with 3 ï m spacing. Calixarenes are promising compounds for sensing studies due to the well-designed cyclic structure, easily derivatization at both p- position of phenolic ring (upper rim) and phenolic-O (lower rim) as well as having diversely cavities which are a straightforward platform to form complex with molecules and ions. Quartz Crystal Microbalance is a powerful technique for nano scale determining the sorption properties of materials. According to Sauerbrey relation, the mass change on quartz crystal electrode cause a certain shift in the resonant frequency of vibrating crystal oscillator. This shift can be monitored using QCM method. In this study, a computer controlled QCM measurement system was developed for toxic gas detection. Iron doped calixarene based sensors were fabricated using drop-casting method on an AT-cut QCM gold electrode and interdigitated gold electrodes. The sensitivity and reproducible detection performances of prepared calixarene-iron doped calixarene thin films were measured under exposure of varying carbon monoxide for nitrogen and dry air used as desorption gas, respectively. The analysis of carbon monoxide sensitivity of iron doped calixarene is a new study for literature. This thesis study will guide future studies on this topic.