Sürdürülebilir Yeşil Kampüs Koleksiyonu / Sustainable Green Campus Collection

Permanent URI for this collectionhttps://hdl.handle.net/11147/7755

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  • Article
    Citation - WoS: 74
    Citation - Scopus: 89
    Seasonal Variation in Drinking Water Concentrations of Disinfection By-Products in Izmir and Associated Human Health Risks
    (Elsevier Ltd., 2008) Baytak, Derya; Sofuoğlu, Aysun; İnal, Fikret; Sofuoğlu, Sait Cemil
    Seasonal variation in concentrations of two different disinfection by-product groups, trihalomethanes (THMs) and haloacetonitriles (HANs), was investigated in tap water samples collected from five sampling points (one groundwater and four surface water sources) in İzmir, Turkey. Estimates of previously published carcinogenic and non-carcinogenic risks through oral exposure to THMs were re-evaluated using a probabilistic approach that took the seasonal concentration variation into account. Chloroform, bromoform, dibromochloromethane and dichloroacetonitrile were the most frequently detected compounds. Among these, chloroform was detected with the highest concentrations ranging from 0.03 to 98.4 μg/L. In tap water, at the groundwater supplied sampling point, brominated species, bromoform and dibromoacetonitrile, were detected at the highest levels most probably due to bromide ion intrusion from seawater. The highest total THM and total HAN concentrations were detected in spring while the lowest in summer and fall. The annual average total THM concentration measured at one of the surface water supplied sampling points exceeded the USEPA's limit of 80 μg/L. While all non-carcinogenic risks due to exposure to THMs in İzmir drinking water were negligible, carcinogenic risk levels associated with bromodichloromethane and dibromochloromethane were higher than one in million.
  • Master Thesis
    Seasonal Variation in Disinfection By-Product Concentrations in Izmir Drinking Water
    (Izmir Institute of Technology, 2007) Baytak, Derya; Sofuoğlu, Sait Cemil
    The goal of this study was to investigate the seasonal variation in disinfection byproduct (DBP) concentrations in drinking water zmir. In accordance with this aim, drinking water samples were collected from tap water of five sampling points in the distribution system of three different water sources (Tahtalı Reservoir, Balçova Reservoir and ground water) during a 10 month period, from June 2006 to April 2007. The samples were analyzed by GC-ECD according to EPA Method 551.1. In addition, while the organic matter content (measured as NPOC) and bromide ion concentration were measured in samples from Tahtalı and Balçova Water Treatment Plants, other parameters including pH, temperature and chlorine dose were obtained from the treatment plants. These parameters were used as explanatory variables in the multivariate regression analysis to construct statistical models for DBPs. Trihalomethanes were the most abundant DBPs in all samples, followed by haloacetonitriles, chloropicrin and halogenated ketones. The mean total trihalomethanes (TTHMs) concentration of Balçova, Narlıdere and Güzelbahçe was 20.78 ppb while it was 94.71 ppb at Hatay. Concentrations of DBPs in all sampling locations were found to be the highest in spring and lowest in summer and fall. Although TTHM levels in all samples were found to be in accordance with the current drinking water regulations of Turkey, 41 % of the samples from Hatay exceeded the level that will be come into effect in 2012. Multivariate regression analysis suggested that water temperature and total chlorine dose were the most effective parameters for DBPs. In addition, simple regression analysis between total haloacetonitriles and TTHMs revealed a very high correlation (R2.0.83). Logistic regression models were able to predict the probability of exceedance of the selected TTHM thresholds with 76 % efficiency.