Sürdürülebilir Yeşil Kampüs Koleksiyonu / Sustainable Green Campus Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7755
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Article Citation - WoS: 27Citation - Scopus: 34Chitosan/Montmorillonite Composite Nanospheres for Sustained Antibiotic Delivery at Post-Implantation Bone Infection Treatment(IOP Publishing Ltd., 2019) Kımna, Ceren; Değer, Sibel; Tamburacı, Sedef; Tıhmınlıoğlu, FundaDespite the advancements in bone transplantation operations, inflammation is still a serious problem that threatens human health at the post-implantation period. Conventional antibiotic therapy methods may lead to some side effects such as ototoxicity and nephrotoxicity, especially when applied in high doses. Therefore, local drug delivery systems play a vital role in bone disorders due to the elimination of the disadvantages introduced by conventional methods. In the presented study, it was aimed to develop Vancomycin (VC) and Gentamicin (GC) loaded chitosan-montmorillonite nanoclay composites (CS/MMT) to provide required antibiotic doses to combat post-implantation infection. CS/MMT nanocomposite formation was supplied by microfluidizer homogenization and spherical drug carrier nanoparticles were obtained by electrospraying technique. Three factors; voltage, distance and flowrate were varied to fabricate spherical nanoparticles with uniform size. Emprical model was developed to predict nanosphere size by altering process variables. Nanospheres were characterized in terms of morphology, hydrodynamic size, zeta potential, drug encapsulation efficiency and release profile. Drug loaded nanospheres have been successfully produced with a size range of 180-350 nm. Nanocomposite drug carriers showed high encapsulation efficiency (80%-95%) and prolonged release period when compared to bare chitosan nanospheres. The drug release from nanocomposite carriers was monitored by diffusion mechanism up to 30 d. The in vitro release medium of nanospheres showed strong antimicrobial activity against gram-positive S. aureus and gram-negative E. coli bacteria. Furthermore, it was found that the nanospheres did not show any cytotoxic effect to fibroblast (NIH/3T3) and osteoblast (SaOS-2) cell lines. The results demonstrated that the prepared composite nanospheres can be a promising option for bone infection prevention at the post implantation period.Article Citation - WoS: 2Citation - Scopus: 3Can Tube Tunnel Crossings Relieve Urban Congestion Problems? Izmir Tube Tunnel Project Proposal Under Scrutiny(MDPI Multidisciplinary Digital Publishing Institute, 2019) Duvarcı, Yavuz; Yiğitcanlar, TanBuilding underwater tube tunnel crossings to ease the urban congestion problems has become a popular approach for many cities across the globe. London, New York, Istanbul, Hamburg, Sydney and Brisbane are among these cities. However, the effectiveness and externalities of these expensive mega urban infrastructures have also been questioned widely among urban, transport and environmental planning scholars. Given the international popularity of the topic, this study places a new tube tunnel crossings project from Izmir, Turkey under the microscope. In this heuristic simulation study, policy-on scenarios were tested to determine possible impacts of the underwater tube tunnel-crossing project. The traffic impacts are discussed using simulations assigning the initial origin-destination data. The results of the study revealed that, given the two locations, outer and inner locations over the dagger-shape bay, the capacity increments on the bridge links and the links around the periphery highway did not bring any effective solutions beyond some minor improvements. The findings disclosed that the ineffectiveness of the tube tunnel crossing might be due to the excessive congestion happening all over the downtown area, which clogs the passageways to the bridge. The paper highlights the limitations of the tube tunnel-crossing project, emphasises the need for comprehensive investigations before committing to the project and advocates the emphasis to be actually given for sustainable mobility.Article Citation - WoS: 3Citation - Scopus: 3A Quality Assessment of Public Water Fountains and Relation To Human Health: a Case Study From Yozgat, Turkey(John Wiley and Sons Inc., 2019) İritaş, Servet Birgin; Türksoy, Vugar Ali; Deniz, Serdar; Koçoğlu, Serhat; Kırat, Güllü; Demirkesen, Ali Can; Baba, AlperPublic fountains are very common and everyday people appreciate the benefits a water fountain can bring. However, consumption of public fountain water in some country has decreased because of growing concerns that constituents in fountain water may have adverse effects on health. A few studies have examined the safety of public fountains, proposing only limited evidence of fountain-related health issues in Turkey. Most of these public fountains are sourced from natural springs in Turkey. In this study, a 177 fountain water and 32 rock samples were analysed for source and quality of water. The geology of the region has the direct impact on the quality of the public fountain water. The results indicate that the level of some elements exceeded the limit values determined by WHO and US.EPA. The most striking high values were observed for iron (Fe), nickel (Ni), aluminum (Al), arsenic (As) and bromine (Br) concentrations.Article Citation - WoS: 18Citation - Scopus: 19Oxyhydroxide of Metallic Nanowires in a Molecular H2o and H2o2 Environment and Their Effects on Mechanical Properties(Royal Society of Chemistry, 2018) Aral, Gürcan; İslam, Md Mahbubul; Wang, Yun-Jiang; Ogata, Shigenobu; van Duin, Adri C. T.To avoid unexpected environmental mechanical failure, there is a strong need to fully understand the details of the oxidation process and intrinsic mechanical properties of reactive metallic iron (Fe) nanowires (NWs) under various aqueous reactive environmental conditions. Herein, we employed ReaxFF reactive molecular dynamics (MD) simulations to elucidate the oxidation of Fe NWs exposed to molecular water (H2O) and hydrogen peroxide (H2O2) environment, and the influence of the oxide shell layer on the tensile mechanical deformation properties of Fe NWs. Our structural analysis shows that oxidation of Fe NWs occurs with the formation of different iron oxide and hydroxide phases in the aqueous molecular H2O and H2O2 oxidizing environments. We observe that the resulting microstructure due to pre-oxide shell layer formation reduces the mechanical stress via increasing the initial defect sites in the vicinity of the oxide region to facilitate the onset of plastic deformation during tensile loading. Specifically, the oxide layer of Fe NWs formed in the H2O2 environment has a relatively significant effect on the deterioration of the mechanical properties of Fe NWs. The weakening of the yield stress and Young modulus of H2O2 oxidized Fe NWs indicates the important role of local oxide microstructures on mechanical deformation properties of individual Fe NWs. Notably, deformation twinning is found as the primary mechanical plastic deformation mechanism of all Fe NWs, but it is initially observed at low strain and stress level for the oxidized Fe NWs.Article Citation - WoS: 2Citation - Scopus: 4Removal of Metals and Metalloids From Acidic Mining Lake (aml) Using Olive Oil Solid Waste (osw)(Springer Verlag, 2019) İlay, Remzi; Baba, Alper; Kavdır, YaseminThe acidic mining lakes have low pH values and high metal and metalloid concentrations. In this study, the ability of low-cost olive oil solid waste (OSW) to remove Al, As, Cd, Fe, B and Ti ions from aqueous solutions in short term has been evaluated. Adsorption capacities (mg g−1) of OSW (1:5–1:10 w/v) were 764.06–411.75 for Al, 0.26 for As, 0.07–0.14 for Cd, 2181.5–2406.5 for Fe, 23.70–82.50 for B and 0.12–0.0.34 for Ti. OSW addition increased acidic mine water (AMW) pH from 2.41 to 3.2 with 1:5 and from 2.41 to 2.7 to 1:10 mixing ratio, respectively, after 10 min. The best gradual decrease has been observed with different ratio of OSW applications on B and Ti concentrations. OSW adsorbs 32.41% and 62.68% of B at the ratio of 1:5 and 1:10 and 55.29% and 83.04% of Ti at the ratio of 1:5 and 1:10 (OSW:AMW) mixtures, respectively. The results show that OSW has great potential for metal removal from acidic mine water.Article Citation - WoS: 20Citation - Scopus: 22Modeling of Seawater Intrusion in a Coastal Aquifer of Karaburun Peninsula, Western Turkey(Springer Verlag, 2017) Mansour, Ahmed Y. S.; Baba, Alper; Gündüz, Orhan; Şimşek, Celalettin; Elçi, Alper; Murathan, Alim; Sözbilir, HasanSeawater intrusion is a major problem to freshwater resources especially in coastal areas where fresh groundwater is surrounded and could be easily influenced by seawater. This study presents the development of a conceptual and numerical model for the coastal aquifer of Karareis region (Karaburun Peninsula) in the western part of Turkey. The study also presents the interpretation and the analysis of the time series data of groundwater levels recorded by data loggers. The SEAWAT model is used in this study to solve the density-dependent flow field and seawater intrusion in the coastal aquifer that is under excessive pumping particularly during summer months. The model was calibrated using the average values of a 1-year dataset and further verified by the average values of another year. Five potential scenarios were analyzed to understand the effects of pumping and climate change on groundwater levels and the extent of seawater intrusion in the next 10 years. The result of the analysis demonstrated high levels of electrical conductivity and chloride along the coastal part of the study area. As a result of the numerical model, seawater intrusion is simulated to move about 420 m toward the land in the next 10 years under “increased pumping” scenario, while a slight change in water level and TDS concentrations was observed in “climate change” scenario. Results also revealed that a reduction in the pumping rate from Karareis wells will be necessary to protect fresh groundwater from contamination by seawater.Article Citation - WoS: 5Citation - Scopus: 5Tannery Wastewater Sediments Produced by Clinoptiolite/Polyacrylamide-aided Flocculation as a Clay Additive in Brick Making(Springer Verlag, 2017) Köseoğlu, Kemal; Cengizler, H.; İsrail, L. İ.; Polat, HürriyetToxic tannery wastewater(s) (TWW) pose(s) a great risk to the environment. This study explores the potential of mitigating the harmful effects of TWW through sedimentation using clinoptiolite in the presence of various anionic, cationic and non-ionic flocculants with different molecular weights and charge densities followed by encapsulation in a brick structure for stability. Compressive strength (CS), size reduction after firing (SRAF), water absorption (WA) and colouring parameters of bricks were determined. X-Ray diffraction (XRD) and scanning electron microscopy (SEM)-energy dispersive X-ray (EDX) analyses were conducted on brick bodies. Kinetic leaching experiments were conducted for possible heavy metal release from the bricks. Bricks containing 10 wt% leather waste and 5 wt% clinoptiolite sintered at 800 °C instead of 920 °C possessed similar properties to the standard brick (SB).Article Citation - WoS: 24Citation - Scopus: 26Role of Surface Oxidation on the Size Dependent Mechanical Properties of Nickel Nanowires: a Reaxff Molecular Dynamics Study(Royal Society of Chemistry, 2017) Aral, Gürcan; Islam, Md Mahbubul; Van Duin, Adri C. T.Highly reactive metallic nickel (Ni) is readily oxidized by oxygen (O2) molecules even at low temperatures. The presence of the naturally resulting pre-oxide shell layer on metallic Ni nano materials such as Ni nanowires (NW) is responsible for degrading the deformation mechanisms and related mechanical properties. However, the role of the pre-oxide shell layer on the metallic Ni NW coupled with the complicated mechanical deformation mechanism and related properties have not yet been fully and independently understood. For this reason, the ReaxFF reactive force field for Ni/O interactions was used to investigate the effect of surface oxide layers and the size-dependent mechanical properties of Ni NWs under precisely controlled tensile loading conditions. To directly quantify the size dependent surface oxidation effect on the tensile mechanical deformation behaviour and related properties for Ni NWs, first, ReaxFF-molecular dynamics (MD) simulations were carried out to study the oxidation kinetics on the free surface of Ni NWs in a molecular O2 environment as a function of various diameters (D = 5.0, 6.5, and 8.0 nm) of the NWs, but at the same length. Single crystalline, pure metallic Ni NWs were also studied as a reference. The results of the oxidation simulations indicate that a surface oxide shell layer with limiting thickness of ∼1.0 nm was formed on the free surface of the bare Ni NW, typically via dissociation of the O-O bonds and the subsequent formation of Ni-O bonds. Furthermore, we investigated the evolution of the size-dependent intrinsic mechanical elastic properties of the core-oxide shell (Ni/NixOy) NWs by comparing them with their un-oxidized counterparts under constant uniaxial tensile loading. We found that the oxide shell layer significantly decreases the mechanical properties of metallic Ni NW as well as facilitates the initiation of plastic deformation as a function of decreasing diameter. The disordered oxide shell layer on the Ni NW's surface remarkably reduces the yield stress and Young's modulus, due to the increased softening effects with the decreasing NW diameter, compared to un-oxidized counterparts. Moreover, the onset of plastic deformation occurs at a relatively low yielding strain and stress level for the smaller diameter of oxide-coated Ni NWs in comparison to their pure counterparts. Furthermore, for pure Ni NWs, Young's modulus, the yielding stress and strain slightly decrease with the decrease in the diameter size of Ni NWs.Article Citation - WoS: 46Citation - Scopus: 50Investigation of Europium Concentration Dependence on the Luminescent Properties of Borogermanate Glasses(Elsevier Ltd., 2017) Gökçe, Melis; Şentürk, Ufuk; Uslu, Deniz K.; Burgaz, Gözde; Şahin, Yüksel; Gökçe, Aytaç GürhanIn order to elucidate the effect of europium content on the optical and luminescent properties of borogermanate glasses, a series of Eu3+ doped 30B2O3-40GeO2-(30-x)Gd2O3 glasses with various doping levels (x=1–9 mol%) have been synthesized and studied with transmission, absorption, photoluminescence and decay time measurements. The transmission spectra proved that the title glasses maintained a high transparency about 80% in the 440 to 900 nm region. Based on the absorption spectra, the optical band gaps obtained from Tauc's plot can be narrowed by increasing content of Eu3+. From the photoluminescence spectra, the strongest red emission has been observed from the 5D0→7F2 level of Eu3+ ions in borogermanate glasses. The strongest emission and excitation intensities of Eu3+ ions are at the doping level of x=7 mol% and then these intensities decrease due to concentration quenching. The red to orange ratio (R/O) of 5D0→7F2 to 5D0→7F1 transitions has been investigated to predict the local environment of Eu3+ ions. Judd-Ofelt (J-O) analyses have been performed from the emission spectra. The values of R/O and Ω2 present an increase with increasing doping level, indicating the lower symmetric environment for Eu3+ ions and higher covalency for Eu-O bond. The emission efficiency calculated from J-O theory is 75% at x=2 mol%. The decay time curves of 6P7/2→8S7/2 transition of Gd3+ ions and 5D0–7F2 transition of Eu3+ ions confirm the energy transfer from Gd3+ to Eu3+ ions.Article Citation - WoS: 18Citation - Scopus: 24Empirical Sediment Transport Models Based on Indoor Rainfall Simulator and Erosion Flume Experimental Data(John Wiley and Sons Inc., 2017) Aksoy, Hafzullah; Eriş, Ebru; Tayfur, GökmenLand degradation processes start with accelerated runoff and sediment delivery. In this study, rainfall-runoff induced sediment transport is investigated using data from an indoor laboratory experimental setup consisting of a rainfall simulator and an erosion flume. The data are analysed to develop empirical models using sediment discharge, slope, flow discharge, rainfall intensity and sediment size. Fine and medium sands are considered as bare soil in experiments. Four rainfall intensities (45, 65, 85 and 105 mm h−1) are applied with combinations of lateral and longitudinal slopes of 5%, 10%, 15% and 20%. Eighty experiments are conducted. Flow is measured, and sediment within flow is separated and weighted. Experimental data are used for developing empirical models through multiple regression with parameters optimized by genetic algorithm. Results show that slope is the main contributing variable to the sediment transport over hillslopes. Accommodating variables among slope, rainfall intensity, flow discharge and median diameter of sediment as independent variables, one-variable, two-variable and four-variable models are developed considering also that higher number of parameters increases the performance of the model with higher cost of parameterization.
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