Sürdürülebilir Yeşil Kampüs Koleksiyonu / Sustainable Green Campus Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7755
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Master Thesis Development of Antibacterial Polymer Based Nanocomposite Materials(Izmir Institute of Technology, 2015) Abatay, Ezgi; Arslanoğlu, Alper; Tanoğlu, MetinHuman beings are often infected by microorganisms such as bacterium, mold, yeast, virus, etc. in the living environment. It became a requirement and a necessity to create sterile fields in areas. Composite stones are one of the main materials that can be used for the contact surfaces in indoor and outdoor places due to their being of highly resistant to abrasives, chemicals and impacts. Research has been intensive in antibacterial material containing various inorganic substances. The aim of this thesis is investigating the antibacterial effect of inorganic substances such as silver, zinc oxide, calcium oxide, titanium oxide and magnesium oxide on stone products. This study also deals with the silver doped zinc oxide powder and their antibacterial efficacies. Stone product is formed of mainly two type compound which are quartz aggregates as reinforced and filler and thermoset polyester resin as matrix. The manufacturing process begins with selection of raw quartz materials. They are crushed and blended in the ratio of 90 % quartz aggregates to 10% polyester matrix and other additives such as antibacterial agent, pigment. These united constituents are used for production of composite stones by applying those combined vacuum, vibration and pressing processes which are named as vibropress, simultaneously. Following it, they are subjected to surface preparation and polishing processes. In this study, mechanical, thermal, and morphological properties of the particles, polyester matrix and stone product were investigated. Antibacterial efficacies of these were investigated based on colony-count method against gram negative (E.coli) and gram positive (Bacillus subtilis) bacteria. Silver-containing stone samples showed best antibacterial property about ninety-nine percent reduction.Master Thesis Processing and Characterization of High Performance Piping Materials for Geothermal Applications(Izmir Institute of Technology, 2003) Toğulga, Murat; Tanoğlu, MetinPolymer composite based pipes are being recently utilized in transportation of geothermal fluids.The utilization of composites is due to their resistance to aggressive chemicals and hot-wet environment with relatively high specific strength and design flexibility.Exposure of materials to wide range of temperatures and humidity level, while under the action of load, may degrade them and cause to severe reduction in their properties and service life.Understanding the complex degradation mechanism of the composites exposed to a variety of temperature and fluid chemistry (including geothermal fluid) is essential to improve their durability.This research focuses on the investigation of interactions between geothermal fluid and composite piping materials made of various matrices and the mechanism of degradation in these composites.The matrix materials include polyester, epoxy and graphite particle added epoxy materials.In this study, E-glass fiber reinforced polymer composites were fabricated by employing filament winding and tube rolling techniques.Fabricated composites and neat polymers were exposed to dry environment, distilled water and geothermal fluid of Balçova geothermal field until the saturation of weight gains due to water uptakes.In addition, the specimens with neat polymers were prepared to simulate and follow the degradation of matrix materials under hot-wet environments.Once the saturation occurred, the specimens were subjected compressive mechanical testing.For both dry and wet specimens, the mechanical testing was performed to obtain stress-strain behavior, modulus of elasticity, strain at failure values and energy absorption during the loading.The results were compared to evaluate the degradation of the properties due to various exposures.Moreover, the thermal conductivity of the various composites fabricated in this research was measured to determine the heat losses and temperature distribution within the materials.The temperature distribution within the cross-section of the pipes for various materials was analyzed using a finite element-modeling tool, LUSAS for uninsulated pipes.The heat loss occurring during the transportation of hot geothermal fluid was calculated as a case study to compare composites and traditional metal piping.It was found that polyester composite pipes have higher mechanical performance under axial and radial compression as compared to the composite with epoxy matrices. For all the composite types, some considerable degradations were measured due to exposure to hot-wet environments.The extend of degradation was less for graphite particles added epoxy composite pipes that exhibited the lowest water uptake values. The graphite particles incorporated into the matrix affected the water uptake and thermal conductivity of the epoxy.The water uptake of polyester matrix composite pipes was the highest that might be related to the most extensive degradation of polyester based composite.Moreover, it was found that the thermal conductivity of the composites is much lower than traditional materials.The graphite particles cause reduction in thermal conductivity, simultaneously in heat loss for uninsulated pipes.However, if the isolation is used, heat loss is not sensitive to pipe material.Master Thesis Investigation of Environmental Durability of Carbon Fiber/Epoxy Composites(Izmir Institute of Technology, 2013) Yağmur, Samet; Tanoğlu, MetinFiber reinforced polymer composites, that have increasing demand in many applications such as aircraft and automotive industry, are usually exposed to different environmental conditions which may be harmful to them. The investigation of their environmental durability is critical for those applications. The objective of this study was to investigate the effects of temperature and moisture on durability of carbon fiber reinforced epoxy composites. For this purpose, 0/90° woven, plain unidirectional and non-crimp biaxial ±45 fabrics were used as reinforcement. The specimens were manufactured using vacuum resin infusion process to obtain relatively high fibre volume fraction ratios. The composites manufactured were exposed to cyclic aging conditions to simulate aircraft flight environment. Hygrothermal, high temperature and freezing conditions were used as in one cycle which was 12 hours long. Moisture absorption was determined by weighing the specimens at regular intervals as a function of aging cycles. Tensile and flexural tests were performed prior to aging and after 500, 1000 and 1500 hours aging. After the completion of aging cycles, the moisture content did not increase significantly due to presence of subzero and high temperatures in aging cycles. The mechanical test results revealed differences based on the fabric types used. It was found that the tensile strength and modulus values of woven composites increased after aging cycles as compared to those of unidirectional and biaxial composites. On the other hand, flexural properties decreased at the end of the aging cycles for the composites aged as test coupons.
